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3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors

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  • Li, Zijiong
  • Liu, Ping
  • Yun, Gaoqian
  • Shi, Kai
  • Lv, Xiaowei
  • Li, Kun
  • Xing, Jianhua
  • Yang, Baocheng

Abstract

3D (Three-dimensional) ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO sandwich-structured were synthesized by adding zinc oxide powder to the reaction of graphitic oxide reduction and heating. In this reaction, ZnO nanorods arrays with the size of 20–40 nm grew on both surfaces of rGO sheets directly. Compared with the rGO, the as-obtained ZnO/rGO/ZnO exhibited higher surface area. The electrochemical performance of ZnO/rGO/ZnO electrodes was investigated for energy storage. The maximum specific capacitance of 275 F g−1 at scan rate of 5 mV s−1 by chronopotentiometry was achieved for ZnO/rGO/ZnO sandwich-structured in 1.0 M Na2SO4. The hybrid ZnO/rGO/ZnO sandwich-structured exhibited an excellent rate capability and excellent long-term cycling stability as compared with rGO. Such results demonstrated that this ZnO/rGO/ZnO sandwich-structured was a promising candidate of electrode material for high-performance supercapacitor.

Suggested Citation

  • Li, Zijiong & Liu, Ping & Yun, Gaoqian & Shi, Kai & Lv, Xiaowei & Li, Kun & Xing, Jianhua & Yang, Baocheng, 2014. "3D (Three-dimensional) sandwich-structured of ZnO (zinc oxide)/rGO (reduced graphene oxide)/ZnO for high performance supercapacitors," Energy, Elsevier, vol. 69(C), pages 266-271.
    • Handle: RePEc:eee:energy:v:69:y:2014:i:c:p:266-271
    DOI: 10.1016/j.energy.2014.03.003
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    References listed on IDEAS

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    1. Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    2. Dubal, Deepak P. & Holze, Rudolf, 2013. "All-solid-state flexible thin film supercapacitor based on Mn3O4 stacked nanosheets with gel electrolyte," Energy, Elsevier, vol. 51(C), pages 407-412.
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    1. Xu, Le & Zhao, Yan & Lian, Jiabiao & Xu, Yuanguo & Bao, Jian & Qiu, Jingxia & Xu, Li & Xu, Hui & Hua, Mingqing & Li, Huaming, 2017. "Morphology controlled preparation of ZnCo2O4 nanostructures for asymmetric supercapacitor with ultrahigh energy density," Energy, Elsevier, vol. 123(C), pages 296-304.
    2. Shao, Zhou & Li, Hongji & Li, Mingji & Li, Cuiping & Qu, Changqing & Yang, Baohe, 2015. "Fabrication of polyaniline nanowire/TiO2 nanotube array electrode for supercapacitors," Energy, Elsevier, vol. 87(C), pages 578-585.
    3. Kim, Hong-Ki & Lee, Seung-Hwan, 2016. "Enhanced electrochemical performances of cylindrical hybrid supercapacitors using activated carbon/ Li4-xMxTi5-yNyO12 (M=Na, N=V, Mn) electrodes," Energy, Elsevier, vol. 109(C), pages 506-511.

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