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Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte

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  • Tamilarasan, P.
  • Ramaprabhu, S.

Abstract

Herein, we report, the fabrication of a mechanically stable, flexible graphene based all-solid-state supercapacitor with ionic liquid incorporated polyacrylonitrile (PAN/[BMIM][TFSI]) electrolyte for electric vehicles (EVs). The PAN/[BMIM][TFSI] electrolyte shows high ionic conductivity (2.42 mS/cm at 28 °C) with high thermal stability. Solid-like layered phase of ionic liquid is observed on the surface of pores of PAN membrane along with liquid phase which made it possible to hold 400 wt% of mobile phase. This phase formation is facilitated by the ionic interaction of CN moieties with the electrolyte ions. A supercapacitor device, comprised PAN/[BMIM][TFSI] electrolyte and graphene as electrode, is fabricated and the performance is demonstrated. Several parameters of the device, like, energy storage and discharge capacity, internal power dissipation, operating temperature, safe operation and mechanical stability, meet the requirements of future EVs. In addition, a good cyclic stability is observed even after 1000 cycles.

Suggested Citation

  • Tamilarasan, P. & Ramaprabhu, S., 2013. "Graphene based all-solid-state supercapacitors with ionic liquid incorporated polyacrylonitrile electrolyte," Energy, Elsevier, vol. 51(C), pages 374-381.
    • Handle: RePEc:eee:energy:v:51:y:2013:i:c:p:374-381
    DOI: 10.1016/j.energy.2012.11.037
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    5. Liew, Chiam-Wen & Ramesh, S. & Arof, A.K., 2016. "Enhanced capacitance of EDLCs (electrical double layer capacitors) based on ionic liquid-added polymer electrolytes," Energy, Elsevier, vol. 109(C), pages 546-556.
    6. Singh, Manoj K. & Suleman, Mohd & Kumar, Yogesh & Hashmi, S.A., 2015. "A novel configuration of electrical double layer capacitor with plastic crystal based gel polymer electrolyte and graphene nano-platelets as electrodes: A high rate performance," Energy, Elsevier, vol. 80(C), pages 465-473.
    7. Huang, Ke-Jing & Wang, Lan & Zhang, Ji-Zong & Wang, Ling-Ling & Mo, Yan-Ping, 2014. "One-step preparation of layered molybdenum disulfide/multi-walled carbon nanotube composites for enhanced performance supercapacitor," Energy, Elsevier, vol. 67(C), pages 234-240.
    8. Miao, Fujun & Shao, Changlu & Li, Xinghua & Lu, Na & Wang, Kexin & Zhang, Xin & Liu, Yichun, 2016. "Polyaniline-coated electrospun carbon nanofibers with high mass loading and enhanced capacitive performance as freestanding electrodes for flexible solid-state supercapacitors," Energy, Elsevier, vol. 95(C), pages 233-241.
    9. Kim, Jongmin & Ju, Haeri & Inamdar, Akbar I. & Jo, Yongcheol & Han, J. & Kim, Hyungsang & Im, Hyunsik, 2014. "Synthesis and enhanced electrochemical supercapacitor properties of Ag–MnO2–polyaniline nanocomposite electrodes," Energy, Elsevier, vol. 70(C), pages 473-477.
    10. Yanik, Mahir Ozan & Yigit, Ekrem Akif & Akansu, Yahya Erkan & Sahmetlioglu, Ertugrul, 2017. "Magnetic conductive polymer-graphene nanocomposites based supercapacitors for energy storage," Energy, Elsevier, vol. 138(C), pages 883-889.
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