IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v46y2012i1p200-210.html
   My bibliography  Save this article

Exergy analysis of thermochemical ethanol production via biomass gasification and catalytic synthesis

Author

Listed:
  • van der Heijden, Harro
  • Ptasinski, Krzysztof J.

Abstract

In this paper an exergy analysis of thermochemical ethanol production from biomass is presented. This process combines a steam-blown indirect biomass gasification of woody feedstock, with a subsequent conversion of produced syngas into ethanol. The production process involves several process sections, including biomass drying and gasification, syngas cleaning, reforming, conditioning, and compression, ethanol synthesis, separation of synthesis products, and heat recovery. The process is simulated with a computer model using the flow-sheeting software Aspen Plus. The exergy analysis is performed for various ethanol catalysts, including Rh-based and MoS2-based (target) catalysts as well as for various gasification temperatures. The exergetic efficiency is 43.5% for Rh-based and 44.4% for MoS2-based (target) catalyst, when ethanol is considered as the only exergetic output. In case when by-products of ethanol synthesis are considered as the additional output the exergetic efficiency for Rh-based catalyst increases to 58.9% and 65.8% for MoS2-based (target) catalyst. The largest exergy losses occur in biomass gasifier and ethanol synthesis reactor. The exergetic efficiency for both ethanol catalysts increases with decreasing gasification temperature.

Suggested Citation

  • van der Heijden, Harro & Ptasinski, Krzysztof J., 2012. "Exergy analysis of thermochemical ethanol production via biomass gasification and catalytic synthesis," Energy, Elsevier, vol. 46(1), pages 200-210.
    • Handle: RePEc:eee:energy:v:46:y:2012:i:1:p:200-210
    DOI: 10.1016/j.energy.2012.08.036
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544212006676
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2012.08.036?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Prins, Mark J. & Ptasinski, Krzysztof J. & Janssen, Frans J.J.G., 2007. "From coal to biomass gasification: Comparison of thermodynamic efficiency," Energy, Elsevier, vol. 32(7), pages 1248-1259.
    2. He, Jie & Zhang, Wennan, 2011. "Techno-economic evaluation of thermo-chemical biomass-to-ethanol," Applied Energy, Elsevier, vol. 88(4), pages 1224-1232, April.
    3. Juraščík, Martin & Sues, Anna & Ptasinski, Krzysztof J., 2010. "Exergy analysis of synthetic natural gas production method from biomass," Energy, Elsevier, vol. 35(2), pages 880-888.
    4. Sues, Anna & Juraščík, Martin & Ptasinski, Krzysztof, 2010. "Exergetic evaluation of 5 biowastes-to-biofuels routes via gasification," Energy, Elsevier, vol. 35(2), pages 996-1007.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Kristianto, Yohanes & Zhu, Liandong, 2017. "Techno-economic optimization of ethanol synthesis from rice-straw supply chains," Energy, Elsevier, vol. 141(C), pages 2164-2176.
    2. Ahmed, A.M.A & Salmiaton, A. & Choong, T.S.Y & Wan Azlina, W.A.K.G., 2015. "Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1623-1644.
    3. Taylor-de-Lima, Reynaldo L.N. & Gerbasi da Silva, Arthur José & Legey, Luiz F.L. & Szklo, Alexandre, 2018. "Evaluation of economic feasibility under uncertainty of a thermochemical route for ethanol production in Brazil," Energy, Elsevier, vol. 150(C), pages 363-376.
    4. Paixão, Susana M. & Alves, Luís & Pacheco, Rui & Silva, Carla M., 2018. "Evaluation of Jerusalem artichoke as a sustainable energy crop to bioethanol: energy and CO2eq emissions modeling for an industrial scenario," Energy, Elsevier, vol. 150(C), pages 468-481.
    5. Jana, Kuntal & De, Sudipta, 2015. "Polygeneration using agricultural waste: Thermodynamic and economic feasibility study," Renewable Energy, Elsevier, vol. 74(C), pages 648-660.
    6. Antonio Molino & Vincenzo Larocca & Simeone Chianese & Dino Musmarra, 2018. "Biofuels Production by Biomass Gasification: A Review," Energies, MDPI, vol. 11(4), pages 1-31, March.
    7. Fallahi, Alireza & Farzad, Somayeh & Mohtasebi, Seyed Saeid & Mandegari, Mohsen & Görgens, Johann F. & Gupta, Vijai Kumar & Lam, Su Shiung & Tabatabaei, Meisam & Aghbashlo, Mortaza, 2021. "Sustainability assessment of sugarcane residues valorization to biobutadiene by exergy and exergoeconomic evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 147(C).
    8. Parvez, A.M. & Mujtaba, I.M. & Wu, T., 2016. "Energy, exergy and environmental analyses of conventional, steam and CO2-enhanced rice straw gasification," Energy, Elsevier, vol. 94(C), pages 579-588.
    9. Nugroho, Yohanes Kristianto & Zhu, Liandong, 2019. "Platforms planning and process optimization for biofuels supply chain," Renewable Energy, Elsevier, vol. 140(C), pages 563-579.
    10. Skorek-Osikowska, Anna & Bartela, Łukasz & Kotowicz, Janusz & Sobolewski, Aleksander & Iluk, Tomasz & Remiorz, Leszek, 2014. "The influence of the size of the CHP (combined heat and power) system integrated with a biomass fueled gas generator and piston engine on the thermodynamic and economic effectiveness of electricity an," Energy, Elsevier, vol. 67(C), pages 328-340.
    11. Morsy, Fatthy Mohamed, 2015. "CO2-free biohydrogen production by mixed dark and photofermentation bacteria from sorghum starch using a modified simple purification and collection system," Energy, Elsevier, vol. 87(C), pages 594-604.
    12. Mendiburu, Andrés Z. & Carvalho, João A. & Coronado, Christian J.R., 2014. "Thermochemical equilibrium modeling of biomass downdraft gasifier: Stoichiometric models," Energy, Elsevier, vol. 66(C), pages 189-201.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Saidur, R. & BoroumandJazi, G. & Mekhilef, S. & Mohammed, H.A., 2012. "A review on exergy analysis of biomass based fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(2), pages 1217-1222.
    2. Kotowicz, Janusz & Sobolewski, Aleksander & Iluk, Tomasz, 2013. "Energetic analysis of a system integrated with biomass gasification," Energy, Elsevier, vol. 52(C), pages 265-278.
    3. Loha, Chanchal & Chattopadhyay, Himadri & Chatterjee, Pradip K., 2011. "Thermodynamic analysis of hydrogen rich synthetic gas generation from fluidized bed gasification of rice husk," Energy, Elsevier, vol. 36(7), pages 4063-4071.
    4. Vitasari, Caecilia R. & Jurascik, Martin & Ptasinski, Krzysztof J., 2011. "Exergy analysis of biomass-to-synthetic natural gas (SNG) process via indirect gasification of various biomass feedstock," Energy, Elsevier, vol. 36(6), pages 3825-3837.
    5. He, Chang & Feng, Xiao & Chu, Khim Hoong, 2013. "Process modeling and thermodynamic analysis of Lurgi fixed-bed coal gasifier in an SNG plant," Applied Energy, Elsevier, vol. 111(C), pages 742-757.
    6. Mendiburu, Andrés Z. & Carvalho, João A. & Coronado, Christian J.R., 2014. "Thermochemical equilibrium modeling of biomass downdraft gasifier: Stoichiometric models," Energy, Elsevier, vol. 66(C), pages 189-201.
    7. Stergios Vakalis & Konstantinos Moustakas, 2019. "Applications of the 3T Method and the R1 Formula as Efficiency Assessment Tools for Comparing Waste-to-Energy and Landfilling," Energies, MDPI, vol. 12(6), pages 1-11, March.
    8. Rovas, Dimitrios & Zabaniotou, Anastasia, 2015. "Exergy analysis of a small gasification-ICE integrated system for CHP production fueled with Mediterranean agro-food processing wastes: The SMARt-CHP," Renewable Energy, Elsevier, vol. 83(C), pages 510-517.
    9. Kolb, Sebastian & Plankenbühler, Thomas & Hofmann, Katharina & Bergerson, Joule & Karl, Jürgen, 2021. "Life cycle greenhouse gas emissions of renewable gas technologies: A comparative review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 146(C).
    10. Wang, Sheng & Bi, Xiaotao & Wang, Shudong, 2015. "Thermodynamic analysis of biomass gasification for biomethane production," Energy, Elsevier, vol. 90(P2), pages 1207-1218.
    11. Atsonios, Konstantinos & Kougioumtzis, Michael-Alexander & D. Panopoulos, Kyriakos & Kakaras, Emmanuel, 2015. "Alternative thermochemical routes for aviation biofuels via alcohols synthesis: Process modeling, techno-economic assessment and comparison," Applied Energy, Elsevier, vol. 138(C), pages 346-366.
    12. Ramos, Ana & Monteiro, Eliseu & Rouboa, Abel, 2019. "Numerical approaches and comprehensive models for gasification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 110(C), pages 188-206.
    13. Karami, Kavosh & Karimi, Keikhosro & Mirmohamadsadeghi, Safoora & Kumar, Rajeev, 2022. "Mesophilic aerobic digestion: An efficient and inexpensive biological pretreatment to improve biogas production from highly-recalcitrant pinewood," Energy, Elsevier, vol. 239(PE).
    14. Gassner, Martin & Maréchal, François, 2009. "Thermodynamic comparison of the FICFB and Viking gasification concepts," Energy, Elsevier, vol. 34(10), pages 1744-1753.
    15. Balcombe, Paul & Speirs, Jamie & Johnson, Erin & Martin, Jeanne & Brandon, Nigel & Hawkes, Adam, 2018. "The carbon credentials of hydrogen gas networks and supply chains," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 1077-1088.
    16. Caspeta, Luis & Caro-Bermúdez, Mario A. & Ponce-Noyola, Teresa & Martinez, Alfredo, 2014. "Enzymatic hydrolysis at high-solids loadings for the conversion of agave bagasse to fuel ethanol," Applied Energy, Elsevier, vol. 113(C), pages 277-286.
    17. Peters, Jens F. & Petrakopoulou, Fontina & Dufour, Javier, 2015. "Exergy analysis of synthetic biofuel production via fast pyrolysis and hydroupgrading," Energy, Elsevier, vol. 79(C), pages 325-336.
    18. Martínez, Laura V. & Rubiano, Jairo E. & Figueredo, Manuel & Gómez, María F., 2020. "Experimental study on the performance of gasification of corncobs in a downdraft fixed bed gasifier at various conditions," Renewable Energy, Elsevier, vol. 148(C), pages 1216-1226.
    19. Ngo, Son Ich & Nguyen, Thanh D.B. & Lim, Young-Il & Song, Byung-Ho & Lee, Uen-Do & Choi, Young-Tai & Song, Jae-Hun, 2011. "Performance evaluation for dual circulating fluidized-bed steam gasifier of biomass using quasi-equilibrium three-stage gasification model," Applied Energy, Elsevier, vol. 88(12), pages 5208-5220.
    20. Wennan Zhang & Jie He & Per Engstrand & Olof Björkqvist, 2015. "Economic Evaluation on Bio-Synthetic Natural Gas Production Integrated in a Thermomechanical Pulp Mill," Energies, MDPI, vol. 8(11), pages 1-15, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:46:y:2012:i:1:p:200-210. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.