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Exergetic evaluation of 5 biowastes-to-biofuels routes via gasification

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  • Sues, Anna
  • Juraščík, Martin
  • Ptasinski, Krzysztof

Abstract

This paper presents the exergy analysis results for the production of several biofuels, i.e., SNG (synthetic natural gas), methanol, Fischer–Tropsch fuels, hydrogen, as well as heat and electricity, from several biowastes generated in the Dutch province of Friesland, selected as one of the typical European regions. Biowastes have been classified in 5 virtual streams according to their ultimate and proximate analysis. All production chains have been modeled in Aspen Plus in order to analyze their technical performance. The common steps for all the production chains are: pre-treatment, gasification, gas cleaning, water–gas-shift reactions, catalytic reactors, final gas separation and upgrading. Optionally a gas turbine and steam turbines are used to produce heat and electricity from unconverted gas and heat removal, respectively. The results show that, in terms of mass conversion, methanol production seems to be the most efficient process for all the biowastes. SNG synthesis is preferred when exergetic efficiency is the objective parameter, but hydrogen process is more efficient when the performance is analyzed by means of the 1st Law of Thermodynamics. The main exergy losses account for the gasification section, except in the electricity and heat production chain, where the combined cycle is less efficient.

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  • Sues, Anna & Juraščík, Martin & Ptasinski, Krzysztof, 2010. "Exergetic evaluation of 5 biowastes-to-biofuels routes via gasification," Energy, Elsevier, vol. 35(2), pages 996-1007.
    • Handle: RePEc:eee:energy:v:35:y:2010:i:2:p:996-1007
    DOI: 10.1016/j.energy.2009.06.027
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    1. Ptasinski, Krzysztof J. & Prins, Mark J. & Pierik, Anke, 2007. "Exergetic evaluation of biomass gasification," Energy, Elsevier, vol. 32(4), pages 568-574.
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    8. Schmidt, Johannes & Leduc, Sylvain & Dotzauer, Erik & Schmid, Erwin, 2011. "Cost-effective policy instruments for greenhouse gas emission reduction and fossil fuel substitution through bioenergy production in Austria," Energy Policy, Elsevier, vol. 39(6), pages 3261-3280, June.
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    13. Clausen, Lasse R. & Houbak, Niels & Elmegaard, Brian, 2010. "Technoeconomic analysis of a methanol plant based on gasification of biomass and electrolysis of water," Energy, Elsevier, vol. 35(5), pages 2338-2347.
    14. Wang, Chaoyang & Liu, Ming & Zhao, Yongliang & Wang, Zhu & Yan, Junjie, 2018. "Thermodynamics analysis on a heat exchanger unit during the transient processes based on the second law," Energy, Elsevier, vol. 165(PB), pages 622-633.
    15. Qin, Shiyue & Chang, Shiyan & Yao, Qiang, 2018. "Modeling, thermodynamic and techno-economic analysis of coal-to-liquids process with different entrained flow coal gasifiers," Applied Energy, Elsevier, vol. 229(C), pages 413-432.
    16. Saidur, R. & BoroumandJazi, G. & Mekhilef, S. & Mohammed, H.A., 2012. "A review on exergy analysis of biomass based fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(2), pages 1217-1222.
    17. Velásquez-Arredondo, H.I. & De Oliveira Junior, S. & Benjumea, P., 2012. "Exergy efficiency analysis of chemical and biochemical stages involved in liquid biofuels production processes," Energy, Elsevier, vol. 41(1), pages 138-145.
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    19. Clausen, Lasse R. & Elmegaard, Brian & Ahrenfeldt, Jesper & Henriksen, Ulrik, 2011. "Thermodynamic analysis of small-scale dimethyl ether (DME) and methanol plants based on the efficient two-stage gasifier," Energy, Elsevier, vol. 36(10), pages 5805-5814.
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