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Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus

Author

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  • Ahmed, A.M.A
  • Salmiaton, A.
  • Choong, T.S.Y
  • Wan Azlina, W.A.K.G.

Abstract

Biomass tar has attracted attention in recent years to be modeled or represented by a specific formula or compound. It is a complex material, and its composition varies according to the process operating conditions such as gasification or pyrolysis. This paper reviews different tar models in which tar is represented as different components such as naphthalene, toluene and even as a bulk tar, based on operating temperatures range and their thermal stability or assumptions that have been made to model the process. All these models are done by Aspen Plus simulator based on kinetic and thermodynamic equilibrium, whereby different reactor models are used to represent processes in relevant with tar production or cracking. Results for the operation of combined heat and power (CHP) biomass bubbling fluidized bed gasification, which integrated with solid fuel cell (SOFC) or coupled with an internal combustion engine (ICE), show different accuracy in terms of cold gas or electrical efficiencies, depending on how tar is approximated (either as one hydrocarbon compound or mixture of hydrocarbons). Likewise, for three-stage and one fluidized bed unit, the performance is predicted through estimation of the cold gas efficiency and high heating value (HHV) of the produced gas, where the tar representation has also an impact on the accuracy of the predictions.

Suggested Citation

  • Ahmed, A.M.A & Salmiaton, A. & Choong, T.S.Y & Wan Azlina, W.A.K.G., 2015. "Review of kinetic and equilibrium concepts for biomass tar modeling by using Aspen Plus," Renewable and Sustainable Energy Reviews, Elsevier, vol. 52(C), pages 1623-1644.
    • Handle: RePEc:eee:rensus:v:52:y:2015:i:c:p:1623-1644
    DOI: 10.1016/j.rser.2015.07.125
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    6. Vera Marcantonio & Luisa Di Paola & Marcello De Falco & Mauro Capocelli, 2023. "Modeling of Biomass Gasification: From Thermodynamics to Process Simulations," Energies, MDPI, vol. 16(20), pages 1-30, October.
    7. Tavares, Raquel & Monteiro, Eliseu & Tabet, Fouzi & Rouboa, Abel, 2020. "Numerical investigation of optimum operating conditions for syngas and hydrogen production from biomass gasification using Aspen Plus," Renewable Energy, Elsevier, vol. 146(C), pages 1309-1314.
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    9. Ferreiro, A.I. & Segurado, R. & Costa, M., 2020. "Modelling soot formation during biomass gasification," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
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