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Impregnation of microporous SDC scaffold as stable solid oxide cell BSCF-based air electrode

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  • Asensio, Antonio Maria
  • Clematis, Davide
  • Viviani, Massimo
  • Carpanese, M. Paola
  • Presto, Sabrina
  • Cademartori, Davide
  • Cabot, Pere L.
  • Barbucci, Antonio

Abstract

Barium strontium cobaltite-ferrite (Ba1-xSrxCoyFe1-yO3-δ, BSCF) is a widely studied mixed ionic-electronic conductor material for air electrode in solid oxide cells (SOC). Despite having excellent features, due to fast oxygen surface exchange and oxygen bulk diffusion, it lacks long-term stability. Electrode/electrolyte thermal expansion coefficient (TEC) mismatch and structural instability at temperature lower than 900 °C are responsible for the increase of electrode polarization which becomes a crucial issue for the long-term stability.

Suggested Citation

  • Asensio, Antonio Maria & Clematis, Davide & Viviani, Massimo & Carpanese, M. Paola & Presto, Sabrina & Cademartori, Davide & Cabot, Pere L. & Barbucci, Antonio, 2021. "Impregnation of microporous SDC scaffold as stable solid oxide cell BSCF-based air electrode," Energy, Elsevier, vol. 237(C).
    • Handle: RePEc:eee:energy:v:237:y:2021:i:c:s036054422101762x
    DOI: 10.1016/j.energy.2021.121514
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    References listed on IDEAS

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    1. Gao, Juntao & Ma, Dan & Zhao, Hui & Li, Qiang & Lü, Zhe & Wei, Bo, 2022. "Synergistically improving electrocatalytic performance and CO2 tolerance of Fe-based cathode catalysts for solid oxide fuel cells," Energy, Elsevier, vol. 252(C).

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