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An optical mechanism for detecting the whole pyrolysis process of oil shale

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  • Zhan, Honglei
  • Wang, Yan
  • Chen, Mengxi
  • Chen, Ru
  • Zhao, Kun
  • Yue, Wenzheng

Abstract

Pyrolysis is one of the most widely applied method for oil shale. Although an accurate exploration of the pyrolysis mechanism of oil shale is of utmost importance to optimize the pyrolysis parameters and decrease energy cost, the typically used pyrolysis techniques fail to provide comprehensive information of entire pyrolysis process. Terahertz time-domain spectroscopy (THz-TDS), a new optical method with different sensitivities to oil, water, gas, and minerals, was used to characterize the physical properties of oil shale’s pyrolysis products The confirmed collected tendency combined with the obvious turning points indicated the four stages during the pyrolysis of oil shale, which solves the acknowledgeable difficulty in identifying the organic decomposition and the mineral reaction. Water and kerogen, which highly absorbed THz waves, were volatized and then decomposed due to the continuous increasing of THz transmittance with THz signal varying by 27.9% and 18.6% from room temperature (∼22 °C) to 500 °C. In particular, the THz signal then decreased by 153%, indicating that the more sensitive calcium oxide crystals in THz range were obtained due to the decomposition of calcite. The THz results were validated by the combination of the material analysis techniques, including thermogravimetric analysis, mass spectrometry, scanning electron microscopy, and energy-dispersive spectrometry. The results proved the ability of this spectroscopic technique to be applied in the key detection of oil shale in the petroleum industry.

Suggested Citation

  • Zhan, Honglei & Wang, Yan & Chen, Mengxi & Chen, Ru & Zhao, Kun & Yue, Wenzheng, 2020. "An optical mechanism for detecting the whole pyrolysis process of oil shale," Energy, Elsevier, vol. 190(C).
  • Handle: RePEc:eee:energy:v:190:y:2020:i:c:s0360544219320389
    DOI: 10.1016/j.energy.2019.116343
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    References listed on IDEAS

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    1. Li, Yi Z. & Wu, Shi X. & Yu, Xiao L. & Bao, Ri M. & Wu, Zhi K. & Wang, Wei & Zhan, Hong L. & Zhao, Kun & Ma, Yue & Wu, Jian X. & Liu, Shao H. & Li, Shu Y., 2017. "Optimization of pyrolysis efficiency based on optical property of semicoke in terahertz region," Energy, Elsevier, vol. 126(C), pages 202-207.
    2. J. David Hughes, 2013. "A reality check on the shale revolution," Nature, Nature, vol. 494(7437), pages 307-308, February.
    3. Yang, Yu & Wang, Quanhai & Lu, Xiaofeng & Li, Jianbo & Liu, Zhuo, 2018. "Combustion behaviors and pollutant emission characteristics of low calorific oil shale and its semi-coke in a lab-scale fluidized bed combustor," Applied Energy, Elsevier, vol. 211(C), pages 631-638.
    4. Zhan, Honglei & Zhao, Kun & Xiao, Lizhi, 2015. "Spectral characterization of the key parameters and elements in coal using terahertz spectroscopy," Energy, Elsevier, vol. 93(P1), pages 1140-1145.
    5. Jing Yang & Javin Hatcherian & Paul C. Hackley & Andrew E. Pomerantz, 2017. "Nanoscale geochemical and geomechanical characterization of organic matter in shale," Nature Communications, Nature, vol. 8(1), pages 1-9, December.
    6. Zhan, Honglei & Chen, Mengxi & Zhao, Kun & Li, Yizhang & Miao, Xinyang & Ye, Haimu & Ma, Yue & Hao, Shijie & Li, Hongfang & Yue, Wenzheng, 2018. "The mechanism of the terahertz spectroscopy for oil shale detection," Energy, Elsevier, vol. 161(C), pages 46-51.
    7. Saif, Tarik & Lin, Qingyang & Gao, Ying & Al-Khulaifi, Yousef & Marone, Federica & Hollis, David & Blunt, Martin J. & Bijeljic, Branko, 2019. "4D in situ synchrotron X-ray tomographic microscopy and laser-based heating study of oil shale pyrolysis," Applied Energy, Elsevier, vol. 235(C), pages 1468-1475.
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    4. Pan, Bin & Yin, Xia & Yang, Zhengru & Ghanizadeh, Amin & Debuhr, Chris & Clarkson, Christopher R. & Gou, Feifei & Zhu, Weiyao & Ju, Yang & Iglauer, Stefan, 2024. "Real-time imaging of oil shale pyrolysis dynamics at nanoscale via environmental scanning electron microscopy," Applied Energy, Elsevier, vol. 363(C).
    5. Popkova, Elena G. & Sergi, Bruno S., 2024. "Energy infrastructure: Investment, sustainability and AI," Resources Policy, Elsevier, vol. 91(C).
    6. Zhan, Honglei & Yang, Qi & Qin, Fankai & Meng, Zhaohui & Chen, Ru & Miao, Xinyang & Zhao, Kun & Yue, Wenzheng, 2022. "Comprehensive preparation and multiscale characterization of kerogen in oil shale," Energy, Elsevier, vol. 252(C).
    7. He, Lu & Ma, Yue & Tan, Ting & Yue, Changtao & Li, Shuyuan & Tang, Xun, 2021. "Mechanisms of sulfur and nitrogen transformation during Longkou oil shale pyrolysis," Energy, Elsevier, vol. 232(C).
    8. Xu, HengYu & Yu, Hao & Fan, JingCun & Xia, Jun & Liu, He & Wu, HengAn, 2022. "Formation mechanism and structural characteristic of pore-networks in shale kerogen during in-situ conversion process," Energy, Elsevier, vol. 242(C).
    9. Kang, Shijie & Sun, Youhong & Qiao, Mingyang & Li, Shengli & Deng, Sunhua & Guo, Wei & Li, Jiasheng & He, Wentong, 2022. "The enhancement on oil shale extraction of FeCl3 catalyst in subcritical water," Energy, Elsevier, vol. 238(PA).
    10. Zhang, Xu & Guo, Wei & Pan, Junfan & Zhu, Chaofan & Deng, Sunhua, 2024. "In-situ pyrolysis of oil shale in pressured semi-closed system: Insights into products characteristics and pyrolysis mechanism," Energy, Elsevier, vol. 286(C).
    11. Dipen Paul & Sushant Malik & Dharmesh K. Mishra & Rushik Hiwale, 2021. "Shale Gas: An Indian Market Perspective," International Journal of Energy Economics and Policy, Econjournals, vol. 11(1), pages 126-136.

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