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Two-step pyrolysis degradation mechanism of oil shale through comprehensive analysis of pyrolysis semi-cokes and pyrolytic gases

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Listed:
  • Zhan, Honglei
  • Qin, Fankai
  • Chen, Sitong
  • Chen, Ru
  • Meng, Zhaohui
  • Miao, Xinyang
  • Zhao, Kun

Abstract

Despite kerogen's importance as organic matter produced from oil shale, its pyrolytic degradation mechanism remains unexplored. As the potential demand for oil shale utilization increases, identifying the physical relationship between pyrolysis degradation and temperature for kerogen becomes all the more important. Here, we determine the variation in the pyrolysis degradation of the Huadian oil shale through comprehensive analysis using terahertz spectroscopy, thermogravimetric analysis, X-ray diffraction, scanning electron microscopy, infrared spectroscopy, and mass spectroscopy. Through the hybrid detection of pyrolysis semi-cokes and pyrolytic gases, we provide a detailed pyrolysis model for oil shale and show that it can be used to predict the essential characteristics that are amenable to experimental validation. Kerogen in oil shale was first depolymerized into asphalt monomer. The macromolecular organic matter (OM) began to decompose and produce CO2, but the OM did not decompose into low-carbon oil and gas. As the temperature continued to rise, the asphalt monomer decomposed into shale oil and shale gas. The OM in the oil shale generated a large amount of oil and gas. Consequently, these results demonstrate the two-step pyrolysis degradation of oil shale, which provides theoretical support for underground in-situ pyrolysis technology and underground oil shale development.

Suggested Citation

  • Zhan, Honglei & Qin, Fankai & Chen, Sitong & Chen, Ru & Meng, Zhaohui & Miao, Xinyang & Zhao, Kun, 2022. "Two-step pyrolysis degradation mechanism of oil shale through comprehensive analysis of pyrolysis semi-cokes and pyrolytic gases," Energy, Elsevier, vol. 241(C).
    • Handle: RePEc:eee:energy:v:241:y:2022:i:c:s0360544221031200
    DOI: 10.1016/j.energy.2021.122871
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    References listed on IDEAS

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    1. Zhan, Honglei & Wang, Yan & Chen, Mengxi & Chen, Ru & Zhao, Kun & Yue, Wenzheng, 2020. "An optical mechanism for detecting the whole pyrolysis process of oil shale," Energy, Elsevier, vol. 190(C).
    2. Jiang, Peng & Meng, Yang & Parvez, Ashak Mahmud & Dong, Xin-yue & Wu, Xin-yun & Xu, Meng-xia & Pang, Cheng Heng & Sun, Cheng-gong & Wu, Tao, 2021. "Influence of co-processing of coal and oil shale on combustion characteristics, kinetics and ash fusion behaviour," Energy, Elsevier, vol. 216(C).
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    4. Li, Yi Z. & Wu, Shi X. & Yu, Xiao L. & Bao, Ri M. & Wu, Zhi K. & Wang, Wei & Zhan, Hong L. & Zhao, Kun & Ma, Yue & Wu, Jian X. & Liu, Shao H. & Li, Shu Y., 2017. "Optimization of pyrolysis efficiency based on optical property of semicoke in terahertz region," Energy, Elsevier, vol. 126(C), pages 202-207.
    5. Yang, Yu & Wang, Quanhai & Lu, Xiaofeng & Li, Jianbo & Liu, Zhuo, 2018. "Combustion behaviors and pollutant emission characteristics of low calorific oil shale and its semi-coke in a lab-scale fluidized bed combustor," Applied Energy, Elsevier, vol. 211(C), pages 631-638.
    6. Zhan, Honglei & Zhao, Kun & Xiao, Lizhi, 2015. "Spectral characterization of the key parameters and elements in coal using terahertz spectroscopy," Energy, Elsevier, vol. 93(P1), pages 1140-1145.
    7. Saif, Tarik & Lin, Qingyang & Gao, Ying & Al-Khulaifi, Yousef & Marone, Federica & Hollis, David & Blunt, Martin J. & Bijeljic, Branko, 2019. "4D in situ synchrotron X-ray tomographic microscopy and laser-based heating study of oil shale pyrolysis," Applied Energy, Elsevier, vol. 235(C), pages 1468-1475.
    8. Zhan, Honglei & Chen, Mengxi & Zhao, Kun & Li, Yizhang & Miao, Xinyang & Ye, Haimu & Ma, Yue & Hao, Shijie & Li, Hongfang & Yue, Wenzheng, 2018. "The mechanism of the terahertz spectroscopy for oil shale detection," Energy, Elsevier, vol. 161(C), pages 46-51.
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    Cited by:

    1. Kang, Shijie & Zhang, Shijing & Wang, Zhendong & Li, Shengli & Zhao, Fangci & Yang, Jie & Zhou, Lingbo & Deng, Yang & Sun, Guidong & Yu, Hongdong, 2023. "Highly efficient catalytic pyrolysis of oil shale by CaCl2 in subcritical water," Energy, Elsevier, vol. 274(C).
    2. Zhan, Honglei & Yang, Qi & Qin, Fankai & Meng, Zhaohui & Chen, Ru & Miao, Xinyang & Zhao, Kun & Yue, Wenzheng, 2022. "Comprehensive preparation and multiscale characterization of kerogen in oil shale," Energy, Elsevier, vol. 252(C).
    3. Xu, Shaotao & Lü, Xiaoshu & Sun, Youhong & Guo, Wei & Li, Qiang & Liu, Lang & Kang, Shijie & Deng, Sunhua, 2023. "Optimization of temperature parameters for the autothermic pyrolysis in-situ conversion process of oil shale," Energy, Elsevier, vol. 264(C).

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