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The novel perovskite-type Ni-doped Sr0.92Y0.08TiO3 as a reforming biogas (CH4+CO2) for H2 production

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  • Kwon, Byeong Wan
  • Oh, Joo Hyeng
  • Kim, Ghun Sik
  • Yoon, Sung Pil
  • Han, Jonghee
  • Nam, Suk Woo
  • Ham, Hyung Chul

Abstract

In this study, novel perovskite-type Sr0.92Y0.08TiO3-based catalysts were investigated for hydrogen production by the dry reforming of biogas (comprising CH4 and CO2). Ni-doped Sr0.92Y0.08TiO3 catalysts with improved catalytic activity were grown using the Pechini method. The prepared catalysts were characterized using X-ray diffraction to check for impurities introduced in the perovskite structure by doping method. The reforming of methane over perovskite-based catalysts has been extensively investigated; however, detailed understanding of the activating catalytic sites under different conditions is still lacking. To understand the details of the activating catalyst mechanism, transmission electron microscopy, temperature-programed reduction, X-ray photoelectron spectroscopic (XPS) analysis were performed under different activating conditions. XPS analysis of 5mol% Ni-doped Sr0.92Y0.08TiO3 revealed that the H2-activated catalyst lost active lattice oxygen sites and Ni sites due to formation of Ni hydroxide. Thus, the H2-activated catalyst has lower catalytic activity than the N2-activated one.

Suggested Citation

  • Kwon, Byeong Wan & Oh, Joo Hyeng & Kim, Ghun Sik & Yoon, Sung Pil & Han, Jonghee & Nam, Suk Woo & Ham, Hyung Chul, 2018. "The novel perovskite-type Ni-doped Sr0.92Y0.08TiO3 as a reforming biogas (CH4+CO2) for H2 production," Applied Energy, Elsevier, vol. 227(C), pages 213-219.
    • Handle: RePEc:eee:appene:v:227:y:2018:i:c:p:213-219
    DOI: 10.1016/j.apenergy.2017.07.105
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