IDEAS home Printed from https://ideas.repec.org/a/eee/appene/v162y2016icp1141-1152.html
   My bibliography  Save this article

Characterization of catalytic partial oxidation of methane with carbon dioxide utilization and excess enthalpy recovery

Author

Listed:
  • Chen, Wei-Hsin
  • Lin, Shih-Cheng

Abstract

The characteristics of catalytic partial oxidation of methane (CPOM) under CO2 addition and excess enthalpy recovery are investigated where a rhodium-based catalyst is employed. The influences of O2/CH4 and CO2/O2 molar ratios, in the ranges of 0.4–0.7 and 0–2, respectively, on CPOM performance are emphasized. The energy efficiency of the Swiss-roll reactor is also studied. The results reveal that the O2/CH4 ratio plays a crucial role in methane conversion, whereas it is insensitive to the CO2/O2 ratio. The H2 contributed by steam reforming is pronounced at higher O2/CH4 ratios; on the other hand, H2 produced from dry reforming is significant at lower O2/CH4 ratios and high CO2/O2 ratios. The H2/CO ratio in the product gas is between 1 and 2, and the values depends on the O2/CH4 and CO2/O2 ratios. Increasing CO2/O2 ratio substantially increases CO2 consumption, but leads to a decrease in CO2 conversion. Within the investigated ranges of O2/CH4 and CO2/O2 ratios, at least 18.2% and up to 77.0% of CO2 in the feed gas is converted to CO. The energy efficiency of the reaction system with considering CH4 conversion is between 83.5% and 89.9%. Overall, CPOM performed at O2/CH4=0.6 is recommended in that it provides higher CH4 conversion, syngas production, CO2 consumption, and system energy efficiency.

Suggested Citation

  • Chen, Wei-Hsin & Lin, Shih-Cheng, 2016. "Characterization of catalytic partial oxidation of methane with carbon dioxide utilization and excess enthalpy recovery," Applied Energy, Elsevier, vol. 162(C), pages 1141-1152.
  • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1141-1152
    DOI: 10.1016/j.apenergy.2015.01.056
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0306261915000720
    Download Restriction: Full text for ScienceDirect subscribers only

    File URL: https://libkey.io/10.1016/j.apenergy.2015.01.056?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Choudhary, Vasant R. & Mondal, Kartick C., 2006. "CO2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over NdCoO3 perovskite-type mixed metal-oxide catalyst," Applied Energy, Elsevier, vol. 83(9), pages 1024-1032, September.
    2. Lu, Shyi-Min, 2015. "A global survey of gas hydrate development and reserves: Specifically in the marine field," Renewable and Sustainable Energy Reviews, Elsevier, vol. 41(C), pages 884-900.
    3. Chen, Wei-Hsin & Chen, Chih-Jung & Hung, Chen-I & Shen, Cheng-Hsien & Hsu, Heng-Wen, 2013. "A comparison of gasification phenomena among raw biomass, torrefied biomass and coal in an entrained-flow reactor," Applied Energy, Elsevier, vol. 112(C), pages 421-430.
    4. Chen, Wei-Hsin & Lin, Bo-Jhih & Lee, How-Ming & Huang, Men-Han, 2012. "One-step synthesis of dimethyl ether from the gas mixture containing CO2 with high space velocity," Applied Energy, Elsevier, vol. 98(C), pages 92-101.
    5. Arab Aboosadi, Z. & Jahanmiri, A.H. & Rahimpour, M.R., 2011. "Optimization of tri-reformer reactor to produce synthesis gas for methanol production using differential evolution (DE) method," Applied Energy, Elsevier, vol. 88(8), pages 2691-2701, August.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Chen, Wei-Hsin & Guo, Yu-Zhi & Chen, Chih-Chun, 2018. "Methanol partial oxidation accompanied by heat recirculation in a Swiss-roll reactor," Applied Energy, Elsevier, vol. 232(C), pages 79-88.
    2. Yu, Tao & Yuan, Qinyuan & Lu, Jianfeng & Ding, Jing & Lu, Yanling, 2017. "Thermochemical storage performances of methane reforming with carbon dioxide in tubular and semi-cavity reactors heated by a solar dish system," Applied Energy, Elsevier, vol. 185(P2), pages 1994-2004.
    3. Ding, Jing & Wang, Yarong & Gu, Rong & Wang, Weilong & Lu, Jianfeng, 2019. "Thermochemical storage performance of methane reforming with carbon dioxide using high temperature slag," Applied Energy, Elsevier, vol. 250(C), pages 1270-1279.
    4. Woo, Seungchul & Kim, Woongil & Lee, Jungkoo & Lee, Kihyung, 2022. "Performance evaluation of the LPG engine applied to catalytic reforming system for producing hydrogen," Applied Energy, Elsevier, vol. 312(C).
    5. Chen, Wei-Hsin & Lin, Shih-Cheng, 2018. "Biogas partial oxidation in a heat recirculation reactor for syngas production and CO2 utilization," Applied Energy, Elsevier, vol. 217(C), pages 113-125.
    6. Luu, Minh Tri & Milani, Dia & Sharma, Manish & Zeaiter, Joseph & Abbas, Ali, 2016. "Model-based analysis of CO2 revalorization for di-methyl ether synthesis driven by solar catalytic reforming," Applied Energy, Elsevier, vol. 177(C), pages 863-878.
    7. Chen, Xuejing & Jiang, Jianguo & Li, Kaimin & Tian, Sicong & Yan, Feng, 2017. "Energy-efficient biogas reforming process to produce syngas: The enhanced methane conversion by O2," Applied Energy, Elsevier, vol. 185(P1), pages 687-697.
    8. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.
    9. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Wei-Hsin & Lin, Shih-Cheng, 2015. "Reaction phenomena of catalytic partial oxidation of methane under the impact of carbon dioxide addition and heat recirculation," Energy, Elsevier, vol. 82(C), pages 206-217.
    2. Gaber, Christian & Demuth, Martin & Prieler, René & Schluckner, Christoph & Schroettner, Hartmuth & Fitzek, Harald & Hochenauer, Christoph, 2019. "Experimental investigation of thermochemical regeneration using oxy-fuel exhaust gases," Applied Energy, Elsevier, vol. 236(C), pages 1115-1124.
    3. Chen, Wei-Hsin & Hsu, Chih-Liang & Wang, Xiao-Dong, 2016. "Thermodynamic approach and comparison of two-step and single step DME (dimethyl ether) syntheses with carbon dioxide utilization," Energy, Elsevier, vol. 109(C), pages 326-340.
    4. Peng Liu & Panpan Lang & Ailing Lu & Yanling Li & Xueqin Li & Tanglei Sun & Yantao Yang & Hui Li & Tingzhou Lei, 2022. "Effect of Evolution of Carbon Structure during Torrefaction in Woody Biomass on Thermal Degradation," IJERPH, MDPI, vol. 19(24), pages 1-11, December.
    5. Walluk, Mark R. & Lin, Jiefeng & Waller, Michael G. & Smith, Daniel F. & Trabold, Thomas A., 2014. "Diesel auto-thermal reforming for solid oxide fuel cell systems: Anode off-gas recycle simulation," Applied Energy, Elsevier, vol. 130(C), pages 94-102.
    6. Liu, H. & Saffaripour, M. & Mellin, P. & Grip, C.-E. & Yang, W. & Blasiak, W., 2014. "A thermodynamic study of hot syngas impurities in steel reheating furnaces – Corrosion and interaction with oxide scales," Energy, Elsevier, vol. 77(C), pages 352-361.
    7. Chung, Wei-Chieh & Chang, Moo-Been, 2016. "Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 13-31.
    8. María Pilar González-Vázquez & Roberto García & Covadonga Pevida & Fernando Rubiera, 2017. "Optimization of a Bubbling Fluidized Bed Plant for Low-Temperature Gasification of Biomass," Energies, MDPI, vol. 10(3), pages 1-16, March.
    9. Glotić, Arnel & Zamuda, Aleš, 2015. "Short-term combined economic and emission hydrothermal optimization by surrogate differential evolution," Applied Energy, Elsevier, vol. 141(C), pages 42-56.
    10. Li, Fenghai & Li, Zhenzhu & Huang, Jiejie & Fang, Yitian, 2014. "Understanding mineral behaviors during anthracite fluidized-bed gasification based on slag characteristics," Applied Energy, Elsevier, vol. 131(C), pages 279-287.
    11. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2017. "Experimental investigation of optimization of well spacing for gas recovery from methane hydrate reservoir in sandy sediment by heat stimulation," Applied Energy, Elsevier, vol. 207(C), pages 562-572.
    12. Rahimpour, Mohammad Reza & Jafari, Mitra & Iranshahi, Davood, 2013. "Progress in catalytic naphtha reforming process: A review," Applied Energy, Elsevier, vol. 109(C), pages 79-93.
    13. Chen, Wei-Hsin & Peng, Jianghong & Bi, Xiaotao T., 2015. "A state-of-the-art review of biomass torrefaction, densification and applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 44(C), pages 847-866.
    14. Wang, Lijun & Du, Xiaocheng & Xu, Lingfeng & Sun, Jiajun, 2020. "Numerical simulation of biomass gasification process and distribution mode in two-stage entrained flow gasifier," Renewable Energy, Elsevier, vol. 162(C), pages 1065-1075.
    15. Nguyen, Nhut M. & Alobaid, Falah & May, Jan & Peters, Jens & Epple, Bernd, 2020. "Experimental study on steam gasification of torrefied woodchips in a bubbling fluidized bed reactor," Energy, Elsevier, vol. 202(C).
    16. Baloyi, J. & Bello-Ochende, T. & Meyer, J.P., 2014. "Thermodynamic optimisation and computational analysis of irreversibilities in a small-scale wood-fired circulating fluidised bed adiabatic combustor," Energy, Elsevier, vol. 70(C), pages 653-663.
    17. Chaiwatanodom, Paphonwit & Vivanpatarakij, Supawat & Assabumrungrat, Suttichai, 2014. "Thermodynamic analysis of biomass gasification with CO2 recycle for synthesis gas production," Applied Energy, Elsevier, vol. 114(C), pages 10-17.
    18. Chen, Yun-Chun & Chen, Wei-Hsin & Lin, Bo-Jhih & Chang, Jo-Shu & Ong, Hwai Chyuan, 2016. "Impact of torrefaction on the composition, structure and reactivity of a microalga residue," Applied Energy, Elsevier, vol. 181(C), pages 110-119.
    19. Pashchenko, Dmitry, 2018. "First law energy analysis of thermochemical waste-heat recuperation by steam methane reforming," Energy, Elsevier, vol. 143(C), pages 478-487.
    20. Wang, Yi & Feng, Jing-Chun & Li, Xiao-Sen & Zhang, Yu, 2016. "Experimental and modeling analyses of scaling criteria for methane hydrate dissociation in sediment by depressurization," Applied Energy, Elsevier, vol. 181(C), pages 299-309.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1141-1152. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/405891/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.