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High temperature energy storage performances of methane reforming with carbon dioxide in a tubular packed reactor

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  • Lu, Jianfeng
  • Chen, Yuan
  • Ding, Jing
  • Wang, Weilong

Abstract

High temperature heat transfer and energy storage performances of methane reforming with carbon dioxide in tubular packed reactor are investigated under different operating conditions. Experimental results show that the methane reforming in tubular packed reactor can efficiently store high temperature thermal energy, and the sensible heat and heat loss besides thermochemical energy storage play important role in the total energy storage process. When the operating temperature is increased, the thermochemical storage efficiency first increases for methane conversion rising and then decreases for heat loss rising. As the operating temperate is 800°C, the methane conversion is 79.6%, and the thermochemical storage efficiency and total energy efficiency can be higher than 47% and 70%. According to the experimental system, the flow and reaction model of methane reforming is established using the laminar finite-rate model and Arrhenius expression, and the simulated methane conversion and energy storage efficiency fit with experimental data. Along the flow direction, the fluid temperature in the catalyst bed first decreases because of the endothermic reaction and then increases for the heat transfer from reactor wall. As a conclusion, the maximum thermochemical storage efficiency will be obtained under optimal operating temperature and optimal flow rate, and the total energy efficiency can be increased by the increase of bed conductivity and decrease of heat loss coefficient.

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  • Lu, Jianfeng & Chen, Yuan & Ding, Jing & Wang, Weilong, 2016. "High temperature energy storage performances of methane reforming with carbon dioxide in a tubular packed reactor," Applied Energy, Elsevier, vol. 162(C), pages 1473-1482.
  • Handle: RePEc:eee:appene:v:162:y:2016:i:c:p:1473-1482
    DOI: 10.1016/j.apenergy.2015.03.140
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    Cited by:

    1. Yu, Tao & Yuan, Qinyuan & Lu, Jianfeng & Ding, Jing & Lu, Yanling, 2017. "Thermochemical storage performances of methane reforming with carbon dioxide in tubular and semi-cavity reactors heated by a solar dish system," Applied Energy, Elsevier, vol. 185(P2), pages 1994-2004.
    2. Baoping Gong & Hao Cheng & Yongjin Feng & Xiaofang Luo & Long Wang & Xiaoyu Wang, 2021. "Effect of Pebble Size Distribution and Wall Effect on Inner Packing Structure and Contact Force Distribution in Tritium Breeder Pebble Bed," Energies, MDPI, vol. 14(2), pages 1-22, January.
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    5. Chen, Xue & Wang, Fuqiang & Yan, Xuewei & Han, Yafen & Cheng, Ziming & Jie, Zhu, 2018. "Thermochemical performance of solar driven CO2 reforming of methane in volumetric reactor with gradual foam structure," Energy, Elsevier, vol. 151(C), pages 545-555.
    6. Hu, Yingxue & Yang, Jian & Wang, Jingyu & Wang, Qiuwang, 2018. "Investigation of hydrodynamic and heat transfer performances in grille-sphere composite pebble beds with DEM-CFD-Taguchi method," Energy, Elsevier, vol. 155(C), pages 909-920.
    7. Wang, Fuqiang & Shi, Xuhang & Zhang, Chuanxin & Cheng, Ziming & Chen, Xue, 2020. "Effects of non-uniform porosity on thermochemical performance of solar driven methane reforming," Energy, Elsevier, vol. 191(C).
    8. Liu, Xianglei & Cheng, Bo & Zhu, Qibin & Gao, Ke & Sun, Nan & Tian, Cheng & Wang, Jiaqi & Zheng, Hangbin & Wang, Xinrui & Dang, Chunzhuo & Xuan, Yimin, 2022. "Highly efficient solar-driven CO2 reforming of methane via concave foam reactors," Energy, Elsevier, vol. 261(PB).
    9. Jin, Jian & Wei, Xin & Liu, Mingkai & Yu, Yuhang & Li, Wenjia & Kong, Hui & Hao, Yong, 2018. "A solar methane reforming reactor design with enhanced efficiency," Applied Energy, Elsevier, vol. 226(C), pages 797-807.
    10. Lu, Yi Ran & Nikrityuk, Petr, 2018. "A fixed-bed reactor for energy storage in chemicals (E2C): Proof of concept," Applied Energy, Elsevier, vol. 228(C), pages 593-607.
    11. von Storch, Henrik & Roeb, Martin & Stadler, Hannes & Sattler, Christian & Bardow, André & Hoffschmidt, Bernhard, 2016. "On the assessment of renewable industrial processes: Case study for solar co-production of methanol and power," Applied Energy, Elsevier, vol. 183(C), pages 121-132.
    12. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    13. Gaber, Christian & Demuth, Martin & Prieler, René & Schluckner, Christoph & Schroettner, Hartmuth & Fitzek, Harald & Hochenauer, Christoph, 2019. "Experimental investigation of thermochemical regeneration using oxy-fuel exhaust gases," Applied Energy, Elsevier, vol. 236(C), pages 1115-1124.
    14. Korba, David & Huang, Wei & Randhir, Kelvin & Petrasch, Joerg & Klausner, James & AuYeung, Nick & Li, Like, 2022. "A continuum model for heat and mass transfer in moving-bed reactors for thermochemical energy storage," Applied Energy, Elsevier, vol. 313(C).
    15. Wang, Jingyu & Yang, Jian & Cheng, Zhilong & Liu, Yan & Chen, Yitung & Wang, Qiuwang, 2018. "Experimental and numerical study on pressure drop and heat transfer performance of grille-sphere composite structured packed bed," Applied Energy, Elsevier, vol. 227(C), pages 719-730.
    16. Shi, Xuhang & Song, Jintao & Cheng, Ziming & Liang, Huaxu & Dong, Yan & Wang, Fuqiang & Zhang, Wenjing, 2023. "Radiative intensity regulation to match energy conversion on demand in solar methane dry reforming to improve solar to fuel conversion efficiency," Renewable Energy, Elsevier, vol. 207(C), pages 436-446.

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