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Conversion of methane by CO2+H2O+CH4 plasma

Author

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  • Rutberg, Philip G.
  • Kuznetsov, Vadim A.
  • Popov, Victor E.
  • Popov, Sergey D.
  • Surov, Alexander V.
  • Subbotin, Dmitry I.
  • Bratsev, Alexander N.

Abstract

A promising method of methane conversion by thermal plasma is presented. It allows syngas production with a set H2/CO ratio of ∼2.1 and with a ∼95.2% H2+CO content. In comparison with other plasma methods, it differs in its high methane conversion level (91–98.3%), low energy consumption (31.8–35.9MJ/kg) of converted methane and high selectivity on H2 and CO. The influence of energy consumption and oxidizer excess on the key parameters of the process is studied. It is found that with a weak influence of heat losses and a volumetric flow of thermal energy (∼1MW/m3), the optimum energy consumption is approximately 25.5–27.1MJ/kg of injected methane and the optimum excess of oxidizer is 0–10%. The principal cause of the differences in experimental and calculated values is the wall influence (heat losses). The economic efficiency by combining the method and Fischer–Tropsch synthesis is estimated for the USA, and the profits of end-product sales have exceeded the expenses by ∼67%.

Suggested Citation

  • Rutberg, Philip G. & Kuznetsov, Vadim A. & Popov, Victor E. & Popov, Sergey D. & Surov, Alexander V. & Subbotin, Dmitry I. & Bratsev, Alexander N., 2015. "Conversion of methane by CO2+H2O+CH4 plasma," Applied Energy, Elsevier, vol. 148(C), pages 159-168.
    • Handle: RePEc:eee:appene:v:148:y:2015:i:c:p:159-168
    DOI: 10.1016/j.apenergy.2015.02.087
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    References listed on IDEAS

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    1. Ding, Mingyue & Yang, Yong & Li, Yongwang & Wang, Tiejun & Ma, Longlong & Wu, Chuangzhi, 2013. "Impact of H2/CO ratios on phase and performance of Mn-modified Fe-based Fischer Tropsch synthesis catalyst," Applied Energy, Elsevier, vol. 112(C), pages 1241-1246.
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    1. Wang, Xiaoling & Gao, Yuan & Zhang, Shuai & Sun, Hao & Li, Jie & Shao, Tao, 2019. "Nanosecond pulsed plasma assisted dry reforming of CH4: The effect of plasma operating parameters," Applied Energy, Elsevier, vol. 243(C), pages 132-144.
    2. Gao, Yuan & Zhang, Shuai & Sun, Hao & Wang, Ruixue & Tu, Xin & Shao, Tao, 2018. "Highly efficient conversion of methane using microsecond and nanosecond pulsed spark discharges," Applied Energy, Elsevier, vol. 226(C), pages 534-545.
    3. Khalifeh, Omid & Mosallanejad, Amin & Taghvaei, Hamed & Rahimpour, Mohammad Reza & Shariati, Alireza, 2016. "Decomposition of methane to hydrogen using nanosecond pulsed plasma reactor with different active volumes, voltages and frequencies," Applied Energy, Elsevier, vol. 169(C), pages 585-596.
    4. Fan, Yongsheng & Zhao, Weidong & Shao, Shanshan & Cai, Yixi & Chen, Yuwei & Jin, Lizhu, 2018. "Promotion of the vapors from biomass vacuum pyrolysis for biofuels under Non-thermal Plasma Synergistic Catalysis (NPSC) system," Energy, Elsevier, vol. 142(C), pages 462-472.
    5. Rincón, R. & Muñoz, J. & Morales-Calero, F.J. & Orejas, J. & Calzada, M.D., 2021. "Assessment of two atmospheric-pressure microwave plasma sources for H2 production from ethanol decomposition," Applied Energy, Elsevier, vol. 294(C).
    6. Wu, Angjian & Li, Xiaodong & Yan, Jianhua & Yang, Jian & Du, Changming & Zhu, Fengsen & Qian, Jinyuan, 2017. "Co-generation of hydrogen and carbon aerosol from coalbed methane surrogate using rotating gliding arc plasma," Applied Energy, Elsevier, vol. 195(C), pages 67-79.

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