IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v82y2015icp206-217.html
   My bibliography  Save this article

Reaction phenomena of catalytic partial oxidation of methane under the impact of carbon dioxide addition and heat recirculation

Author

Listed:
  • Chen, Wei-Hsin
  • Lin, Shih-Cheng

Abstract

The reaction phenomena of CPOM (catalytic partial oxidation of methane) in a Swiss-roll reactor are studied numerically where a rhodium-based catalyst bed is embedded at the center of the reactor. CO2 is added into the feed gas and excess enthalpy recovery is performed to evaluate their influences on CPOM performance. In the study, the mole ratio of O2 to CH4 (O2/CH4 ratio) is fixed at 0.5 and the mole ratio of CO2 to O2 (CO2/O2 ratio) is in the range of 0–2. The results reveal that CO2 addition into the influent has a slight effect on methane combustion, but significantly enhances dry reforming and suppresses steam reforming. The reaction extents of steam reforming and dry reforming in CPOM without heat recovery and CO2 addition are in a comparable state. Once CO2 is added into the feed gas, the dry reforming is enhanced, thereby dominating CH4 consumption. Compared to the reactor without excess enthalpy recovery, heat recirculation drastically increases the maximum reaction temperature and CH4 conversion in the catalyst bed; it also intensifies the H2 selectivity, H2 yield, CO2 conversion, and syngas production rate. The predictions indicate that the heat recirculation is able to improve the syngas formation up to 45%.

Suggested Citation

  • Chen, Wei-Hsin & Lin, Shih-Cheng, 2015. "Reaction phenomena of catalytic partial oxidation of methane under the impact of carbon dioxide addition and heat recirculation," Energy, Elsevier, vol. 82(C), pages 206-217.
    • Handle: RePEc:eee:energy:v:82:y:2015:i:c:p:206-217
    DOI: 10.1016/j.energy.2015.01.031
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S036054421500050X
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2015.01.031?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Choudhary, Vasant R. & Mondal, Kartick C., 2006. "CO2 reforming of methane combined with steam reforming or partial oxidation of methane to syngas over NdCoO3 perovskite-type mixed metal-oxide catalyst," Applied Energy, Elsevier, vol. 83(9), pages 1024-1032, September.
    2. Chen, Wei-Hsin & Lin, Bo-Jhih & Lee, How-Ming & Huang, Men-Han, 2012. "One-step synthesis of dimethyl ether from the gas mixture containing CO2 with high space velocity," Applied Energy, Elsevier, vol. 98(C), pages 92-101.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Wan, Jianlong & Fan, Aiwu & Yao, Hong & Liu, Wei, 2016. "Experimental investigation and numerical analysis on the blow-off limits of premixed CH4/air flames in a mesoscale bluff-body combustor," Energy, Elsevier, vol. 113(C), pages 193-203.
    2. Chein, Rei-Yu & Lu, Cheng-Yang & Chen, Wei-Hsin, 2022. "Syngas production via chemical looping reforming using methane-based feed and NiO/Al2O3 oxygen carrier," Energy, Elsevier, vol. 250(C).
    3. Chen, Wei-Hsin & Tsai, Ching-Wei & Lin, Yu-Li, 2017. "Numerical studies of the influences of bypass on hydrogen separation in a multichannel Pd membrane system," Renewable Energy, Elsevier, vol. 104(C), pages 259-270.
    4. Wan, Jianlong & Xu, Zuwei & Zhao, Haibo, 2018. "Methane/air premixed flame topology structure in a mesoscale combustor with a plate flame holder and preheating channels," Energy, Elsevier, vol. 165(PB), pages 802-811.
    5. Chen, Wei-Hsin & Lin, Shih-Cheng, 2018. "Biogas partial oxidation in a heat recirculation reactor for syngas production and CO2 utilization," Applied Energy, Elsevier, vol. 217(C), pages 113-125.
    6. Wang, Yuqing & Zeng, Hongyu & Shi, Yixiang & Cao, Tianyu & Cai, Ningsheng & Ye, Xiaofeng & Wang, Shaorong, 2016. "Power and heat co-generation by micro-tubular flame fuel cell on a porous media burner," Energy, Elsevier, vol. 109(C), pages 117-123.
    7. Wan, Jianlong & Fan, Aiwu & Yao, Hong & Liu, Wei, 2015. "Effect of pressure on the blow-off limits of premixed CH4/air flames in a mesoscale cavity-combustor," Energy, Elsevier, vol. 91(C), pages 102-109.
    8. Chen, Wei-Hsin & Li, Shu-Cheng & Lim, Steven & Chen, Zih-Yu & Juan, Joon Ching, 2021. "Reaction and hydrogen production phenomena of ethanol steam reforming in a catalytic membrane reactor," Energy, Elsevier, vol. 220(C).
    9. Siang, T.J. & Jalil, A.A. & Abdulrasheed, A.A. & Hambali, H.U. & Nabgan, Walid, 2020. "Thermodynamic equilibrium study of altering methane partial oxidation for Fischer–Tropsch synfuel production," Energy, Elsevier, vol. 198(C).
    10. Chen, Wei-Hsin & Guo, Yu-Zhi & Chen, Chih-Chun, 2018. "Methanol partial oxidation accompanied by heat recirculation in a Swiss-roll reactor," Applied Energy, Elsevier, vol. 232(C), pages 79-88.
    11. Ray, Debjyoti & Nepak, Devadutta & Vinodkumar, T. & Subrahmanyam, Ch., 2019. "g-C3N4 promoted DBD plasma assisted dry reforming of methane," Energy, Elsevier, vol. 183(C), pages 630-638.
    12. Wachter, Philipp & Gaber, Christian & Demuth, Martin & Hochenauer, Christoph, 2020. "Experimental investigation of tri-reforming on a stationary, recuperative TCR-reformer applied to an oxy-fuel combustion of natural gas, using a Ni-catalyst," Energy, Elsevier, vol. 212(C).
    13. Wan, Jianlong & Zhao, Haibo, 2017. "Dynamics of premixed CH4/air flames in a micro combustor with a plate flame holder and preheating channels," Energy, Elsevier, vol. 139(C), pages 366-379.
    14. Peng, Qingguo & Yang, Wenming & E, Jiaqiang & Li, Shaobo & Li, Zhenwei & Xu, Hongpeng & Fu, Guang, 2021. "Effects of propane addition and burner scale on the combustion characteristics and working performance," Applied Energy, Elsevier, vol. 285(C).
    15. Wan, Jianlong & Zhao, Haibo, 2018. "Thermal performance of solid walls in a mesoscale combustor with a plate flame holder and preheating channels," Energy, Elsevier, vol. 157(C), pages 448-459.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Wei-Hsin & Lin, Shih-Cheng, 2016. "Characterization of catalytic partial oxidation of methane with carbon dioxide utilization and excess enthalpy recovery," Applied Energy, Elsevier, vol. 162(C), pages 1141-1152.
    2. Chen, Wei-Hsin & Hsu, Chih-Liang & Wang, Xiao-Dong, 2016. "Thermodynamic approach and comparison of two-step and single step DME (dimethyl ether) syntheses with carbon dioxide utilization," Energy, Elsevier, vol. 109(C), pages 326-340.
    3. Walluk, Mark R. & Lin, Jiefeng & Waller, Michael G. & Smith, Daniel F. & Trabold, Thomas A., 2014. "Diesel auto-thermal reforming for solid oxide fuel cell systems: Anode off-gas recycle simulation," Applied Energy, Elsevier, vol. 130(C), pages 94-102.
    4. Vadikkeettil, Yugesh & Subramaniam, Yugeswaran & Murugan, Ramaswamy & Ananthapadmanabhan, P.V. & Mostaghimi, Javad & Pershin, Larry & Batiot-Dupeyrat, Catherine & Kobayashi, Yasukazu, 2022. "Plasma assisted decomposition and reforming of greenhouse gases: A review of current status and emerging trends," Renewable and Sustainable Energy Reviews, Elsevier, vol. 161(C).
    5. Chung, Wei-Chieh & Chang, Moo-Been, 2016. "Review of catalysis and plasma performance on dry reforming of CH4 and possible synergistic effects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 62(C), pages 13-31.
    6. Li, Chunlin & Xu, Hengyong & Hou, Shoufu & Sun, Jian & Meng, Fanqiong & Ma, Junguo & Tsubaki, Noritatsu, 2013. "SiC foam monolith catalyst for pressurized adiabatic methane reforming," Applied Energy, Elsevier, vol. 107(C), pages 297-303.
    7. Lu, Jianfeng & Chen, Yuan & Ding, Jing & Wang, Weilong, 2016. "High temperature energy storage performances of methane reforming with carbon dioxide in a tubular packed reactor," Applied Energy, Elsevier, vol. 162(C), pages 1473-1482.
    8. Rutberg, Philip G. & Kuznetsov, Vadim A. & Popov, Victor E. & Popov, Sergey D. & Surov, Alexander V. & Subbotin, Dmitry I. & Bratsev, Alexander N., 2015. "Conversion of methane by CO2+H2O+CH4 plasma," Applied Energy, Elsevier, vol. 148(C), pages 159-168.
    9. Jalali, Ramin & Rezaei, Mehran & Nematollahi, Behzad & Baghalha, Morteza, 2020. "Preparation of Ni/MeAl2O4-MgAl2O4 (Me=Fe, Co, Ni, Cu, Zn, Mg) nanocatalysts for the syngas production via combined dry reforming and partial oxidation of methane," Renewable Energy, Elsevier, vol. 149(C), pages 1053-1067.
    10. Jang, Won-Jun & Jeong, Dae-Woon & Shim, Jae-Oh & Kim, Hak-Min & Roh, Hyun-Seog & Son, In Hyuk & Lee, Seung Jae, 2016. "Combined steam and carbon dioxide reforming of methane and side reactions: Thermodynamic equilibrium analysis and experimental application," Applied Energy, Elsevier, vol. 173(C), pages 80-91.
    11. Luu, Minh Tri & Milani, Dia & Sharma, Manish & Zeaiter, Joseph & Abbas, Ali, 2016. "Model-based analysis of CO2 revalorization for di-methyl ether synthesis driven by solar catalytic reforming," Applied Energy, Elsevier, vol. 177(C), pages 863-878.
    12. Arab Aboosadi, Z. & Jahanmiri, A.H. & Rahimpour, M.R., 2011. "Optimization of tri-reformer reactor to produce synthesis gas for methanol production using differential evolution (DE) method," Applied Energy, Elsevier, vol. 88(8), pages 2691-2701, August.
    13. Chen, Wei-Hsin & Hsia, Ming-Hsien & Chi, Yen-Hsun & Lin, Yu-Li & Yang, Chang-Chung, 2014. "Polarization phenomena of hydrogen-rich gas in high-permeance Pd and Pd–Cu membrane tubes," Applied Energy, Elsevier, vol. 113(C), pages 41-50.
    14. Pashchenko, Dmitry, 2018. "First law energy analysis of thermochemical waste-heat recuperation by steam methane reforming," Energy, Elsevier, vol. 143(C), pages 478-487.
    15. Chen, Xuejing & Jiang, Jianguo & Li, Kaimin & Tian, Sicong & Yan, Feng, 2017. "Energy-efficient biogas reforming process to produce syngas: The enhanced methane conversion by O2," Applied Energy, Elsevier, vol. 185(P1), pages 687-697.
    16. Enbin Liu & Xudong Lu & Daocheng Wang, 2023. "A Systematic Review of Carbon Capture, Utilization and Storage: Status, Progress and Challenges," Energies, MDPI, vol. 16(6), pages 1-48, March.
    17. Zuo, Hongmei & Mao, Dongsen & Guo, Xiaoming & Yu, Jun, 2018. "Highly efficient synthesis of dimethyl ether directly from biomass-derived gas over Li-modified Cu-ZnO-Al2O3/HZSM-5 hybrid catalyst," Renewable Energy, Elsevier, vol. 116(PA), pages 38-47.
    18. Bakhtyari, Ali & Bardool, Roghayeh & Rahimpour, Mohammad Reza & Iulianelli, Adolfo, 2021. "Dehydration of bio-alcohols in an enhanced membrane-assisted reactor: A rigorous sensitivity analysis and multi-objective optimization," Renewable Energy, Elsevier, vol. 177(C), pages 519-543.
    19. Das, Satyen Kumar & Mohanty, Pravakar & Majhi, Sachchit & Pant, Kamal Kishore, 2013. "CO-hydrogenation over silica supported iron based catalysts: Influence of potassium loading," Applied Energy, Elsevier, vol. 111(C), pages 267-276.
    20. Gaber, Christian & Demuth, Martin & Prieler, René & Schluckner, Christoph & Schroettner, Hartmuth & Fitzek, Harald & Hochenauer, Christoph, 2019. "Experimental investigation of thermochemical regeneration using oxy-fuel exhaust gases," Applied Energy, Elsevier, vol. 236(C), pages 1115-1124.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:82:y:2015:i:c:p:206-217. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.