IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v11y2018i10p2537-d171629.html
   My bibliography  Save this article

(Solar) Mixed Reforming of Methane: Potential and Limits in Utilizing CO 2 as Feedstock for Syngas Production—A Thermodynamic Analysis

Author

Listed:
  • Henrik Von Storch

    (Solar Chemical Engineering, Institute of Solar Research, German Aerospace Center (DLR), 51147 Leitung Köln-Porz, Germany)

  • Sonja Becker-Hardt

    (Solar Chemical Engineering, Institute of Solar Research, German Aerospace Center (DLR), 51147 Leitung Köln-Porz, Germany)

  • Christian Sattler

    (Solar Chemical Engineering, Institute of Solar Research, German Aerospace Center (DLR), 51147 Leitung Köln-Porz, Germany)

Abstract

The reforming of natural gas with steam and CO 2 is commonly referred to as mixed reforming and considered a promising route to utilize CO 2 in the production of synthetic fuels and base chemicals such as methanol. In the present study, the mixed reforming reaction is assessed regarding its potential to effectively utilize CO 2 in such processes based on simple thermodynamic models. Requirements for the mixed reforming reactions based on process considerations are defined. These are the avoidance of carbon formation in the reactor, high conversion of the valuable inlet streams CH 4 and CO 2 as well as a suitable syngas composition for subsequent synthesis. The syngas composition is evaluated based on the module M = ( z H 2 − z CO 2 ) / ( z CO 2 + z CO ) , which should assume a value close to 2. A large number of different configurations regarding CO 2 /H 2 O/CH 4 at the reactor inlet, operating pressure and outlet temperature are simulated and evaluated according to the defined requirements. The results show that the actual potential of the mixed reforming reaction to utilize CO 2 as feedstock for fuels and methanol is limited to approximately 0.35 CO 2 /CH 4 , which is significantly lower than suggested in literature. At 900 °C and 7 bar at the reactor outlet, which is seen suitable for solar reforming, a ratio of H 2 O/CH 4 of 1.4 can be set and the resulting value of M is 1.92 (CO 2 /CO/H 2 = 0.07/0.4/1).

Suggested Citation

  • Henrik Von Storch & Sonja Becker-Hardt & Christian Sattler, 2018. "(Solar) Mixed Reforming of Methane: Potential and Limits in Utilizing CO 2 as Feedstock for Syngas Production—A Thermodynamic Analysis," Energies, MDPI, vol. 11(10), pages 1-14, September.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:10:p:2537-:d:171629
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/11/10/2537/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/11/10/2537/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Nancy Eloísa Rodríguez-Olalde & Erick Alejandro Mendoza-Chávez & Agustín Jaime Castro-Montoya & Jaime Saucedo-Luna & Rafael Maya-Yescas & José Guadalupe Rutiaga-Quiñones & José María Ponce Ortega, 2015. "Simulation of Syngas Production from Lignin Using Guaiacol as a Model Compound," Energies, MDPI, vol. 8(7), pages 1-10, June.
    2. Agrafiotis, Christos & von Storch, Henrik & Roeb, Martin & Sattler, Christian, 2014. "Solar thermal reforming of methane feedstocks for hydrogen and syngas production—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 656-682.
    3. Rei-Yu Chein & Wen-Hwai Hsu, 2018. "Analysis of Syngas Production from Biogas via the Tri-Reforming Process," Energies, MDPI, vol. 11(5), pages 1-18, April.
    4. Chein, Rei-Yu & Wang, Chien-Yu & Yu, Ching-Tsung, 2017. "Parametric study on catalytic tri-reforming of methane for syngas production," Energy, Elsevier, vol. 118(C), pages 1-17.
    5. Blumberg, Timo & Morosuk, Tatiana & Tsatsaronis, George, 2017. "Exergy-based evaluation of methanol production from natural gas with CO2 utilization," Energy, Elsevier, vol. 141(C), pages 2528-2539.
    6. Jang, Won-Jun & Jeong, Dae-Woon & Shim, Jae-Oh & Kim, Hak-Min & Roh, Hyun-Seog & Son, In Hyuk & Lee, Seung Jae, 2016. "Combined steam and carbon dioxide reforming of methane and side reactions: Thermodynamic equilibrium analysis and experimental application," Applied Energy, Elsevier, vol. 173(C), pages 80-91.
    7. von Storch, Henrik & Roeb, Martin & Stadler, Hannes & Sattler, Christian & Bardow, André & Hoffschmidt, Bernhard, 2016. "On the assessment of renewable industrial processes: Case study for solar co-production of methanol and power," Applied Energy, Elsevier, vol. 183(C), pages 121-132.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Mattia Boscherini & Alba Storione & Matteo Minelli & Francesco Miccio & Ferruccio Doghieri, 2023. "New Perspectives on Catalytic Hydrogen Production by the Reforming, Partial Oxidation and Decomposition of Methane and Biogas," Energies, MDPI, vol. 16(17), pages 1-33, September.
    2. Tooba Qureshi & Majeda Khraisheh & Fares Almomani, 2023. "Cost and Heat Integration Analysis for CO 2 Removal Using Imidazolium-Based Ionic Liquid-ASPEN PLUS Modelling Study," Sustainability, MDPI, vol. 15(4), pages 1-23, February.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Chen, Xue & Wang, Fuqiang & Yan, Xuewei & Han, Yafen & Cheng, Ziming & Jie, Zhu, 2018. "Thermochemical performance of solar driven CO2 reforming of methane in volumetric reactor with gradual foam structure," Energy, Elsevier, vol. 151(C), pages 545-555.
    2. Gaber, Christian & Demuth, Martin & Prieler, René & Schluckner, Christoph & Schroettner, Hartmuth & Fitzek, Harald & Hochenauer, Christoph, 2019. "Experimental investigation of thermochemical regeneration using oxy-fuel exhaust gases," Applied Energy, Elsevier, vol. 236(C), pages 1115-1124.
    3. Park, Min-Ju & Kim, Hak-Min & Gu, Yun-Jeong & Jeong, Dae-Woon, 2023. "Optimization of biogas-reforming conditions considering carbon formation, hydrogen production, and energy efficiencies," Energy, Elsevier, vol. 265(C).
    4. Robert Kaczmarczyk, 2021. "Thermodynamic Analysis of the Effect of Green Hydrogen Addition to a Fuel Mixture on the Steam Methane Reforming Process," Energies, MDPI, vol. 14(20), pages 1-14, October.
    5. Jiang, Dongyue & Yang, Wenming & Tang, Aikun, 2016. "A refractory selective solar absorber for high performance thermochemical steam reforming," Applied Energy, Elsevier, vol. 170(C), pages 286-292.
    6. Kwon, Gihoon & Tsang, Daniel C.W. & Oh, Jeong-Ik & Kwon, Eilhann E. & Song, Hocheol, 2019. "Pyrolysis of aquatic carbohydrates using CO2 as reactive gas medium: A case study of chitin," Energy, Elsevier, vol. 177(C), pages 136-143.
    7. Shah, Vedant & Cheng, Zhuo & Baser, Deven S. & Fan, Jonathan A. & Fan, Liang-Shih, 2021. "Highly Selective Production of Syngas from Chemical Looping Reforming of Methane with CO2 Utilization on MgO-supported Calcium Ferrite Redox Materials," Applied Energy, Elsevier, vol. 282(PA).
    8. Rawan Hakawati & Beatrice Smyth & Helen Daly & Geoffrey McCullough & David Rooney, 2019. "Is the Fischer-Tropsch Conversion of Biogas-Derived Syngas to Liquid Fuels Feasible at Atmospheric Pressure?," Energies, MDPI, vol. 12(6), pages 1-28, March.
    9. Zhu, Qibin & Xuan, Yimin & Liu, Xianglei & Yang, Lili & Lian, Wenlei & Zhang, Jin, 2020. "A 130 kWe solar simulator with tunable ultra-high flux and characterization using direct multiple lamps mapping," Applied Energy, Elsevier, vol. 270(C).
    10. Danbee Han & Yunji Kim & Wonjun Cho & Youngsoon Baek, 2020. "Effect of Oxidants on Syngas Synthesis from Biogas over 3 wt % Ni-Ce-MgO-ZrO 2 /Al 2 O 3 Catalyst," Energies, MDPI, vol. 13(2), pages 1-14, January.
    11. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    12. Mattia Boscherini & Alba Storione & Matteo Minelli & Francesco Miccio & Ferruccio Doghieri, 2023. "New Perspectives on Catalytic Hydrogen Production by the Reforming, Partial Oxidation and Decomposition of Methane and Biogas," Energies, MDPI, vol. 16(17), pages 1-33, September.
    13. Allouhi, A. & Agrouaz, Y. & Benzakour Amine, Mohammed & Rehman, S. & Buker, M.S. & Kousksou, T. & Jamil, A. & Benbassou, A., 2017. "Design optimization of a multi-temperature solar thermal heating system for an industrial process," Applied Energy, Elsevier, vol. 206(C), pages 382-392.
    14. Yih-Hang Chen & David Shan-Hill Wong & Ya-Chien Chen & Chao-Min Chang & Hsuan Chang, 2019. "Design and Performance Comparison of Methanol Production Processes with Carbon Dioxide Utilization," Energies, MDPI, vol. 12(22), pages 1-18, November.
    15. Chein, Rei-Yu & Lu, Cheng-Yang & Chen, Wei-Hsin, 2022. "Syngas production via chemical looping reforming using methane-based feed and NiO/Al2O3 oxygen carrier," Energy, Elsevier, vol. 250(C).
    16. Jin, Jian & Wang, Hongsheng & Shen, Yili & Shu, Ziyun & Liu, Taixiu & Li, Wenjia, 2023. "Thermodynamic analysis of methane to methanol through a two-step process driven by concentrated solar energy," Energy, Elsevier, vol. 273(C).
    17. Villafán-Vidales, H.I. & Arancibia-Bulnes, C.A. & Riveros-Rosas, D. & Romero-Paredes, H. & Estrada, C.A., 2017. "An overview of the solar thermochemical processes for hydrogen and syngas production: Reactors, and facilities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 894-908.
    18. Deng, Yimin & Li, Shuo & Appels, Lise & Zhang, Huili & Sweygers, Nick & Baeyens, Jan & Dewil, Raf, 2023. "Steam reforming of ethanol by non-noble metal catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 175(C).
    19. Nakyai, Teeranun & Patcharavorachot, Yaneeporn & Arpornwichanop, Amornchai & Saebea, Dang, 2020. "Comparative exergoeconomic analysis of indirect and direct bio-dimethyl ether syntheses based on air-steam biomass gasification with CO2 utilization," Energy, Elsevier, vol. 209(C).
    20. Ouyang, Tiancheng & Xu, Jisong & Qin, Peijia & Cheng, Liang, 2022. "Utilizing flue gas low-grade waste heat and furnace excess heat to produce syngas and sulfuric acid recovery in coal-fired power plant," Energy, Elsevier, vol. 258(C).

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:11:y:2018:i:10:p:2537-:d:171629. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.