IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v14y2021i20p6564-d654669.html
   My bibliography  Save this article

Thermodynamic Analysis of the Effect of Green Hydrogen Addition to a Fuel Mixture on the Steam Methane Reforming Process

Author

Listed:
  • Robert Kaczmarczyk

    (Department of Fundamental Research in Energy Engineering, Faculty of Energy and Fuels, AGH University of Science and Technology, Al. Mickiewicza 30, 30-059 Krakow, Poland)

Abstract

Steam methane (CH 4 –H 2 O) reforming in the presence of a catalyst, usually nickel, is the most common technology for generating synthesis gas as a feedstock in chemical synthesis and a source of pure H 2 and CO. What is essential from the perspective of further gas use is the parameter describing a ratio of equilibrium concentration of hydrogen to carbon monoxide ( H / C = x H 2 / x C O ) . The parameter is determined by operating temperature and the initial ratio of steam concentration to methane S C = x H 2 O 0 / x C H 4 0 . In this paper, the author presents a thermodynamic analysis of the effect of green hydrogen addition to a fuel mixture on the steam methane reforming process of gaseous phase (CH 4 /H 2 )–H 2 O. The thermodynamic analysis of conversion of hydrogen-enriched methane (CH 4 /H 2 )–H 2 O has been performed using parametric equation formalism, allowing for determining the equilibrium composition of the process in progress. A thermodynamic condition of carbon precipitation in methane reforming (CH 4 /H 2 ) with the gaseous phase of H 2 O has been interpreted. The ranges of substrate concentrations creating carbon deposition for temperature T = 1000 K have been determined, based on the technologies used. The results obtained can serve as a model basis for describing the properties of steam reforming of methane and hydrogen mixture (CH 4 /H 2 )–H 2 O.

Suggested Citation

  • Robert Kaczmarczyk, 2021. "Thermodynamic Analysis of the Effect of Green Hydrogen Addition to a Fuel Mixture on the Steam Methane Reforming Process," Energies, MDPI, vol. 14(20), pages 1-14, October.
    • Handle: RePEc:gam:jeners:v:14:y:2021:i:20:p:6564-:d:654669
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/14/20/6564/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/14/20/6564/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Agrafiotis, Christos & von Storch, Henrik & Roeb, Martin & Sattler, Christian, 2014. "Solar thermal reforming of methane feedstocks for hydrogen and syngas production—A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 29(C), pages 656-682.
    2. van der Zwaan, B.C.C. & Schoots, K. & Rivera-Tinoco, R. & Verbong, G.P.J., 2011. "The cost of pipelining climate change mitigation: An overview of the economics of CH4, CO2 and H2 transportation," Applied Energy, Elsevier, vol. 88(11), pages 3821-3831.
    3. Marcin Pajak & Grzegorz Brus & Janusz S. Szmyd, 2021. "Catalyst Distribution Optimization Scheme for Effective Green Hydrogen Production from Biogas Reforming," Energies, MDPI, vol. 14(17), pages 1-14, September.
    4. Minutillo, Mariagiovanna & Perna, Alessandra & Sorce, Alessandro, 2020. "Green hydrogen production plants via biogas steam and autothermal reforming processes: energy and exergy analyses," Applied Energy, Elsevier, vol. 277(C).
    5. Robert Kaczmarczyk & Sebastian Gurgul, 2021. "A Thermodynamic Analysis of Heavy Hydrocarbons Reforming for Solid Oxide Fuel Cell Application as a Part of Hybrid Energy Systems," Energies, MDPI, vol. 14(2), pages 1-11, January.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Marcin Pajak & Grzegorz Brus & Shinji Kimijima & Janusz S. Szmyd, 2023. "Enhancing Hydrogen Production from Biogas through Catalyst Rearrangements," Energies, MDPI, vol. 16(10), pages 1-21, May.
    2. Gayatri Udaysinh Ingale & Hyun-Min Kwon & Soohwa Jeong & Dongho Park & Whidong Kim & Byeingryeol Bang & Young-Il Lim & Sung Won Kim & Youn-Bae Kang & Jungsoo Mun & Sunwoo Jun & Uendo Lee, 2022. "Assessment of Greenhouse Gas Emissions from Hydrogen Production Processes: Turquoise Hydrogen vs. Steam Methane Reforming," Energies, MDPI, vol. 15(22), pages 1-20, November.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhao, Xinyue & Chen, Heng & Zheng, Qiwei & Liu, Jun & Pan, Peiyuan & Xu, Gang & Zhao, Qinxin & Jiang, Xue, 2023. "Thermo-economic analysis of a novel hydrogen production system using medical waste and biogas with zero carbon emission," Energy, Elsevier, vol. 265(C).
    2. Chu, Genyun & Fan, Yingjie & Zhang, Dawei & Gao, Minglin & Yu, Jianhua & Xie, Jianhui & Yang, Qingchun, 2022. "A highly efficient and environmentally friendly approach for in-situ utilization of CO2 from coal to ethylene glycol plant," Energy, Elsevier, vol. 256(C).
    3. Henrik Von Storch & Sonja Becker-Hardt & Christian Sattler, 2018. "(Solar) Mixed Reforming of Methane: Potential and Limits in Utilizing CO 2 as Feedstock for Syngas Production—A Thermodynamic Analysis," Energies, MDPI, vol. 11(10), pages 1-14, September.
    4. Jiang, Dongyue & Yang, Wenming & Tang, Aikun, 2016. "A refractory selective solar absorber for high performance thermochemical steam reforming," Applied Energy, Elsevier, vol. 170(C), pages 286-292.
    5. Juan Félix González & Carmen María Álvez-Medina & Sergio Nogales-Delgado, 2023. "Biogas Steam Reforming in Wastewater Treatment Plants: Opportunities and Challenges," Energies, MDPI, vol. 16(17), pages 1-35, September.
    6. Dang, Chengxiong & Xia, Huanhuan & Yuan, Shuting & Wei, Xingchuan & Cai, Weiquan, 2022. "Green hydrogen production from sorption-enhanced steam reforming of biogas over a Pd/Ni–CaO-mayenite multifunctional catalyst," Renewable Energy, Elsevier, vol. 201(P1), pages 314-322.
    7. Hajizadeh, Abdollah & Mohamadi-Baghmolaei, Mohamad & Cata Saady, Noori M. & Zendehboudi, Sohrab, 2022. "Hydrogen production from biomass through integration of anaerobic digestion and biogas dry reforming," Applied Energy, Elsevier, vol. 309(C).
    8. Onyebuchi, V.E. & Kolios, A. & Hanak, D.P. & Biliyok, C. & Manovic, V., 2018. "A systematic review of key challenges of CO2 transport via pipelines," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 2563-2583.
    9. Zhou-Qiao Dai & Xu Ma & Xin-Yuan Tang & Ren-Zhong Zhang & Wei-Wei Yang, 2023. "Solar-Thermal-Chemical Integrated Design of a Cavity-Type Solar-Driven Methane Dry Reforming Reactor," Energies, MDPI, vol. 16(6), pages 1-21, March.
    10. Schröders, Sarah & Allelein, Hans-Josef, 2018. "Energy economic evaluation of process heat supply by solar tower and high temperature reactor based on the ammonia production process," Applied Energy, Elsevier, vol. 212(C), pages 622-639.
    11. Zhu, Qibin & Xuan, Yimin & Liu, Xianglei & Yang, Lili & Lian, Wenlei & Zhang, Jin, 2020. "A 130 kWe solar simulator with tunable ultra-high flux and characterization using direct multiple lamps mapping," Applied Energy, Elsevier, vol. 270(C).
    12. von Storch, Henrik & Roeb, Martin & Stadler, Hannes & Sattler, Christian & Bardow, André & Hoffschmidt, Bernhard, 2016. "On the assessment of renewable industrial processes: Case study for solar co-production of methanol and power," Applied Energy, Elsevier, vol. 183(C), pages 121-132.
    13. Pettinau, Alberto & Ferrara, Francesca & Amorino, Carlo, 2012. "Techno-economic comparison between different technologies for a CCS power generation plant integrated with a sub-bituminous coal mine in Italy," Applied Energy, Elsevier, vol. 99(C), pages 32-39.
    14. Sunku Prasad, J. & Muthukumar, P. & Desai, Fenil & Basu, Dipankar N. & Rahman, Muhammad M., 2019. "A critical review of high-temperature reversible thermochemical energy storage systems," Applied Energy, Elsevier, vol. 254(C).
    15. Wang, Yangjie & Li, Qiang & Xuan, Yimin, 2019. "Thermal and chemical reaction performance analyses of solar thermochemical volumetric receiver/reactor with nanofluid," Energy, Elsevier, vol. 189(C).
    16. Marcin Pajak & Grzegorz Brus & Shinji Kimijima & Janusz S. Szmyd, 2023. "Enhancing Hydrogen Production from Biogas through Catalyst Rearrangements," Energies, MDPI, vol. 16(10), pages 1-21, May.
    17. Carminati, Hudson Bolsoni & de Medeiros, José Luiz & Araújo, Ofélia de Queiroz F., 2021. "Sustainable Gas-to-Wire via dry reforming of carbonated natural gas: Ionic-liquid pre-combustion capture and thermodynamic efficiency," Renewable and Sustainable Energy Reviews, Elsevier, vol. 151(C).
    18. Luu, Minh Tri & Milani, Dia & Sharma, Manish & Zeaiter, Joseph & Abbas, Ali, 2016. "Model-based analysis of CO2 revalorization for di-methyl ether synthesis driven by solar catalytic reforming," Applied Energy, Elsevier, vol. 177(C), pages 863-878.
    19. Jin, Jian & Wang, Hongsheng & Shen, Yili & Shu, Ziyun & Liu, Taixiu & Li, Wenjia, 2023. "Thermodynamic analysis of methane to methanol through a two-step process driven by concentrated solar energy," Energy, Elsevier, vol. 273(C).
    20. Villafán-Vidales, H.I. & Arancibia-Bulnes, C.A. & Riveros-Rosas, D. & Romero-Paredes, H. & Estrada, C.A., 2017. "An overview of the solar thermochemical processes for hydrogen and syngas production: Reactors, and facilities," Renewable and Sustainable Energy Reviews, Elsevier, vol. 75(C), pages 894-908.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:14:y:2021:i:20:p:6564-:d:654669. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.