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Insights into Pyrolysis Kinetics, Thermodynamics, and the Reaction Mechanism of Wheat Straw for Its Resource Utilization

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  • Jialiu Lei

    (School of Materials Science and Engineering, Hubei Polytechnic University, Huangshi 435003, China
    The State Key Laboratory of Refractories & Metallurgy, Wuhan University of Science and Technology, Wuhan 430081, China)

  • Xiaofeng Ye

    (School of Materials Science and Engineering, Hubei Polytechnic University, Huangshi 435003, China)

  • Han Wang

    (School of Materials Science and Engineering, Hubei Polytechnic University, Huangshi 435003, China)

  • Dongnan Zhao

    (School of Materials Science and Engineering, Hubei Polytechnic University, Huangshi 435003, China)

Abstract

To realize the energy recovery of wheat straw, the pyrolysis behavior of wheat straw was studied at three heating rates (10, 20, and 30 K/min) based on thermogravimetric analysis (TG–DTG). Kinetics and thermodynamics were analyzed using Flynn–Wall–Ozawa (FWO) and Kissinger–Akahira–Sunose (KAS) model-free methods, and the reaction mechanism was determined using the Coats–Redfern (CR) model-fitting method. The results show that there are three weightlessness stages in the pyrolysis process, of which the second stage was the main weightlessness stage and two distinct peaks of weightlessness were observed in this stage. With increasing heating rate, the main pyrolytic weightlessness peaks of the DTG curve shift to the high-temperature side. The pyrolysis activation energies calculated by the FWO and KAS methods are 165.17–440.02 kJ/mol and 163.72–452.07 kJ/mol, and the pre-exponential factors vary in the range of 2.58 × 10 12 –7.45 × 10 36 s −1 and 1.91 × 10 12 –8.66 × 10 37 s −1 , respectively. The thermodynamic parameters indicate that wheat straw has favorable conditions for product formation and it is a promising feedstock. Its pyrolysis reaction was nonspontaneous and the energy output is stable. CR method analysis shows that the A 1/3 random nucleation model is the most suitable mechanism to characterize the pyrolysis process and random nucleation may be in charge of the main pyrolysis stage. This study can provide a theoretical basis for the thermochemical conversion and utilization of wheat straw.

Suggested Citation

  • Jialiu Lei & Xiaofeng Ye & Han Wang & Dongnan Zhao, 2023. "Insights into Pyrolysis Kinetics, Thermodynamics, and the Reaction Mechanism of Wheat Straw for Its Resource Utilization," Sustainability, MDPI, vol. 15(16), pages 1-15, August.
    • Handle: RePEc:gam:jsusta:v:15:y:2023:i:16:p:12536-:d:1219804
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    1. Haiyu Meng & Heng Yang & Zhiqiang Wu & Danting Li & Zhe Wang & Dongqi Wang & Hui Wang & Huaien Li & Jiake Li, 2024. "Co-Pyrolysis of Mushroom Residue Blended with Pine Sawdust/Wheat Straw for Sustainable Utilization of Biomass Wastes: Thermal Characteristics, Kinetic/Thermodynamic Analysis, and Structure Evolution o," Sustainability, MDPI, vol. 16(15), pages 1-30, August.

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