Pyrolysis of Solid Digestate from Sewage Sludge and Lignocellulosic Biomass: Kinetic and Thermodynamic Analysis, Characterization of Biochar

This study investigates the pyrolysis behavior and reaction kinetics of two different types of solid digestates from: (i) sewage sludge and (ii) a mixture of sewage sludge and lignocellulosic biomass— Typha latifolia plant. Thermogravimetric data in the temperature range 25–800 °C were analyzed using Flynn–Wall–Ozawa and Kissinger–Akahira–Sunose kinetic methods, and the thermodynamic parameters ( Δ H , Δ G , and Δ S ) were also determined. Biochars were characterized using different chemical methods (FTIR, SEM–EDS, XRD, heavy metal, and nutrient analysis) and tested as soil enhancers using a germination test. Finally, their potential for biosorption of NH 4 + , PO 4 3− , Cu 2+ , and Cd 2+ ions was studied. Kinetic and thermodynamic parameters revealed a complex degradation mechanism of digestates, as they showed higher activation energies than undigested materials. Values for sewage sludge digestate were between 57 and 351 kJ/mol, and for digestate composed of sewage sludge and T. latifolia between 62 and 401 kJ/mol. Characterizations of biochars revealed high nutrient content and promising potential for further use. The advantage of biochar obtained from a digestate mixture of sewage sludge and lignocellulosic biomass is the lower content of heavy metals. Biosorption tests showed low biosorption capacity of digestate-derived biochars and their modifications for NH 4 + and PO 4 3− ions, but high biosorption capacity for Cu 2+ and Cd 2+ ions. Modification with KOH was more efficient than modification with HCl. The digestate-derived biochars exhibited excellent performance in germination tests, especially at concentrations between 6 and 10 wt.%.