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Kinetic and thermodynamic analysis of Putranjiva roxburghii (putranjiva) and Cassia fistula (amaltas) non-edible oilseeds using thermogravimetric analyzer

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  • Sahoo, Abhisek
  • Kumar, Sachin
  • Mohanty, Kaustubha

Abstract

Kinetic triplets and thermodynamic parameters of the pyrolysis of Putranjiva roxburghii (PR) and Cassia fistula (CF) non-edible oilseeds were studied using thermogravimetric analyzer. The kinetic parameters were assessed using both model-free [Kissinger-Akahira-Sunose (KAS), Flynn-Wall-Ozawa (OFW), Starink (STR), Li and Tang (LTA), Friedman (FRM), Vyazovkin (VYZ), Kissinger (KN), Avrami (AVM), and Master plot (MP)] and model-fitting [Coats-Redfern (CR)] methods at four different heating rates (10, 25, 40, and 55 °C/min) somewhere in the range of 10% and 80% conversions. The reaction mechanisms were found to be in good agreement with the experimental thermal analysis data. Thermodynamic parameters (ΔG, ΔH, and ΔS) are also determined by model-free isoconversional method. The kinetic and thermodynamic parameters recommended the appropriateness of PR and CF non-edible oilseeds for pyrolysis process.

Suggested Citation

  • Sahoo, Abhisek & Kumar, Sachin & Mohanty, Kaustubha, 2021. "Kinetic and thermodynamic analysis of Putranjiva roxburghii (putranjiva) and Cassia fistula (amaltas) non-edible oilseeds using thermogravimetric analyzer," Renewable Energy, Elsevier, vol. 165(P1), pages 261-277.
    • Handle: RePEc:eee:renene:v:165:y:2021:i:p1:p:261-277
    DOI: 10.1016/j.renene.2020.11.011
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    2. Sahu, Parmanand & Gangil, Sandip & Bhargav, Vinod Kumar, 2023. "Biopolymeric transitions under pyrolytic thermal degradation of Pigeon pea stalk," Renewable Energy, Elsevier, vol. 206(C), pages 157-167.
    3. Janaki Komandur & Abhishek Kumar & Preethi Para & Kaustubha Mohanty, 2022. "Kinetic Parameters Estimation of Thermal and Co-Pyrolysis of Groundnut De-oiled Cake and Polyethylene Terephthalate (PET) Waste," Energies, MDPI, vol. 15(20), pages 1-12, October.
    4. Sahoo, Abhisek & Saini, Komal & Negi, Shweta & Kumar, Jitendra & Pant, Kamal K. & Bhaskar, Thallada, 2022. "Inspecting the bioenergy potential of noxious Vachellia nilotica weed via pyrolysis: Thermo-kinetic study, neural network modeling and response surface optimization," Renewable Energy, Elsevier, vol. 185(C), pages 386-402.
    5. Ni, Zhanshi & Bi, Haobo & Jiang, Chunlong & Sun, Hao & Zhou, Wenliang & Qiu, Zhicong & He, Liqun & Lin, Qizhao, 2022. "Research on the co-pyrolysis of coal slime and lignin based on the combination of TG-FTIR, artificial neural network, and principal component analysis," Energy, Elsevier, vol. 261(PA).
    6. Nawaz, Ahmad & Kumar, Pradeep, 2022. "Pyrolysis behavior of low value biomass (Sesbania bispinosa) to elucidate its bioenergy potential: Kinetic, thermodynamic and prediction modelling using artificial neural network," Renewable Energy, Elsevier, vol. 200(C), pages 257-270.

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