IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v206y2023icp157-167.html
   My bibliography  Save this article

Biopolymeric transitions under pyrolytic thermal degradation of Pigeon pea stalk

Author

Listed:
  • Sahu, Parmanand
  • Gangil, Sandip
  • Bhargav, Vinod Kumar

Abstract

In this article, thermogravimetric analysis (TGA) is used to explore biopolymeric transitions in Pigeon pea stalks (PPS) at various heating rates (10, 20, 30 and 40 °C/min). The appeared transitions of TG-signals were analyzed in depth and discussed critically in terms of biopolymeric changes occurring within the major bioconstituents of PPS due to the influence of different heating rates. The intersection points of the deconvoluted conversion rate spectrum were taken as the stage transition points from one biopolymeric region to another. The stage transition points for hemicellulose to cellulose were at 328 °C and from cellulose to lignin at 356 °C, respectively, at a heating rate of 10 °C/min. This article is presenting the stage transition points first time and highlights the procedure of obtaining them using the conversion rate spectrum. The kinetics of individual bioconstituents of the PPS was also thoroughly investigated. The average activation energy was highest for hemicellulose 283–287 kJ/mol, followed by cellulose (134–137 kJ/mol) and lignin (30–41 kJ/mol). The pyrolysis of PPS followed the multistage reaction mechanism (F1 and A4) based on the Z-master plot technique.

Suggested Citation

  • Sahu, Parmanand & Gangil, Sandip & Bhargav, Vinod Kumar, 2023. "Biopolymeric transitions under pyrolytic thermal degradation of Pigeon pea stalk," Renewable Energy, Elsevier, vol. 206(C), pages 157-167.
    • Handle: RePEc:eee:renene:v:206:y:2023:i:c:p:157-167
    DOI: 10.1016/j.renene.2023.02.012
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148123001568
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2023.02.012?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Sharma, Abhishek & Pareek, Vishnu & Zhang, Dongke, 2015. "Biomass pyrolysis—A review of modelling, process parameters and catalytic studies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 1081-1096.
    2. Cardoen, Dennis & Joshi, Piyush & Diels, Ludo & Sarma, Priyangshu M. & Pant, Deepak, 2015. "Agriculture biomass in India: Part 1. Estimation and characterization," Resources, Conservation & Recycling, Elsevier, vol. 102(C), pages 39-48.
    3. Durga, Mattaparthi Lakshmi & Gangil, Sandip & Bhargav, Vinod Kumar, 2022. "Thermal influx induced biopolymeric transitions in paddy straw," Renewable Energy, Elsevier, vol. 199(C), pages 1024-1032.
    4. Gangil, Sandip, 2015. "Superiority of intrinsic biopolymeric constituents in briquettes of lignocellulosic crop residues over wood: A TG-diagnosis," Renewable Energy, Elsevier, vol. 76(C), pages 478-483.
    5. Tomasz Noszczyk & Arkadiusz Dyjakon & Jacek A. Koziel, 2021. "Kinetic Parameters of Nut Shells Pyrolysis," Energies, MDPI, vol. 14(3), pages 1-22, January.
    6. Sahoo, Abhisek & Kumar, Sachin & Mohanty, Kaustubha, 2021. "Kinetic and thermodynamic analysis of Putranjiva roxburghii (putranjiva) and Cassia fistula (amaltas) non-edible oilseeds using thermogravimetric analyzer," Renewable Energy, Elsevier, vol. 165(P1), pages 261-277.
    7. Singh, Rishikesh kumar & Sarkar, Arnab & Chakraborty, Jyoti Prasad, 2019. "Effect of torrefaction on the physicochemical properties of pigeon pea stalk (Cajanus cajan) and estimation of kinetic parameters," Renewable Energy, Elsevier, vol. 138(C), pages 805-819.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Durga, Mattaparthi Lakshmi & Gangil, Sandip & Bhargav, Vinod Kumar, 2022. "Thermal influx induced biopolymeric transitions in paddy straw," Renewable Energy, Elsevier, vol. 199(C), pages 1024-1032.
    2. Taghizadeh-Alisaraei, Ahmad & Assar, Hossein Alizadeh & Ghobadian, Barat & Motevali, Ali, 2017. "Potential of biofuel production from pistachio waste in Iran," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 510-522.
    3. Tabet, F. & Gökalp, I., 2015. "Review on CFD based models for co-firing coal and biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1101-1114.
    4. Kumar, R. & Strezov, V., 2021. "Thermochemical production of bio-oil: A review of downstream processing technologies for bio-oil upgrading, production of hydrogen and high value-added products," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    5. Juan Luis Aguirre & Juan Baena & María Teresa Martín & Leonor Nozal & Sergio González & José Luis Manjón & Manuel Peinado, 2020. "Composition, Ageing and Herbicidal Properties of Wood Vinegar Obtained through Fast Biomass Pyrolysis," Energies, MDPI, vol. 13(10), pages 1-17, May.
    6. Fan, Honggang & Gu, Jing & Wang, Yazhuo & Yuan, Haoran & Chen, Yong, 2022. "Insight into the pyrolysis kinetics of cellulose, xylan and lignin with the addition of potassium and calcium based on distributed activation energy model," Energy, Elsevier, vol. 243(C).
    7. Ortiz, Leandro Rodriguez & Torres, Erick & Zalazar, Daniela & Zhang, Huili & Rodriguez, Rosa & Mazza, Germán, 2020. "Influence of pyrolysis temperature and bio-waste composition on biochar characteristics," Renewable Energy, Elsevier, vol. 155(C), pages 837-847.
    8. Watcharakorn Ketren & Heishun Zen & Ryuichi Ashida & Toshiteru Kii & Hideaki Ohgaki, 2019. "Investigation on Conversion Pathways in Degradative Solvent Extraction of Rice Straw by Using Liquid Membrane-FTIR Spectroscopy," Energies, MDPI, vol. 12(3), pages 1-18, February.
    9. Ghorbani, Saba & Atashkari, Kazem & Borji, Mehdi, 2022. "Three-stage model-based evaluation of a downdraft biomass gasifier," Renewable Energy, Elsevier, vol. 194(C), pages 734-745.
    10. Lin, Yi-Li & Zheng, Nai-Yun & Lin, Ching-Shi, 2021. "Repurposing Washingtonia filifera petiole and Sterculia foetida follicle waste biomass for renewable energy through torrefaction," Energy, Elsevier, vol. 223(C).
    11. Nallagatla Vinod Kumar & Gajanan L. Sawargaonkar & C. Sudha Rani & Ajay Singh & T. Ram Prakash & S. Triveni & Prasad J. Kamdi & Rajesh Pasumarthi & Rayapati Karthik & Bathula Venkatesh, 2023. "Comparative Analysis of Pigeonpea Stalk Biochar Characteristics and Energy Use under Different Biochar Production Methods," Sustainability, MDPI, vol. 15(19), pages 1-17, September.
    12. Kan, Tao & Strezov, Vladimir & Evans, Tim & He, Jing & Kumar, Ravinder & Lu, Qiang, 2020. "Catalytic pyrolysis of lignocellulosic biomass: A review of variations in process factors and system structure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    13. Chamizo-Gonzalez, Julián & Cano-Montero, Elisa Isabel & Muñoz-Colomina, Clara Isabel, 2016. "Municipal Solid Waste Management services and its funding in Spain," Resources, Conservation & Recycling, Elsevier, vol. 107(C), pages 65-72.
    14. Bhoi, P.R. & Ouedraogo, A.S. & Soloiu, V. & Quirino, R., 2020. "Recent advances on catalysts for improving hydrocarbon compounds in bio-oil of biomass catalytic pyrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    15. Hongbo Du, & Deng, Fang & Kommalapati, Raghava R. & Amarasekara, Ananda S., 2020. "Iron based catalysts in biomass processing," Renewable and Sustainable Energy Reviews, Elsevier, vol. 134(C).
    16. Das, Prantika & Gundimeda, Haripriya, 2021. "Economic Evaluation of Achieving Biofuel Mandate through Advanced Biofuels in Developing Country: Case of India," 2021 Conference, August 17-31, 2021, Virtual 315355, International Association of Agricultural Economists.
    17. Kang, Shimin & Fu, Jinxia & Zhang, Gang, 2018. "From lignocellulosic biomass to levulinic acid: A review on acid-catalyzed hydrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 94(C), pages 340-362.
    18. Jiang, Shengjuan & Hu, Xun & Xia, Daohong & Li, Chun-Zhu, 2016. "Formation of aromatic ring structures during the thermal treatment of mallee wood cylinders at low temperature," Applied Energy, Elsevier, vol. 183(C), pages 542-551.
    19. Slimane Smouh & Fatima Zohra Gargab & Badr Ouhammou & Abdel Ali Mana & Rachid Saadani & Abdelmajid Jamil, 2022. "A New Approach to Energy Transition in Morocco for Low Carbon and Sustainable Industry (Case of Textile Sector)," Energies, MDPI, vol. 15(10), pages 1-26, May.
    20. Alexandre Tisserant & Francesco Cherubini, 2019. "Potentials, Limitations, Co-Benefits, and Trade-Offs of Biochar Applications to Soils for Climate Change Mitigation," Land, MDPI, vol. 8(12), pages 1-34, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:206:y:2023:i:c:p:157-167. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.