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Comparison of Combustion and Pyrolysis Behavior of the Peanut Shells in Air and N 2 : Kinetics, Thermodynamics and Gas Emissions

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  • Zhenghui Xu

    (South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
    Key Laboratory of Poyang Lake Environment and Resource Utilization, Ministry of Education, School of Resources Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, Guangzhou 510655, China)

  • Xiang Xiao

    (South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, Guangzhou 510655, China)

  • Ping Fang

    (South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, Guangzhou 510655, China)

  • Lyumeng Ye

    (School of Environmental Science and Engineering, Sun Yat-sen University, Guangzhou 510655, China)

  • Jianhang Huang

    (South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, Guangzhou 510655, China)

  • Haiwen Wu

    (South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, Guangzhou 510655, China)

  • Zijun Tang

    (South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, Guangzhou 510655, China)

  • Dongyao Chen

    (South China Institute of Environmental Sciences, Ministry of Ecology and Environment, Guangzhou 510655, China
    The Key Laboratory of Water and Air Pollution Control of Guangdong Province, Guangzhou 510655, China)

Abstract

The influences of four heating rates on the combustion and pyrolysis behavior in the N 2 and air atmosphere were investigated by the Fourier transform infrared spectrometry (FTIR) and thermogravimetric (TG) analysis. the distributed activation energy model (DEAM) and Flynn-Wall-Ozawa (FWO) were used to estimate Ea and A , ΔH , ΔG and ΔS . Experimental results showed that the similar thermal behavior emerged, but the temperatures in the air and N 2 atmospheres representing the end of the reaction were about 500 °C and 550 °C, respectively. The results of FTIR showed the peak positions were basically the same, but the concentrations of aromatics, aldehydes and ketones produced by pyrolysis in the N 2 atmosphere were higher. When the heating rate was 20 K/min, the comprehensive combustion parameters were 56.442 and 6.871 × 10 −7 % 2 /(min 2 • K 3 ) in the air and N 2 atmospheres, respectively, indicating that the peanut shells had great potential to become bioenergy.

Suggested Citation

  • Zhenghui Xu & Xiang Xiao & Ping Fang & Lyumeng Ye & Jianhang Huang & Haiwen Wu & Zijun Tang & Dongyao Chen, 2020. "Comparison of Combustion and Pyrolysis Behavior of the Peanut Shells in Air and N 2 : Kinetics, Thermodynamics and Gas Emissions," Sustainability, MDPI, vol. 12(2), pages 1-14, January.
  • Handle: RePEc:gam:jsusta:v:12:y:2020:i:2:p:464-:d:306231
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    References listed on IDEAS

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    4. Budzeń, Małgorzata & Zając, Grzegorz & Sujak, Agnieszka & Szyszlak-Bargłowicz, Joanna, 2021. "Energetic and thermal characteristics of Lavatera thuringiaca L. biomass of different age produced from He–Ne laser light stimulated seeds," Renewable Energy, Elsevier, vol. 178(C), pages 520-531.

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