IDEAS home Printed from https://ideas.repec.org/a/gam/jsusta/v13y2021i22p12813-d683183.html
   My bibliography  Save this article

Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review

Author

Listed:
  • Mohsin Raza

    (Chemical and Petroleum Engineering Department, College of Engineering, United Arab Emirates University, Al Ain 15551, United Arab Emirates)

  • Abrar Inayat

    (Department of Sustainable and Renewable Energy Engineering, University of Sharjah, Sharjah 27272, United Arab Emirates)

  • Basim Abu-Jdayil

    (Chemical and Petroleum Engineering Department, College of Engineering, United Arab Emirates University, Al Ain 15551, United Arab Emirates
    National Water and Energy Center, United Arab Emirates University, Al Ain 15551, United Arab Emirates)

Abstract

Biodiesel is an emerging substitute for petroleum-based products. It is considered an ecologically safe and sustainable fuel. The high cost of biodiesel production is linearly related to its feedstock. Crude glycerol, which is a by-product of the biodiesel industry, is also a major challenge that must be addressed. A large volume of crude glycerol needs to be disposed of, and this involves processing, dumping, and land requirements. This increases the cost of biodiesel production. One way to decrease the cost of biodiesel production is to utilize its by-product to make valuable products. Crude glycerol can be processed to produce a variety of chemicals and products. The present utilization of crude glycerol is not enough to bring down its surplus availability. Thermochemical conversion processes can utilize crude glycerol as a starting feedstock and convert it into solid, liquid, and gaseous fuels. The utilization of crude glycerol through integrated thermochemical conversion processes could lead to an integrated biorefinery. This review paper highlights the research scope for areas where crude glycerol could be utilized as a feedstock or co-feedstock in thermochemical conversion technology. Various thermochemical conversion processes, namely, gasification, pyrolysis, combustion, catalytic steam reforming, liquefaction, and supercritical water reforming, are discussed and shown to be highly suitable for the use of crude glycerol as an economical feedstock. It is found that the integration of crude glycerol with other thermochemical conversion processes for energy production is a promising option to overcome the challenges related to biodiesel production costs. Hence, this paper provides all the necessary information on the present utilization status of crude glycerol in thermochemical conversion processes, as well as identifying possible research gaps that could be filled by future research studies.

Suggested Citation

  • Mohsin Raza & Abrar Inayat & Basim Abu-Jdayil, 2021. "Crude Glycerol as a Potential Feedstock for Future Energy via Thermochemical Conversion Processes: A Review," Sustainability, MDPI, vol. 13(22), pages 1-27, November.
  • Handle: RePEc:gam:jsusta:v:13:y:2021:i:22:p:12813-:d:683183
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/2071-1050/13/22/12813/pdf
    Download Restriction: no

    File URL: https://www.mdpi.com/2071-1050/13/22/12813/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Long, Huiling & Li, Xiaobing & Wang, Hong & Jia, Jingdun, 2013. "Biomass resources and their bioenergy potential estimation: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 26(C), pages 344-352.
    2. Adhikari, Sushil & Fernando, Sandun D. & Haryanto, Agus, 2008. "Hydrogen production from glycerin by steam reforming over nickel catalysts," Renewable Energy, Elsevier, vol. 33(5), pages 1097-1100.
    3. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Xu, Yujie, 2014. "Hydrogen production from catalytic steam reforming of biodiesel byproduct glycerol: Issues and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 30(C), pages 950-960.
    4. Tian, Xueyu & You, Fengqi, 2019. "Carbon-neutral hybrid energy systems with deep water source cooling, biomass heating, and geothermal heat and power," Applied Energy, Elsevier, vol. 250(C), pages 413-432.
    5. Silvia Román Suero & Beatriz Ledesma & Andrés Álvarez-Murillo & Awf Al-Kassir & Talal Yusaf, 2015. "Glycerin, a Biodiesel By-Product with Potentiality to Produce Hydrogen by Steam Gasification," Energies, MDPI, vol. 8(11), pages 1-11, November.
    6. Dou, Binlin & Song, Yongchen & Wang, Chao & Chen, Haisheng & Yang, Mingjun & Xu, Yujie, 2014. "Hydrogen production by enhanced-sorption chemical looping steam reforming of glycerol in moving-bed reactors," Applied Energy, Elsevier, vol. 130(C), pages 342-349.
    7. Inayat, Abrar & Raza, Mohsin, 2019. "District cooling system via renewable energy sources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 360-373.
    8. Chen, Haisheng & Ding, Yulong & Cong, Ngoc T. & Dou, Binlin & Dupont, Valerie & Ghadiri, Mojtaba & Williams, Paul T., 2011. "A comparative study on hydrogen production from steam-glycerol reforming: thermodynamics and experimental," Renewable Energy, Elsevier, vol. 36(2), pages 779-788.
    9. Joselin Herbert, G.M. & Iniyan, S. & Sreevalsan, E. & Rajapandian, S., 2007. "A review of wind energy technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(6), pages 1117-1145, August.
    10. Kezhen Qian & Ajay Kumar & Krushna Patil & Danielle Bellmer & Donghai Wang & Wenqiao Yuan & Raymond L. Huhnke, 2013. "Effects of Biomass Feedstocks and Gasification Conditions on the Physiochemical Properties of Char," Energies, MDPI, vol. 6(8), pages 1-15, August.
    11. Bai, Zhang & Liu, Qibin & Lei, Jing & Hong, Hui & Jin, Hongguang, 2017. "New solar-biomass power generation system integrated a two-stage gasifier," Applied Energy, Elsevier, vol. 194(C), pages 310-319.
    12. Goyal, H.B. & Seal, Diptendu & Saxena, R.C., 2008. "Bio-fuels from thermochemical conversion of renewable resources: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(2), pages 504-517, February.
    13. Silitonga, A.S. & Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Mekhilef, S., 2011. "A review on prospect of Jatropha curcas for biodiesel in Indonesia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3733-3756.
    14. Effendi, A. & Gerhauser, H. & Bridgwater, A.V., 2008. "Production of renewable phenolic resins by thermochemical conversion of biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(8), pages 2092-2116, October.
    15. Van de Velden, Manon & Baeyens, Jan & Brems, Anke & Janssens, Bart & Dewil, Raf, 2010. "Fundamentals, kinetics and endothermicity of the biomass pyrolysis reaction," Renewable Energy, Elsevier, vol. 35(1), pages 232-242.
    16. Gutiérrez Ortiz, F.J. & Serrera, A. & Galera, S. & Ollero, P., 2013. "Experimental study of the supercritical water reforming of glycerol without the addition of a catalyst," Energy, Elsevier, vol. 56(C), pages 193-206.
    17. Ardi, M.S. & Aroua, M.K. & Hashim, N. Awanis, 2015. "Progress, prospect and challenges in glycerol purification process: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1164-1173.
    18. Atabani, A.E. & Silitonga, A.S. & Badruddin, Irfan Anjum & Mahlia, T.M.I. & Masjuki, H.H. & Mekhilef, S., 2012. "A comprehensive review on biodiesel as an alternative energy resource and its characteristics," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(4), pages 2070-2093.
    19. Chen, Jen-Jeng & Lee, Yu-Ru, 2018. "Optimization of the transesterification reaction of microalgal Monoraphidium sp," Renewable Energy, Elsevier, vol. 129(PB), pages 717-723.
    20. Alberg Østergaard, Poul & Mathiesen, Brian Vad & Möller, Bernd & Lund, Henrik, 2010. "A renewable energy scenario for Aalborg Municipality based on low-temperature geothermal heat, wind power and biomass," Energy, Elsevier, vol. 35(12), pages 4892-4901.
    21. Gutiérrez Ortiz, F.J. & Campanario, F.J. & Aguilera, P.G. & Ollero, P., 2015. "Hydrogen production from supercritical water reforming of glycerol over Ni/Al2O3–SiO2 catalyst," Energy, Elsevier, vol. 84(C), pages 634-642.
    22. Tan, H.W. & Abdul Aziz, A.R. & Aroua, M.K., 2013. "Glycerol production and its applications as a raw material: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 118-127.
    23. Hoang, Anh Tuan & Sandro Nižetić, & Olcer, Aykut I. & Ong, Hwai Chyuan & Chen, Wei-Hsin & Chong, Cheng Tung & Thomas, Sabu & Bandh, Suhaib A. & Nguyen, Xuan Phuong, 2021. "Impacts of COVID-19 pandemic on the global energy system and the shift progress to renewable energy: Opportunities, challenges, and policy implications," Energy Policy, Elsevier, vol. 154(C).
    24. Li, Hui & Liu, Fengsheng & Ma, Xiaoling & Cui, Ping & Guo, Min & Li, Yan & Gao, Yan & Zhou, Shoujun & Yu, Mingzhi, 2020. "An efficient basic heterogeneous catalyst synthesis of magnetic mesoporous Fe@C support SrO for transesterification," Renewable Energy, Elsevier, vol. 149(C), pages 816-827.
    25. Kan, Tao & Strezov, Vladimir & Evans, Tim J., 2016. "Lignocellulosic biomass pyrolysis: A review of product properties and effects of pyrolysis parameters," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 1126-1140.
    26. Quispe, César A.G. & Coronado, Christian J.R. & Carvalho Jr., João A., 2013. "Glycerol: Production, consumption, prices, characterization and new trends in combustion," Renewable and Sustainable Energy Reviews, Elsevier, vol. 27(C), pages 475-493.
    27. Sansaniwal, S.K. & Pal, K. & Rosen, M.A. & Tyagi, S.K., 2017. "Recent advances in the development of biomass gasification technology: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 363-384.
    28. Roy, Poritosh & Dias, Goretty, 2017. "Prospects for pyrolysis technologies in the bioenergy sector: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 77(C), pages 59-69.
    29. Mei, Danhua & Liu, Shiyun & Wang, Sen & Zhou, Renwu & Zhou, Rusen & Fang, Zhi & Zhang, Xianhui & Cullen, Patrick J. & Ostrikov, Kostya (Ken), 2020. "Plasma-enabled liquefaction of lignocellulosic biomass: Balancing feedstock content for maximum energy yield," Renewable Energy, Elsevier, vol. 157(C), pages 1061-1071.
    30. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    31. Nayak, Sheetal N. & Bhasin, Chandra Prakash & Nayak, Milap G., 2019. "A review on microwave-assisted transesterification processes using various catalytic and non-catalytic systems," Renewable Energy, Elsevier, vol. 143(C), pages 1366-1387.
    32. Anuar, Mohd Razealy & Abdullah, Ahmad Zuhairi, 2016. "Challenges in biodiesel industry with regards to feedstock, environmental, social and sustainability issues: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 208-223.
    33. Inayat, Abrar & Inayat, Muddasser & Shahbaz, Muhammad & Sulaiman, Shaharin A. & Raza, Mohsin & Yusup, Suzana, 2020. "Parametric analysis and optimization for the catalytic air gasification of palm kernel shell using coal bottom ash as catalyst," Renewable Energy, Elsevier, vol. 145(C), pages 671-681.
    34. Reinhard Rauch & Jitka Hrbek & Hermann Hofbauer, 2014. "Biomass gasification for synthesis gas production and applications of the syngas," Wiley Interdisciplinary Reviews: Energy and Environment, Wiley Blackwell, vol. 3(4), pages 343-362, July.
    35. Leoneti, Alexandre Bevilacqua & Aragão-Leoneti, Valquiria & de Oliveira, Sonia Valle Walter Borges, 2012. "Glycerol as a by-product of biodiesel production in Brazil: Alternatives for the use of unrefined glycerol," Renewable Energy, Elsevier, vol. 45(C), pages 138-145.
    36. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Hazrat, M.A. & Liaquat, A.M. & Shahabuddin, M. & Varman, M., 2012. "Prospects of biodiesel from Jatropha in Malaysia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(7), pages 5007-5020.
    37. Yang, Jie & (Sophia) He, Quan & Yang, Linxi, 2019. "A review on hydrothermal co-liquefaction of biomass," Applied Energy, Elsevier, vol. 250(C), pages 926-945.
    38. Lima-Corrêa, Renata A.B. & Castro, Cínthia S. & Damasceno, Amanda S. & Assaf, José M., 2020. "The enhanced activity of base metal modified MgAl mixed oxides from sol-gel hydrotalcite for ethylic transesterification," Renewable Energy, Elsevier, vol. 146(C), pages 1984-1990.
    39. Remón, J. & Arcelus-Arrillaga, P. & García, L. & Arauzo, J., 2018. "Simultaneous production of gaseous and liquid biofuels from the synergetic co-valorisation of bio-oil and crude glycerol in supercritical water," Applied Energy, Elsevier, vol. 228(C), pages 2275-2287.
    40. Collard, François-Xavier & Blin, Joël, 2014. "A review on pyrolysis of biomass constituents: Mechanisms and composition of the products obtained from the conversion of cellulose, hemicelluloses and lignin," Renewable and Sustainable Energy Reviews, Elsevier, vol. 38(C), pages 594-608.
    41. Shahzad, M. Kashif & Zahid, Adeem & ur Rashid, Tanzeel & Rehan, Mirza Abdullah & Ali, Muzaffar & Ahmad, Mueen, 2017. "Techno-economic feasibility analysis of a solar-biomass off grid system for the electrification of remote rural areas in Pakistan using HOMER software," Renewable Energy, Elsevier, vol. 106(C), pages 264-273.
    42. Pascoal, C.V.P. & Oliveira, A.L.L. & Figueiredo, D.D. & Assunção, J.C.C., 2020. "Optimization and kinetic study of ultrasonic-mediated in situ transesterification for biodiesel production from the almonds of Syagrus cearensis," Renewable Energy, Elsevier, vol. 147(P1), pages 1815-1824.
    43. Avhad, M.R. & Marchetti, J.M., 2015. "A review on recent advancement in catalytic materials for biodiesel production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 696-718.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Sara Maen Asaad & Abrar Inayat & Farrukh Jamil & Chaouki Ghenai & Abdallah Shanableh, 2023. "Optimization of Biodiesel Production from Waste Cooking Oil Using a Green Catalyst Prepared from Glass Waste and Animal Bones," Energies, MDPI, vol. 16(5), pages 1-13, February.
    2. Zhang, Jianan & Wang, Yuesen & Muldoon, Valerie L. & Deng, Sili, 2022. "Crude glycerol and glycerol as fuels and fuel additives in combustion applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    2. Andrew N. Amenaghawon & Chinedu L. Anyalewechi & Charity O. Okieimen & Heri Septya Kusuma, 2021. "Biomass pyrolysis technologies for value-added products: a state-of-the-art review," Environment, Development and Sustainability: A Multidisciplinary Approach to the Theory and Practice of Sustainable Development, Springer, vol. 23(10), pages 14324-14378, October.
    3. Jia, Guangxin & He, Beibei & Ma, Wenlin & Sun, Yifan, 2019. "Thermodynamic analysis based on simultaneous chemical and phase equilibrium for dehydration of glycerol with methanol," Energy, Elsevier, vol. 188(C).
    4. Kawale, Harshal D. & Kishore, Nanda, 2020. "Comparative study on pyrolysis of Delonix Regia, Pinewood sawdust and their co-feed for plausible bio-fuels production," Energy, Elsevier, vol. 203(C).
    5. Zhang, Jianan & Wang, Yuesen & Muldoon, Valerie L. & Deng, Sili, 2022. "Crude glycerol and glycerol as fuels and fuel additives in combustion applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 159(C).
    6. Silva, Joel M. & Soria, M.A. & Madeira, Luis M., 2015. "Challenges and strategies for optimization of glycerol steam reforming process," Renewable and Sustainable Energy Reviews, Elsevier, vol. 42(C), pages 1187-1213.
    7. Hameed, Zeeshan & Aslam, Muhammad & Khan, Zakir & Maqsood, Khuram & Atabani, A.E. & Ghauri, Moinuddin & Khurram, Muhammad Shahzad & Rehan, Mohammad & Nizami, Abdul-Sattar, 2021. "Gasification of municipal solid waste blends with biomass for energy production and resources recovery: Current status, hybrid technologies and innovative prospects," Renewable and Sustainable Energy Reviews, Elsevier, vol. 136(C).
    8. Schwengber, Carine Aline & Alves, Helton José & Schaffner, Rodolfo Andrade & da Silva, Fernando Alves & Sequinel, Rodrigo & Bach, Vanessa Rossato & Ferracin, Ricardo José, 2016. "Overview of glycerol reforming for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 259-266.
    9. Zhang, Chenting & Chao, Li & Zhang, Zhanming & Zhang, Lijun & Li, Qingyin & Fan, Huailin & Zhang, Shu & Liu, Qing & Qiao, Yingyun & Tian, Yuanyu & Wang, Yi & Hu, Xun, 2021. "Pyrolysis of cellulose: Evolution of functionalities and structure of bio-char versus temperature," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    10. Yang, Lan & Wang, Xue-Chao & Dai, Min & Chen, Bin & Qiao, Yuanbo & Deng, Huijing & Zhang, Dingfan & Zhang, Yizhe & Villas Bôas de Almeida, Cecília Maria & Chiu, Anthony S.F. & Klemeš, Jiří Jaromír & W, 2021. "Shifting from fossil-based economy to bio-based economy: Status quo, challenges, and prospects," Energy, Elsevier, vol. 228(C).
    11. Mohsin Raza & Abrar Inayat & Ashfaq Ahmed & Farrukh Jamil & Chaouki Ghenai & Salman R. Naqvi & Abdallah Shanableh & Muhammad Ayoub & Ammara Waris & Young-Kwon Park, 2021. "Progress of the Pyrolyzer Reactors and Advanced Technologies for Biomass Pyrolysis Processing," Sustainability, MDPI, vol. 13(19), pages 1-42, October.
    12. Jun Sheng Teh & Yew Heng Teoh & Heoy Geok How & Thanh Danh Le & Yeoh Jun Jie Jason & Huu Tho Nguyen & Dong Lin Loo, 2021. "The Potential of Sustainable Biomass Producer Gas as a Waste-to-Energy Alternative in Malaysia," Sustainability, MDPI, vol. 13(7), pages 1-31, April.
    13. Primaz, Carmem T. & Ribes-Greus, Amparo & Jacques, Rosângela A., 2021. "Valorization of cotton residues for production of bio-oil and engineered biochar," Energy, Elsevier, vol. 235(C).
    14. Mahmudul, H.M. & Hagos, F.Y. & Mamat, R. & Adam, A. Abdul & Ishak, W.F.W. & Alenezi, R., 2017. "Production, characterization and performance of biodiesel as an alternative fuel in diesel engines – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 72(C), pages 497-509.
    15. Perkins, Greg & Bhaskar, Thallada & Konarova, Muxina, 2018. "Process development status of fast pyrolysis technologies for the manufacture of renewable transport fuels from biomass," Renewable and Sustainable Energy Reviews, Elsevier, vol. 90(C), pages 292-315.
    16. Kartal, Furkan & Dalbudak, Yağmur & Özveren, Uğur, 2023. "Prediction of thermal degradation of biopolymers in biomass under pyrolysis atmosphere by means of machine learning," Renewable Energy, Elsevier, vol. 204(C), pages 774-787.
    17. Motasemi, F. & Afzal, Muhammad T., 2013. "A review on the microwave-assisted pyrolysis technique," Renewable and Sustainable Energy Reviews, Elsevier, vol. 28(C), pages 317-330.
    18. Marta Ramos & Ana Paula Soares Dias & Jaime Filipe Puna & João Gomes & João Carlos Bordado, 2019. "Biodiesel Production Processes and Sustainable Raw Materials," Energies, MDPI, vol. 12(23), pages 1-30, November.
    19. Mofijur, M. & Atabani, A.E. & Masjuki, H.H. & Kalam, M.A. & Masum, B.M., 2013. "A study on the effects of promising edible and non-edible biodiesel feedstocks on engine performance and emissions production: A comparative evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 391-404.
    20. Kong, Pei San & Aroua, Mohamed Kheireddine & Daud, Wan Mohd Ashri Wan, 2016. "Conversion of crude and pure glycerol into derivatives: A feasibility evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 533-555.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jsusta:v:13:y:2021:i:22:p:12813-:d:683183. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.