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Overview of glycerol reforming for hydrogen production

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  • Schwengber, Carine Aline
  • Alves, Helton José
  • Schaffner, Rodolfo Andrade
  • da Silva, Fernando Alves
  • Sequinel, Rodrigo
  • Bach, Vanessa Rossato
  • Ferracin, Ricardo José

Abstract

Hydrogen is used by the chemical industry in numerous processes, and today almost 95% is produced from raw materials based on fossil fuels, such as methane (CH4). However, catalytic reforming technologies face a number of technical and scientific challenges involving the quality of raw materials, conversion efficiency, and safety issues in the integration of systems of H2 production, purification and use, among others. Glycerol is a versatile raw material for H2 production because it is the main by-product of biodiesel production, which a few years ago was consolidated in the world energy matrix and whose production continues to grow in the main consumer markets. Moreover, it has the noteworthy characteristic of decentralized production, which is directly reflected in its easy use. This paper presents a literature review on the reforming technologies applied to glycerol, the advantages of each route, and the main problems involved.

Suggested Citation

  • Schwengber, Carine Aline & Alves, Helton José & Schaffner, Rodolfo Andrade & da Silva, Fernando Alves & Sequinel, Rodrigo & Bach, Vanessa Rossato & Ferracin, Ricardo José, 2016. "Overview of glycerol reforming for hydrogen production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 58(C), pages 259-266.
    • Handle: RePEc:eee:rensus:v:58:y:2016:i:c:p:259-266
    DOI: 10.1016/j.rser.2015.12.279
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    2. Moreira, Rui & Bimbela, Fernando & Gandía, Luis M. & Ferreira, Abel & Sánchez, Jose Luis & Portugal, António, 2021. "Oxidative steam reforming of glycerol. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    3. Okoye, P.U. & Abdullah, A.Z. & Hameed, B.H., 2017. "A review on recent developments and progress in the kinetics and deactivation of catalytic acetylation of glycerol—A byproduct of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 74(C), pages 387-401.
    4. Monteiro, Marcos Roberto & Kugelmeier, Cristie Luis & Pinheiro, Rafael Sanaiotte & Batalha, Mario Otávio & da Silva César, Aldara, 2018. "Glycerol from biodiesel production: Technological paths for sustainability," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 109-122.
    5. Silva-Illanes, Fernando & Tapia-Venegas, Estela & Schiappacasse, M. Cristina & Trably, Eric & Ruiz-Filippi, Gonzalo, 2017. "Impact of hydraulic retention time (HRT) and pH on dark fermentative hydrogen production from glycerol," Energy, Elsevier, vol. 141(C), pages 358-367.
    6. He, Quan (Sophia) & McNutt, Josiah & Yang, Jie, 2017. "Utilization of the residual glycerol from biodiesel production for renewable energy generation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 71(C), pages 63-76.
    7. Larimi, Afsanehsadat & Khorasheh, Farhad, 2018. "Renewable hydrogen production by ethylene glycol steam reforming over Al2O3 supported Ni-Pt bimetallic nano-catalysts," Renewable Energy, Elsevier, vol. 128(PA), pages 188-199.

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