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Optimization of the transesterification reaction of microalgal Monoraphidium sp

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  • Chen, Jen-Jeng
  • Lee, Yu-Ru

Abstract

This study optimized biodiesel production by Monoraphidium sp. in terms of fatty acid methyl ester (FAME) yield by varying four variables (volume of methanol, reaction temperature, reaction time, and ultrasound power) using a Box-Behnken design (BBD). Within the experimental range, the volume of methanol was found to be the most important factor, having a positive influence on the FAME yield. The test variables affected the FAME yield, and the optimal condition varied between alkali- and acid-catalyzed transesterification. Both types of transesterification reaction occurred at their optimal catalyst concentrations, 0.5% NaOH and 2% H2SO4, respectively, for both dry and wet microalgal biomass. The FAME yield with the acid-catalyzed reaction was better than that with the alkali-catalyzed reaction. The combined alkali-and-acid-catalyzed transesterification reactions enhanced the FAME yield. The microalgae produced fatty acids, comprising mainly palmitic acid (C16:0), oleic acid (C18:1), linoleic acid (C18:2), and linolenic acid (C18:3), with palmitic acid (C16:0) and linoleic acid (C18:2) being the most abundant.

Suggested Citation

  • Chen, Jen-Jeng & Lee, Yu-Ru, 2018. "Optimization of the transesterification reaction of microalgal Monoraphidium sp," Renewable Energy, Elsevier, vol. 129(PB), pages 717-723.
    • Handle: RePEc:eee:renene:v:129:y:2018:i:pb:p:717-723
    DOI: 10.1016/j.renene.2017.06.012
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    References listed on IDEAS

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    1. Eevera, T. & Rajendran, K. & Saradha, S., 2009. "Biodiesel production process optimization and characterization to assess the suitability of the product for varied environmental conditions," Renewable Energy, Elsevier, vol. 34(3), pages 762-765.
    2. Singh, Jasvinder & Gu, Sai, 2010. "Commercialization potential of microalgae for biofuels production," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(9), pages 2596-2610, December.
    3. Holbrook, Gabriel P. & Davidson, Zachary & Tatara, Robert A. & Ziemer, Norbert L. & Rosentrater, Kurt A. & Scott Grayburn, W., 2014. "Use of the microalga Monoraphidium sp. grown in wastewater as a feedstock for biodiesel: Cultivation and fuel characteristics," Applied Energy, Elsevier, vol. 131(C), pages 386-393.
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