IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v11y2018i4p730-d137743.html
   My bibliography  Save this article

Pyrolysis of Grape Marc from Tunisian Wine Industry: Feedstock Characterization, Thermal Degradation and Kinetic Analysis

Author

Listed:
  • Besma Khiari

    (Laboratoire des Sciences et Technologies de l’Environnement, University of Carthage, BP 50 Borj Cedria Technopark, 2050 Hammam-Lif, Tunisia)

  • Mejdi Jeguirim

    (Institut de Sciences des Matériaux de Mulhouse, UMR 7661 CNRS, 15 rue Jean Starcky, 68057 Mulhouse, France)

Abstract

Despite the huge amounts of grape marc generated in Tunisia from the wine industry, very few efforts have been exerted to manage this harmful waste. Therefore, thermal processes may contribute to an environmental friendly management and also help winemakers to create new economic profitable circuits in an increasingly competitive context. Among the various thermochemical conversion process, pyrolysis is suitable for the recovery of food processing residues, due to their high minerals content and ability to create high added values of the derived products (biochar, bio-oil and syngas). In this context, the aim of this work is to optimize the pyrolysis process in order to benefit from the grape marc potential for achieving highest product yields. Therefore, physico-chemical and energy characteristics of grape marc issued from a Tunisian wine cooperative were determined according to international standards. Thermogravimetric analyzes were also performed to predict the grape marc behavior during degradation under an inert atmosphere. The profile of the mass loss rate shows two decomposition peaks corresponding to the cellulose and lignin decomposition. These peaks are shifted to lower temperatures comparing to several lignocellulosic biomass feedstocks due to high content of minerals that may play a catalytic role in the thermal degradation process. The biochar yield was about 40%, which was never met in literature for agricultural biomass in slow pyrolysis. Such behavior may be attributed to high lignin content in grape marc. Activation energies were calculated using integral Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose methods and differential Friedman method. The obtained values were 226.8, 224.2 and 229.5 kJ/mol, respectively. Such kinetics data are crucial in the design of the pyrolyzer for Tunisian grape marc recovery.

Suggested Citation

  • Besma Khiari & Mejdi Jeguirim, 2018. "Pyrolysis of Grape Marc from Tunisian Wine Industry: Feedstock Characterization, Thermal Degradation and Kinetic Analysis," Energies, MDPI, vol. 11(4), pages 1-14, March.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:4:p:730-:d:137743
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/11/4/730/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/11/4/730/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. El may, Yassine & Jeguirim, Mejdi & Dorge, Sophie & Trouvé, Gwenaelle & Said, Rachid, 2012. "Study on the thermal behavior of different date palm residues: Characterization and devolatilization kinetics under inert and oxidative atmospheres," Energy, Elsevier, vol. 44(1), pages 702-709.
    2. Haddad, Khouloud & Jeguirim, Mejdi & Jellali, Salah & Guizani, Chamseddine & Delmotte, Luc & Bennici, Simona & Limousy, Lionel, 2017. "Combined NMR structural characterization and thermogravimetric analyses for the assessment of the AAEM effect during lignocellulosic biomass pyrolysis," Energy, Elsevier, vol. 134(C), pages 10-23.
    3. Mohammad I. Jahirul & Mohammad G. Rasul & Ashfaque Ahmed Chowdhury & Nanjappa Ashwath, 2012. "Biofuels Production through Biomass Pyrolysis —A Technological Review," Energies, MDPI, vol. 5(12), pages 1-50, November.
    4. María Pilar González-Vázquez & Roberto García & Covadonga Pevida & Fernando Rubiera, 2017. "Optimization of a Bubbling Fluidized Bed Plant for Low-Temperature Gasification of Biomass," Energies, MDPI, vol. 10(3), pages 1-16, March.
    5. Xing Yang & Hailong Wang & Peter James Strong & Song Xu & Shujuan Liu & Kouping Lu & Kuichuan Sheng & Jia Guo & Lei Che & Lizhi He & Yong Sik Ok & Guodong Yuan & Ying Shen & Xin Chen, 2017. "Thermal Properties of Biochars Derived from Waste Biomass Generated by Agricultural and Forestry Sectors," Energies, MDPI, vol. 10(4), pages 1-12, April.
    6. Mohammed J. Kabir & Ashfaque Ahmed Chowdhury & Mohammad G. Rasul, 2015. "Pyrolysis of Municipal Green Waste: A Modelling, Simulation and Experimental Analysis," Energies, MDPI, vol. 8(8), pages 1-20, July.
    7. Kraiem, Nesrine & Lajili, Marzouk & Limousy, Lionel & Said, Rachid & Jeguirim, Mejdi, 2016. "Energy recovery from Tunisian agri-food wastes: Evaluation of combustion performance and emissions characteristics of green pellets prepared from tomato residues and grape marc," Energy, Elsevier, vol. 107(C), pages 409-418.
    8. Marculescu, Cosmin & Ciuta, Simona, 2013. "Wine industry waste thermal processing for derived fuel properties improvement," Renewable Energy, Elsevier, vol. 57(C), pages 645-652.
    9. Chamseddine Guizani & Mejdi Jeguirim & Sylvie Valin & Lionel Limousy & Sylvain Salvador, 2017. "Biomass Chars: The Effects of Pyrolysis Conditions on Their Morphology, Structure, Chemical Properties and Reactivity," Energies, MDPI, vol. 10(6), pages 1-18, June.
    10. Patrick Brassard & Stéphane Godbout & Vijaya Raghavan & Joahnn H. Palacios & Michèle Grenier & Dan Zegan, 2017. "The Production of Engineered Biochars in a Vertical Auger Pyrolysis Reactor for Carbon Sequestration," Energies, MDPI, vol. 10(3), pages 1-15, February.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Khiari, Besma & Jeguirim, Mejdi & Limousy, Lionel & Bennici, Simona, 2019. "Biomass derived chars for energy applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 253-273.
    2. Ramos, João S. & Ferreira, Ana F., 2022. "Techno-economic analysis and life cycle assessment of olive and wine industry co-products valorisation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    3. Azzaz, Ahmed Amine & Khiari, Besma & Jellali, Salah & Ghimbeu, Camélia Matei & Jeguirim, Mejdi, 2020. "Hydrochars production, characterization and application for wastewater treatment: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    4. Mejdi Jeguirim & Lionel Limousy, 2019. "Biomass Chars: Elaboration, Characterization and Applications II," Energies, MDPI, vol. 12(3), pages 1-6, January.
    5. Jialiu Lei & Xiaofeng Ye & Han Wang & Dongnan Zhao, 2023. "Insights into Pyrolysis Kinetics, Thermodynamics, and the Reaction Mechanism of Wheat Straw for Its Resource Utilization," Sustainability, MDPI, vol. 15(16), pages 1-15, August.
    6. Hani Hussain Sait & Ahmed Hussain & Mohamed Bassyouni & Imtiaz Ali & Ramesh Kanthasamy & Bamidele Victor Ayodele & Yasser Elhenawy, 2022. "Hydrogen-Rich Syngas and Biochar Production by Non-Catalytic Valorization of Date Palm Seeds," Energies, MDPI, vol. 15(8), pages 1-13, April.
    7. Dahou, T. & Defoort, F. & Khiari, B. & Labaki, M. & Dupont, C. & Jeguirim, M., 2021. "Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    8. Ibn Ferjani, A. & Jeguirim, M. & Jellali, S. & Limousy, L. & Courson, C. & Akrout, H. & Thevenin, N. & Ruidavets, L. & Muller, A. & Bennici, S., 2019. "The use of exhausted grape marc to produce biofuels and biofertilizers: Effect of pyrolysis temperatures on biochars properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 425-433.
    9. Tianbao Gu & Torsten Berning & Chungen Yin, 2021. "Application of a New Statistical Model for the Description of Solid Fuel Decomposition in the Analysis of Artemisia apiacea Pyrolysis," Energies, MDPI, vol. 14(18), pages 1-12, September.
    10. Longwei Pan & Yong Jiang & Lei Wang & Wu Xu, 2018. "Kinetic Study on the Pyrolysis of Medium Density Fiberboard: Effects of Secondary Charring Reactions," Energies, MDPI, vol. 11(9), pages 1-17, September.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mejdi Jeguirim & Lionel Limousy, 2017. "Biomass Chars: Elaboration, Characterization and Applications," Energies, MDPI, vol. 10(12), pages 1-7, December.
    2. Shi-Xiang Zhao & Na Ta & Xu-Dong Wang, 2017. "Effect of Temperature on the Structural and Physicochemical Properties of Biochar with Apple Tree Branches as Feedstock Material," Energies, MDPI, vol. 10(9), pages 1-15, August.
    3. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2017. "Chemical Characteristics and NaCl Component Behavior of Biochar Derived from the Salty Food Waste by Water Flushing," Energies, MDPI, vol. 10(10), pages 1-15, October.
    4. Ibn Ferjani, A. & Jeguirim, M. & Jellali, S. & Limousy, L. & Courson, C. & Akrout, H. & Thevenin, N. & Ruidavets, L. & Muller, A. & Bennici, S., 2019. "The use of exhausted grape marc to produce biofuels and biofertilizers: Effect of pyrolysis temperatures on biochars properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 425-433.
    5. Daniele Basso & Elsa Weiss-Hortala & Francesco Patuzzi & Marco Baratieri & Luca Fiori, 2018. "In Deep Analysis on the Behavior of Grape Marc Constituents during Hydrothermal Carbonization," Energies, MDPI, vol. 11(6), pages 1-19, May.
    6. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2018. "Value-Added Performance and Thermal Decomposition Characteristics of Dumped Food Waste Compost by Pyrolysis," Energies, MDPI, vol. 11(5), pages 1-14, April.
    7. Campuzano, Felipe & Brown, Robert C. & Martínez, Juan Daniel, 2019. "Auger reactors for pyrolysis of biomass and wastes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 102(C), pages 372-409.
    8. Waheed A. Rasaq & Mateusz Golonka & Miklas Scholz & Andrzej Białowiec, 2021. "Opportunities and Challenges of High-Pressure Fast Pyrolysis of Biomass: A Review," Energies, MDPI, vol. 14(17), pages 1-20, August.
    9. Alba Dieguez-Alonso & Axel Funke & Andrés Anca-Couce & Alessandro Girolamo Rombolà & Gerardo Ojeda & Jörg Bachmann & Frank Behrendt, 2018. "Towards Biochar and Hydrochar Engineering—Influence of Process Conditions on Surface Physical and Chemical Properties, Thermal Stability, Nutrient Availability, Toxicity and Wettability," Energies, MDPI, vol. 11(3), pages 1-26, February.
    10. Lajili, M. & Guizani, C. & Escudero Sanz, F.J. & Jeguirim, M., 2018. "Fast pyrolysis and steam gasification of pellets prepared from olive oil mill residues," Energy, Elsevier, vol. 150(C), pages 61-68.
    11. Mika Pahnila & Aki Koskela & Petri Sulasalmi & Timo Fabritius, 2023. "A Review of Pyrolysis Technologies and the Effect of Process Parameters on Biocarbon Properties," Energies, MDPI, vol. 16(19), pages 1-27, October.
    12. Dina Aboelela & Habibatallah Saleh & Attia M. Attia & Yasser Elhenawy & Thokozani Majozi & Mohamed Bassyouni, 2023. "Recent Advances in Biomass Pyrolysis Processes for Bioenergy Production: Optimization of Operating Conditions," Sustainability, MDPI, vol. 15(14), pages 1-30, July.
    13. Seung-Yong Oh & Young-Man Yoon, 2017. "Energy Recovery Efficiency of Poultry Slaughterhouse Sludge Cake by Hydrothermal Carbonization," Energies, MDPI, vol. 10(11), pages 1-13, November.
    14. Yin Pang & Leo Bahr & Peter Fendt & Lars Zigan & Stefan Will & Thomas Hammer & Manfred Baldauf & Robert Fleck & Dominik Müller & Jürgen Karl, 2018. "Plasma-Assisted Biomass Gasification with Focus on Carbon Conversion and Reaction Kinetics Compared to Thermal Gasification," Energies, MDPI, vol. 11(5), pages 1-24, May.
    15. Jun-Ho Jo & Seung-Soo Kim & Jae-Wook Shim & Ye-Eun Lee & Yeong-Seok Yoo, 2017. "Pyrolysis Characteristics and Kinetics of Food Wastes," Energies, MDPI, vol. 10(8), pages 1-13, August.
    16. Nourelhouda Boukaous & Lokmane Abdelouahed & Mustapha Chikhi & Abdeslam-Hassen Meniai & Chetna Mohabeer & Taouk Bechara, 2018. "Combustion of Flax Shives, Beech Wood, Pure Woody Pseudo-Components and Their Chars: A Thermal and Kinetic Study," Energies, MDPI, vol. 11(8), pages 1-16, August.
    17. Czajczyńska, Dina & Krzyżyńska, Renata & Jouhara, Hussam & Spencer, Nik, 2017. "Use of pyrolytic gas from waste tire as a fuel: A review," Energy, Elsevier, vol. 134(C), pages 1121-1131.
    18. Antonio Molino & Vincenzo Larocca & Simeone Chianese & Dino Musmarra, 2018. "Biofuels Production by Biomass Gasification: A Review," Energies, MDPI, vol. 11(4), pages 1-31, March.
    19. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2018. "Influence of NaCl Concentration on Food-Waste Biochar Structure and Templating Effects," Energies, MDPI, vol. 11(9), pages 1-16, September.
    20. Xia Liu & Juntao Wei & Wei Huo & Guangsuo Yu, 2017. "Gasification under CO 2 –Steam Mixture: Kinetic Model Study Based on Shared Active Sites," Energies, MDPI, vol. 10(11), pages 1-10, November.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:11:y:2018:i:4:p:730-:d:137743. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.