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Pyrolysis of Grape Marc from Tunisian Wine Industry: Feedstock Characterization, Thermal Degradation and Kinetic Analysis

Author

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  • Besma Khiari

    (Laboratoire des Sciences et Technologies de l’Environnement, University of Carthage, BP 50 Borj Cedria Technopark, 2050 Hammam-Lif, Tunisia)

  • Mejdi Jeguirim

    (Institut de Sciences des Matériaux de Mulhouse, UMR 7661 CNRS, 15 rue Jean Starcky, 68057 Mulhouse, France)

Abstract

Despite the huge amounts of grape marc generated in Tunisia from the wine industry, very few efforts have been exerted to manage this harmful waste. Therefore, thermal processes may contribute to an environmental friendly management and also help winemakers to create new economic profitable circuits in an increasingly competitive context. Among the various thermochemical conversion process, pyrolysis is suitable for the recovery of food processing residues, due to their high minerals content and ability to create high added values of the derived products (biochar, bio-oil and syngas). In this context, the aim of this work is to optimize the pyrolysis process in order to benefit from the grape marc potential for achieving highest product yields. Therefore, physico-chemical and energy characteristics of grape marc issued from a Tunisian wine cooperative were determined according to international standards. Thermogravimetric analyzes were also performed to predict the grape marc behavior during degradation under an inert atmosphere. The profile of the mass loss rate shows two decomposition peaks corresponding to the cellulose and lignin decomposition. These peaks are shifted to lower temperatures comparing to several lignocellulosic biomass feedstocks due to high content of minerals that may play a catalytic role in the thermal degradation process. The biochar yield was about 40%, which was never met in literature for agricultural biomass in slow pyrolysis. Such behavior may be attributed to high lignin content in grape marc. Activation energies were calculated using integral Flynn-Wall-Ozawa and Kissinger-Akahira-Sunose methods and differential Friedman method. The obtained values were 226.8, 224.2 and 229.5 kJ/mol, respectively. Such kinetics data are crucial in the design of the pyrolyzer for Tunisian grape marc recovery.

Suggested Citation

  • Besma Khiari & Mejdi Jeguirim, 2018. "Pyrolysis of Grape Marc from Tunisian Wine Industry: Feedstock Characterization, Thermal Degradation and Kinetic Analysis," Energies, MDPI, vol. 11(4), pages 1-14, March.
    • Handle: RePEc:gam:jeners:v:11:y:2018:i:4:p:730-:d:137743
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    References listed on IDEAS

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    Cited by:

    1. Ramos, João S. & Ferreira, Ana F., 2022. "Techno-economic analysis and life cycle assessment of olive and wine industry co-products valorisation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 155(C).
    2. Jialiu Lei & Xiaofeng Ye & Han Wang & Dongnan Zhao, 2023. "Insights into Pyrolysis Kinetics, Thermodynamics, and the Reaction Mechanism of Wheat Straw for Its Resource Utilization," Sustainability, MDPI, vol. 15(16), pages 1-15, August.
    3. Hani Hussain Sait & Ahmed Hussain & Mohamed Bassyouni & Imtiaz Ali & Ramesh Kanthasamy & Bamidele Victor Ayodele & Yasser Elhenawy, 2022. "Hydrogen-Rich Syngas and Biochar Production by Non-Catalytic Valorization of Date Palm Seeds," Energies, MDPI, vol. 15(8), pages 1-13, April.
    4. Khiari, Besma & Jeguirim, Mejdi & Limousy, Lionel & Bennici, Simona, 2019. "Biomass derived chars for energy applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 108(C), pages 253-273.
    5. Azzaz, Ahmed Amine & Khiari, Besma & Jellali, Salah & Ghimbeu, Camélia Matei & Jeguirim, Mejdi, 2020. "Hydrochars production, characterization and application for wastewater treatment: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 127(C).
    6. Mejdi Jeguirim & Lionel Limousy, 2019. "Biomass Chars: Elaboration, Characterization and Applications II," Energies, MDPI, vol. 12(3), pages 1-6, January.
    7. Dahou, T. & Defoort, F. & Khiari, B. & Labaki, M. & Dupont, C. & Jeguirim, M., 2021. "Role of inorganics on the biomass char gasification reactivity: A review involving reaction mechanisms and kinetics models," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    8. Ibn Ferjani, A. & Jeguirim, M. & Jellali, S. & Limousy, L. & Courson, C. & Akrout, H. & Thevenin, N. & Ruidavets, L. & Muller, A. & Bennici, S., 2019. "The use of exhausted grape marc to produce biofuels and biofertilizers: Effect of pyrolysis temperatures on biochars properties," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 425-433.
    9. Tianbao Gu & Torsten Berning & Chungen Yin, 2021. "Application of a New Statistical Model for the Description of Solid Fuel Decomposition in the Analysis of Artemisia apiacea Pyrolysis," Energies, MDPI, vol. 14(18), pages 1-12, September.
    10. Longwei Pan & Yong Jiang & Lei Wang & Wu Xu, 2018. "Kinetic Study on the Pyrolysis of Medium Density Fiberboard: Effects of Secondary Charring Reactions," Energies, MDPI, vol. 11(9), pages 1-17, September.

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