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The Production of Engineered Biochars in a Vertical Auger Pyrolysis Reactor for Carbon Sequestration

Author

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  • Patrick Brassard

    (Research and Development Institute for the Agri-Environment (IRDA), 2700 Einstein Street, Quebec City, QC G1P 3W8, Canada
    Department of Bioresource Engineering, MacDonald Campus, McGill University, 2111 Lakeshore, Sainte-Anne-de-Bellevue, QC H9X 3V9, Canada)

  • Stéphane Godbout

    (Research and Development Institute for the Agri-Environment (IRDA), 2700 Einstein Street, Quebec City, QC G1P 3W8, Canada)

  • Vijaya Raghavan

    (Department of Bioresource Engineering, MacDonald Campus, McGill University, 2111 Lakeshore, Sainte-Anne-de-Bellevue, QC H9X 3V9, Canada)

  • Joahnn H. Palacios

    (Research and Development Institute for the Agri-Environment (IRDA), 2700 Einstein Street, Quebec City, QC G1P 3W8, Canada)

  • Michèle Grenier

    (Research and Development Institute for the Agri-Environment (IRDA), 2700 Einstein Street, Quebec City, QC G1P 3W8, Canada)

  • Dan Zegan

    (Research and Development Institute for the Agri-Environment (IRDA), 2700 Einstein Street, Quebec City, QC G1P 3W8, Canada)

Abstract

Biomass pyrolysis and the valorization of co-products (biochar, bio-oil, syngas) could be a sustainable management solution for agricultural and forest residues. Depending on its properties, biochar amended to soil could improve fertility. Moreover, biochar is expected to mitigate climate change by reducing soil greenhouse gas emissions, if its C/N ratio is lower than 30, and sequestrating carbon if its O/Corg and H/Corg ratios are lower than 0.2 and 0.7, respectively. However, the yield and properties of biochar are influenced by biomass feedstock and pyrolysis operating parameters. The objective of this research study was to validate an approach based on the response surface methodology, to identify the optimal pyrolysis operating parameters (temperature, solid residence time, and carrier gas flowrate), in order to produce engineered biochars for carbon sequestration. The pyrolysis of forest residues, switchgrass, and the solid fraction of pig manure, was carried out in a vertical auger reactor following a Box-Behnken design, in order to develop response surface models. The optimal pyrolysis operating parameters were estimated to obtain biochar with the lowest H/Corg and O/Corg ratios. Validation pyrolysis experiments confirmed that the selected approach can be used to accurately predict the optimal operating parameters for producing biochar with the desired properties to sequester carbon.

Suggested Citation

  • Patrick Brassard & Stéphane Godbout & Vijaya Raghavan & Joahnn H. Palacios & Michèle Grenier & Dan Zegan, 2017. "The Production of Engineered Biochars in a Vertical Auger Pyrolysis Reactor for Carbon Sequestration," Energies, MDPI, vol. 10(3), pages 1-15, February.
    • Handle: RePEc:gam:jeners:v:10:y:2017:i:3:p:288-:d:91722
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    References listed on IDEAS

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    1. Dominic Woolf & James E. Amonette & F. Alayne Street-Perrott & Johannes Lehmann & Stephen Joseph, 2010. "Sustainable biochar to mitigate global climate change," Nature Communications, Nature, vol. 1(1), pages 1-9, December.
    2. Mohammad I. Jahirul & Mohammad G. Rasul & Ashfaque Ahmed Chowdhury & Nanjappa Ashwath, 2012. "Biofuels Production through Biomass Pyrolysis —A Technological Review," Energies, MDPI, vol. 5(12), pages 1-50, November.
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    1. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2018. "Value-Added Performance and Thermal Decomposition Characteristics of Dumped Food Waste Compost by Pyrolysis," Energies, MDPI, vol. 11(5), pages 1-14, April.
    2. Chamseddine Guizani & Mejdi Jeguirim & Sylvie Valin & Lionel Limousy & Sylvain Salvador, 2017. "Biomass Chars: The Effects of Pyrolysis Conditions on Their Morphology, Structure, Chemical Properties and Reactivity," Energies, MDPI, vol. 10(6), pages 1-18, June.
    3. Robert Hren & Aleksandra Petrovič & Lidija Čuček & Marjana Simonič, 2020. "Determination of Various Parameters during Thermal and Biological Pretreatment of Waste Materials," Energies, MDPI, vol. 13(9), pages 1-15, May.
    4. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2018. "Influence of NaCl Concentration on Food-Waste Biochar Structure and Templating Effects," Energies, MDPI, vol. 11(9), pages 1-16, September.
    5. Mejdi Jeguirim & Lionel Limousy, 2017. "Biomass Chars: Elaboration, Characterization and Applications," Energies, MDPI, vol. 10(12), pages 1-7, December.
    6. Campuzano, Felipe & Brown, Robert C. & Martínez, Juan Daniel, 2019. "Auger reactors for pyrolysis of biomass and wastes," Renewable and Sustainable Energy Reviews, Elsevier, vol. 102(C), pages 372-409.
    7. Shi-Xiang Zhao & Na Ta & Xu-Dong Wang, 2017. "Effect of Temperature on the Structural and Physicochemical Properties of Biochar with Apple Tree Branches as Feedstock Material," Energies, MDPI, vol. 10(9), pages 1-15, August.
    8. Brassard, P. & Godbout, S. & Hamelin, L., 2021. "Framework for consequential life cycle assessment of pyrolysis biorefineries: A case study for the conversion of primary forestry residues," Renewable and Sustainable Energy Reviews, Elsevier, vol. 138(C).
    9. Alba Dieguez-Alonso & Axel Funke & Andrés Anca-Couce & Alessandro Girolamo Rombolà & Gerardo Ojeda & Jörg Bachmann & Frank Behrendt, 2018. "Towards Biochar and Hydrochar Engineering—Influence of Process Conditions on Surface Physical and Chemical Properties, Thermal Stability, Nutrient Availability, Toxicity and Wettability," Energies, MDPI, vol. 11(3), pages 1-26, February.
    10. Francisco Anguebes-Franseschi & Mohamed Abatal & Ali Bassam & Mauricio A. Escalante Soberanis & Oscar May Tzuc & Lauro Bucio-Galindo & Atl Victor Cordova Quiroz & Claudia Alejandra Aguilar Ucan & Migu, 2018. "Esterification Optimization of Crude African Palm Olein Using Response Surface Methodology and Heterogeneous Acid Catalysis," Energies, MDPI, vol. 11(1), pages 1-15, January.
    11. Ye-Eun Lee & Jun-Ho Jo & I-Tae Kim & Yeong-Seok Yoo, 2017. "Chemical Characteristics and NaCl Component Behavior of Biochar Derived from the Salty Food Waste by Water Flushing," Energies, MDPI, vol. 10(10), pages 1-15, October.
    12. Mika Pahnila & Aki Koskela & Petri Sulasalmi & Timo Fabritius, 2023. "A Review of Pyrolysis Technologies and the Effect of Process Parameters on Biocarbon Properties," Energies, MDPI, vol. 16(19), pages 1-27, October.
    13. Besma Khiari & Mejdi Jeguirim, 2018. "Pyrolysis of Grape Marc from Tunisian Wine Industry: Feedstock Characterization, Thermal Degradation and Kinetic Analysis," Energies, MDPI, vol. 11(4), pages 1-14, March.
    14. Seung-Yong Oh & Young-Man Yoon, 2017. "Energy Recovery Efficiency of Poultry Slaughterhouse Sludge Cake by Hydrothermal Carbonization," Energies, MDPI, vol. 10(11), pages 1-13, November.

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