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Removal and Conversion of Tar in Syngas from Woody Biomass Gasification for Power Utilization Using Catalytic Hydrocracking

Author

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  • Jiu Huang

    (School of Environmental Science and Spatial Informatics, China University of Mining and Technology (CUMT), Xuzhou 221008, China)

  • Klaus Gerhard Schmidt

    (Institute of Energy and Environmental Technology e.V. (IUTA), Duisburg 47229, Germany)

  • Zhengfu Bian

    (School of Environmental Science and Spatial Informatics, China University of Mining and Technology (CUMT), Xuzhou 221008, China)

Abstract

Biomass gasification has yet to obtain industrial acceptance. The high residual tar concentrations in syngas prevent any ambitious utilization. In this paper a novel gas purification technology based on catalytic hydrocracking is introduced, whereby most of the tarry components can be converted and removed. Pilot scale experiments were carried out with an updraft gasifier. The hydrocracking catalyst was palladium (Pd). The results show the dominant role of temperature and flow rate. At a constant flow rate of 20 Nm 3 /h and temperatures of 500 °C, 600 °C and 700 °C the tar conversion rates reached 44.9%, 78.1% and 92.3%, respectively. These results could be increased up to 98.6% and 99.3% by using an operating temperature of 700 °C and lower flow rates of 15 Nm 3 /h and 10 Nm 3 /h. The syngas quality after the purification process at 700 °C/10 Nm 3 /h is acceptable for inner combustion (IC) gas engine utilization.

Suggested Citation

  • Jiu Huang & Klaus Gerhard Schmidt & Zhengfu Bian, 2011. "Removal and Conversion of Tar in Syngas from Woody Biomass Gasification for Power Utilization Using Catalytic Hydrocracking," Energies, MDPI, vol. 4(8), pages 1-15, August.
    • Handle: RePEc:gam:jeners:v:4:y:2011:i:8:p:1163-1177:d:13523
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    References listed on IDEAS

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    1. Saxena, R.C. & Seal, Diptendu & Kumar, Satinder & Goyal, H.B., 2008. "Thermo-chemical routes for hydrogen rich gas from biomass: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(7), pages 1909-1927, September.
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    3. Rahman, Md Mashiur & Aravindakshan, Sreejith & Matin, Md Abdul, 2021. "Design and performance evaluation of an inclined nozzle and combustor of a downdraft moving bed gasifier for tar reduction," Renewable Energy, Elsevier, vol. 172(C), pages 239-250.
    4. Li, Bin & Magoua Mbeugang, Christian Fabrice & Huang, Yong & Liu, Dongjing & Wang, Qian & Zhang, Shu, 2022. "A review of CaO based catalysts for tar removal during biomass gasification," Energy, Elsevier, vol. 244(PB).
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