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Catalytic Upgrading of Residual Fat Pyrolysis Vapors over Activated Carbon Pellets into Hydrocarbons-like Fuels in a Two-Stage Reactor: Analysis of Hydrocarbons Composition and Physical-Chemistry Properties

Author

Listed:
  • Lucas Pinto Bernar

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Caio Campos Ferreira

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Augusto Fernando de Freitas Costa

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Haroldo Jorge da Silva Ribeiro

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Wenderson Gomes dos Santos

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Lia Martins Pereira

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Anderson Mathias Pereira

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Nathalia Lobato Moraes

    (Faculty of Sanitary and Environmental Engineering, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Corrêa N° 1, Belém 66075-900, Brazil)

  • Fernanda Paula da Costa Assunção

    (Graduate Program of Civil Engineering, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Sílvio Alex Pereira da Mota

    (Graduate Program of Chemistry, Universidade Federal do Sul e Sudeste do Pará, Folha 31, Quadra 7, Lote Especial—Nova Marabá, CEP, Marabá 68507-590, Brazil)

  • Douglas Alberto Rocha de Castro

    (Cursos de Engenharia Química, Mecânica e Elétrica, Centro Universitário Luterano de Manaus—CEULM/ULBRA, Avenida Carlos Drummond de Andrade N°. 1460, Manaus 69077-730, Brazil)

  • Marcelo Costa Santos

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil)

  • Neyson Martins Mendonça

    (Faculty of Sanitary and Environmental Engineering, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Corrêa N° 1, Belém 66075-900, Brazil)

  • Sergio Duvoisin

    (Faculty of Chemical Engineering, Universidade do Estado do Amazonas-UEA, Avenida Darcy Vargas N°. 1200, Manaus 69050-020, Brazil)

  • Luiz Eduardo Pizarro Borges

    (Laboratory of Catalyst Preparation and Catalytic Cracking, Section of Chemical Engineering, Instituto Militar de Engenharia-IME, Praça General Tibúrcio N°. 80, Rio de Janeiro 22290-270, Brazil)

  • Nélio Teixeira Machado

    (Graduate Program of Natural Resources Engineering of Amazon, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Augusto Corrêa N° 1, Belém 66075-110, Brazil
    Faculty of Sanitary and Environmental Engineering, Campus Profissional-UFPA, Universidade Federal do Pará, Rua Corrêa N° 1, Belém 66075-900, Brazil)

Abstract

This work investigated the influence of the reaction time and catalyst-to-residual fat ratio by catalytic upgrading from pyrolysis vapors of residual fat at 400 °C and 1.0 atmosphere, on the yields of reaction products, physicochemical properties (density, kinematic viscosity, and acid value) and chemical composition of bio-oils, over a catalyst fixed-bed reactor of activated carbon pellets impregnated with 10.0 M NaOH, in semi-pilot scale. The experiments were carried out at 400 °C and 1.0 atmosphere, using a process schema consisting of a thermal cracking reactor of 2.0 L coupled to a catalyst fixed-bed reactor of 53 mL, without catalyst and using 5.0%, 7.5%, and 10.0% (wt.) activated carbon pellets impregnated with 10.0 M NaOH, in batch mode. Results show yields of bio-oil decreasing with increasing catalyst-to-tallow ratio. The GC-MS of liquid reaction products identified the presence of hydrocarbons (alkanes, alkenes, ring-containing alkanes, ring-containing alkenes, and aromatics) and oxygenates (carboxylic acids, ketones, esters, alcohols, and aldehydes). For all the pyrolysis and catalytic cracking experiments, the hydrocarbon selectivity in bio-oil increases with increasing reaction time, while those of oxygenates decrease, reaching concentrations of hydrocarbons up to 95.35% (area).

Suggested Citation

  • Lucas Pinto Bernar & Caio Campos Ferreira & Augusto Fernando de Freitas Costa & Haroldo Jorge da Silva Ribeiro & Wenderson Gomes dos Santos & Lia Martins Pereira & Anderson Mathias Pereira & Nathalia , 2022. "Catalytic Upgrading of Residual Fat Pyrolysis Vapors over Activated Carbon Pellets into Hydrocarbons-like Fuels in a Two-Stage Reactor: Analysis of Hydrocarbons Composition and Physical-Chemistry Prop," Energies, MDPI, vol. 15(13), pages 1-26, June.
  • Handle: RePEc:gam:jeners:v:15:y:2022:i:13:p:4587-:d:845883
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    References listed on IDEAS

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    1. Vichaphund, Supawan & Aht-ong, Duangdao & Sricharoenchaikul, Viboon & Atong, Duangduen, 2014. "Catalytic upgrading pyrolysis vapors of Jatropha waste using metal promoted ZSM-5 catalysts: An analytical PY-GC/MS," Renewable Energy, Elsevier, vol. 65(C), pages 70-77.
    2. Douglas Alberto Rocha de Castro & Haroldo Jorge da Silva Ribeiro & Lauro Henrique Hamoy Guerreiro & Lucas Pinto Bernar & Sami Jonatan Bremer & Marcelo Costa Santo & Hélio da Silva Almeida & Sergio Duv, 2021. "Production of Fuel-Like Fractions by Fractional Distillation of Bio-Oil from Açaí ( Euterpe oleracea Mart.) Seeds Pyrolysis," Energies, MDPI, vol. 14(13), pages 1-27, June.
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    Cited by:

    1. Augusto Fernando de Freitas Costa & Caio Campos Ferreira & Simone Patrícia Aranha da Paz & Marcelo Costa Santos & Luiz Gabriel Santos Moreira & Neyson Martins Mendonça & Fernanda Paula da Costa Assunç, 2023. "Catalytic Upgrading of Plastic Waste of Electric and Electronic Equipment (WEEE) Pyrolysis Vapors over Si–Al Ash Pellets in a Two-Stage Reactor," Energies, MDPI, vol. 16(1), pages 1-32, January.
    2. Fernanda Paula da Costa Assunção & Diogo Oliveira Pereira & Jéssica Cristina Conte da Silva & Jorge Fernando Hungria Ferreira & Kelly Christina Alves Bezerra & Lucas Pinto Bernar & Caio Campos Ferreir, 2022. "A Systematic Approach to Thermochemical Treatment of Municipal Household Solid Waste into Valuable Products: Analysis of Routes, Gravimetric Analysis, Pre-Treatment of Solid Mixtures, Thermochemical P," Energies, MDPI, vol. 15(21), pages 1-30, October.
    3. Gérson Daniel Valdez & Flávio Pinheiro Valois & Sammy Jonatan Bremer & Kelly Christina Alves Bezerra & Lauro Henrique Hamoy Guerreiro & Marcelo Costa Santos & Lucas Pinto Bernar & Waldeci Paraguassu F, 2023. "Improving the Bio-Oil Quality of Residual Biomass Pyrolysis by Chemical Activation: Effect of Alkalis and Acid Pre-Treatment," Energies, MDPI, vol. 16(7), pages 1-18, March.
    4. Caio Campos Ferreira & Lucas Pinto Bernar & Augusto Fernando de Freitas Costa & Haroldo Jorge da Silva Ribeiro & Marcelo Costa Santos & Nathalia Lobato Moraes & Yasmin Santos Costa & Ana Cláudia Fonse, 2022. "Improving Fuel Properties and Hydrocarbon Content from Residual Fat Pyrolysis Vapors over Activated Red Mud Pellets in Two-Stage Reactor: Optimization of Reaction Time and Catalyst Content," Energies, MDPI, vol. 15(15), pages 1-33, August.

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