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NCA, NCM811, and the Route to Ni-Richer Lithium-Ion Batteries

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  • Christian M. Julien

    (Institut de Minéralogie, de Physique des Matériaux et de Cosmologie (IMPMC), Sorbonne Université, CNRS-UMR 7590, 4 Place Jussieu, 75252 Paris, France)

  • Alain Mauger

    (Institut de Minéralogie, de Physique des Matériaux et de Cosmologie (IMPMC), Sorbonne Université, CNRS-UMR 7590, 4 Place Jussieu, 75252 Paris, France)

Abstract

The aim of this article is to examine the progress achieved in the recent years on two advanced cathode materials for EV Li-ion batteries, namely Ni-rich layered oxides LiNi 0.8 Co 0.15 Al 0.05 O 2 (NCA) and LiNi 0.8 Co 0.1 Mn 0.1 O 2 (NCM811). Both materials have the common layered (two-dimensional) crystal network isostructural with LiCoO 2 . The performance of these electrode materials are examined, the mitigation of their drawbacks (i.e., antisite defects, microcracks, surface side reactions) are discussed, together with the prospect on a next generation of Li-ion batteries with Co-free Ni-rich Li-ion batteries.

Suggested Citation

  • Christian M. Julien & Alain Mauger, 2020. "NCA, NCM811, and the Route to Ni-Richer Lithium-Ion Batteries," Energies, MDPI, vol. 13(23), pages 1-46, December.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:23:p:6363-:d:454921
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    References listed on IDEAS

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    1. Zubi, Ghassan & Dufo-López, Rodolfo & Carvalho, Monica & Pasaoglu, Guzay, 2018. "The lithium-ion battery: State of the art and future perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 89(C), pages 292-308.
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    3. Feng Lin & Isaac M. Markus & Dennis Nordlund & Tsu-Chien Weng & Mark D. Asta & Huolin L. Xin & Marca M. Doeff, 2014. "Surface reconstruction and chemical evolution of stoichiometric layered cathode materials for lithium-ion batteries," Nature Communications, Nature, vol. 5(1), pages 1-9, May.
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    2. Ruixia Chu & Yujian Zou & Peidong Zhu & Shiwei Tan & Fangyuan Qiu & Wenjun Fu & Fu Niu & Wanyou Huang, 2022. "Progress of Single-Crystal Nickel-Cobalt-Manganese Cathode Research," Energies, MDPI, vol. 15(23), pages 1-32, December.
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