IDEAS home Printed from https://ideas.repec.org/a/gam/jeners/v15y2022i23p9235-d994772.html
   My bibliography  Save this article

Progress of Single-Crystal Nickel-Cobalt-Manganese Cathode Research

Author

Listed:
  • Ruixia Chu

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China
    Key Laboratory of Transportation Industry for Transport Vehicle Detection, Diagnosis and Maintenance Technology, Jinan 250357, China
    Intelligent Testing and High-End Equipment of Automotive Power Systems, Shandong Province Engineering Research Center, Jinan 250357, China
    Jinan Engineering Research Center of Automotive Equipment and Technology, Shandong Province Engineering Research Center, Jinan 250357, China)

  • Yujian Zou

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China)

  • Peidong Zhu

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China)

  • Shiwei Tan

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China)

  • Fangyuan Qiu

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China
    Key Laboratory of Transportation Industry for Transport Vehicle Detection, Diagnosis and Maintenance Technology, Jinan 250357, China
    Intelligent Testing and High-End Equipment of Automotive Power Systems, Shandong Province Engineering Research Center, Jinan 250357, China)

  • Wenjun Fu

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China
    Key Laboratory of Transportation Industry for Transport Vehicle Detection, Diagnosis and Maintenance Technology, Jinan 250357, China
    Intelligent Testing and High-End Equipment of Automotive Power Systems, Shandong Province Engineering Research Center, Jinan 250357, China)

  • Fu Niu

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China
    Key Laboratory of Transportation Industry for Transport Vehicle Detection, Diagnosis and Maintenance Technology, Jinan 250357, China
    Intelligent Testing and High-End Equipment of Automotive Power Systems, Shandong Province Engineering Research Center, Jinan 250357, China)

  • Wanyou Huang

    (Departments of Energy and Power Engineering, Automotive Engineering College, Shandong Jiaotong University, Jinan 250357, China
    Key Laboratory of Transportation Industry for Transport Vehicle Detection, Diagnosis and Maintenance Technology, Jinan 250357, China
    Intelligent Testing and High-End Equipment of Automotive Power Systems, Shandong Province Engineering Research Center, Jinan 250357, China)

Abstract

The booming electric vehicle industry continues to place higher requirements on power batteries related to economic-cost, power density and safety. The positive electrode materials play an important role in the energy storage performance of the battery. The nickel-rich NCM (LiNi x Co y Mn z O 2 with x + y + z = 1) materials have received increasing attention due to their high energy density, which can satisfy the demand of commercial-grade power batteries. Prominently, single-crystal nickel-rich electrodes with s unique micron-scale single-crystal structure possess excellent electrochemical and mechanical performance, even when tested at high rates, high cut-off voltages and high temperatures. In this review, we outline in brief the characteristics, problems faced and countermeasures of nickel-rich NCM materials. Then the distinguishing features and main synthesis methods of single-crystal nickel-rich NCM materials are summarized. Some existing issues and modification methods are also discussed in detail, especially the optimization strategies under harsh conditions. Finally, an outlook on the future development of single-crystal nickel-rich materials is provided. This work is expected to provide some reference for research on single-crystal nickel-rich ternary materials with high energy density, high safety levels, long-life, and their contribution to sustainable development.

Suggested Citation

  • Ruixia Chu & Yujian Zou & Peidong Zhu & Shiwei Tan & Fangyuan Qiu & Wenjun Fu & Fu Niu & Wanyou Huang, 2022. "Progress of Single-Crystal Nickel-Cobalt-Manganese Cathode Research," Energies, MDPI, vol. 15(23), pages 1-32, December.
    • Handle: RePEc:gam:jeners:v:15:y:2022:i:23:p:9235-:d:994772
    as

    Download full text from publisher

    File URL: https://www.mdpi.com/1996-1073/15/23/9235/pdf
    Download Restriction: no
    File URL: https://www.mdpi.com/1996-1073/15/23/9235/
    Download Restriction: no
    ---><---

    References listed on IDEAS

    as
    1. Hyeonsu Lim & Dan Na & Cheul-Ro Lee & Hyung-Kee Seo & O-Hyeon Kwon & Jae-Kwang Kim & Inseok Seo, 2021. "An Integrated Device of a Lithium-Ion Battery Combined with Silicon Solar Cells," Energies, MDPI, vol. 14(19), pages 1-11, September.
    2. Jun-Ping Hu & Hang Sheng & Qi Deng & Qiang Ma & Jun Liu & Xiong-Wei Wu & Jun-Jie Liu & Yu-Ping Wu, 2020. "High-Rate Layered Cathode of Lithium-Ion Batteries through Regulating Three-Dimensional Agglomerated Structure," Energies, MDPI, vol. 13(7), pages 1-12, April.
    3. Pengfei Yan & Jianming Zheng & Jian Liu & Biqiong Wang & Xiaopeng Cheng & Yuefei Zhang & Xueliang Sun & Chongmin Wang & Ji-Guang Zhang, 2018. "Tailoring grain boundary structures and chemistry of Ni-rich layered cathodes for enhanced cycle stability of lithium-ion batteries," Nature Energy, Nature, vol. 3(7), pages 600-605, July.
    4. Wangda Li & Evan M. Erickson & Arumugam Manthiram, 2020. "High-nickel layered oxide cathodes for lithium-based automotive batteries," Nature Energy, Nature, vol. 5(1), pages 26-34, January.
    5. J.-M. Tarascon & M. Armand, 2001. "Issues and challenges facing rechargeable lithium batteries," Nature, Nature, vol. 414(6861), pages 359-367, November.
    6. Christian M. Julien & Alain Mauger, 2020. "NCA, NCM811, and the Route to Ni-Richer Lithium-Ion Batteries," Energies, MDPI, vol. 13(23), pages 1-46, December.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Jung-Hui Kim & Ju-Myung Kim & Seok-Kyu Cho & Nag-Young Kim & Sang-Young Lee, 2022. "Redox-homogeneous, gel electrolyte-embedded high-mass-loading cathodes for high-energy lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-11, December.
    2. Gogwon Choe & Hyungsub Kim & Jaesub Kwon & Woochul Jung & Kyu-Young Park & Yong-Tae Kim, 2024. "Re-evaluation of battery-grade lithium purity toward sustainable batteries," Nature Communications, Nature, vol. 15(1), pages 1-10, December.
    3. Junbo Zhang & Haikuo Zhang & Suting Weng & Ruhong Li & Di Lu & Tao Deng & Shuoqing Zhang & Ling Lv & Jiacheng Qi & Xuezhang Xiao & Liwu Fan & Shujiang Geng & Fuhui Wang & Lixin Chen & Malachi Noked & , 2023. "Multifunctional solvent molecule design enables high-voltage Li-ion batteries," Nature Communications, Nature, vol. 14(1), pages 1-14, December.
    4. Yi Pei & Qing Chen & Meiyu Wang & Pengjun Zhang & Qingyong Ren & Jingkai Qin & Penghao Xiao & Li Song & Yu Chen & Wen Yin & Xin Tong & Liang Zhen & Peng Wang & Cheng-Yan Xu, 2022. "A medium-entropy transition metal oxide cathode for high-capacity lithium metal batteries," Nature Communications, Nature, vol. 13(1), pages 1-13, December.
    5. Held, Marcel & Tuchschmid, Martin & Zennegg, Markus & Figi, Renato & Schreiner, Claudia & Mellert, Lars Derek & Welte, Urs & Kompatscher, Michael & Hermann, Michael & Nachef, Léa, 2022. "Thermal runaway and fire of electric vehicle lithium-ion battery and contamination of infrastructure facility," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    6. Zhi Chang & Huijun Yang & Xingyu Zhu & Ping He & Haoshen Zhou, 2022. "A stable quasi-solid electrolyte improves the safe operation of highly efficient lithium-metal pouch cells in harsh environments," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    7. Chao Wang & Ming Liu & Michel Thijs & Frans G. B. Ooms & Swapna Ganapathy & Marnix Wagemaker, 2021. "High dielectric barium titanate porous scaffold for efficient Li metal cycling in anode-free cells," Nature Communications, Nature, vol. 12(1), pages 1-11, December.
    8. Liao, Xiaolin & Sun, Peiyi & Xu, Mengqing & Xing, Lidan & Liao, Youhao & Zhang, Liping & Yu, Le & Fan, Weizhen & Li, Weishan, 2016. "Application of tris(trimethylsilyl)borate to suppress self-discharge of layered nickel cobalt manganese oxide for high energy battery," Applied Energy, Elsevier, vol. 175(C), pages 505-511.
    9. Pranjal Barman & Lachit Dutta & Brian Azzopardi, 2023. "Electric Vehicle Battery Supply Chain and Critical Materials: A Brief Survey of State of the Art," Energies, MDPI, vol. 16(8), pages 1-23, April.
    10. Ma, Mina & Wang, Yu & Duan, Qiangling & Wu, Tangqin & Sun, Jinhua & Wang, Qingsong, 2018. "Fault detection of the connection of lithium-ion power batteries in series for electric vehicles based on statistical analysis," Energy, Elsevier, vol. 164(C), pages 745-756.
    11. Guo-Rui Zhu & Qin Zhang & Qing-Song Liu & Qi-Yao Bai & Yi-Zhou Quan & You Gao & Gang Wu & Yu-Zhong Wang, 2023. "Non-flammable solvent-free liquid polymer electrolyte for lithium metal batteries," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    12. Navaratnarajah Kuganathan & Alexander Chroneos, 2020. "Lithium Storage in Nanoporous Complex Oxide 12CaO•7Al 2 O 3 (C12A7)," Energies, MDPI, vol. 13(7), pages 1-10, March.
    13. Zhi Chang & Huijun Yang & Anqiang Pan & Ping He & Haoshen Zhou, 2022. "An improved 9 micron thick separator for a 350 Wh/kg lithium metal rechargeable pouch cell," Nature Communications, Nature, vol. 13(1), pages 1-12, December.
    14. Zhu, Xiaoqing & Wang, Zhenpo & Wang, Yituo & Wang, Hsin & Wang, Cong & Tong, Lei & Yi, Mi, 2019. "Overcharge investigation of large format lithium-ion pouch cells with Li(Ni0.6Co0.2Mn0.2)O2 cathode for electric vehicles: Thermal runaway features and safety management method," Energy, Elsevier, vol. 169(C), pages 868-880.
    15. Wang, Wei & Wu, Yufeng, 2017. "An overview of recycling and treatment of spent LiFePO4 batteries in China," Resources, Conservation & Recycling, Elsevier, vol. 127(C), pages 233-243.
    16. Byungkwon Lim & Hyeon Sook Kim & Jaehwan Park, 2021. "Implicit Interpretation of Indonesian Export Bans on LME Nickel Prices: Evidence from the Announcement Effect," Risks, MDPI, vol. 9(5), pages 1-7, May.
    17. Ziyao Gao & Chenglong Zhao & Kai Zhou & Junru Wu & Yao Tian & Xianming Deng & Lihan Zhang & Kui Lin & Feiyu Kang & Lele Peng & Marnix Wagemaker & Baohua Li, 2024. "Kirkendall effect-induced uniform stress distribution stabilizes nickel-rich layered oxide cathodes," Nature Communications, Nature, vol. 15(1), pages 1-11, December.
    18. Xiaozhe Zhang & Pan Xu & Jianing Duan & Xiaodong Lin & Juanjuan Sun & Wenjie Shi & Hewei Xu & Wenjie Dou & Qingyi Zheng & Ruming Yuan & Jiande Wang & Yan Zhang & Shanshan Yu & Zehan Chen & Mingsen Zhe, 2024. "A dicarbonate solvent electrolyte for high performance 5 V-Class Lithium-based batteries," Nature Communications, Nature, vol. 15(1), pages 1-18, December.
    19. Pinelopi Angelopoulou & Spyros Kassavetis & Joan Papavasiliou & Dimitris Karfaridis & Grzegorz Słowik & Panos Patsalas & George Avgouropoulos, 2021. "Enhanced Performance of LiAl 0.1 Mn 1.9 O 4 Cathode for Li-Ion Battery via TiN Coating," Energies, MDPI, vol. 14(4), pages 1-14, February.
    20. Xinxin Wang & Jingjing Chen & Dajian Wang & Zhiyong Mao, 2021. "Improving the alkali metal electrode/inorganic solid electrolyte contact via room-temperature ultrasound solid welding," Nature Communications, Nature, vol. 12(1), pages 1-8, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:gam:jeners:v:15:y:2022:i:23:p:9235-:d:994772. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: MDPI Indexing Manager (email available below). General contact details of provider: https://www.mdpi.com .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.