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High-Rate Layered Cathode of Lithium-Ion Batteries through Regulating Three-Dimensional Agglomerated Structure

Author

Listed:
  • Jun-Ping Hu

    (School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China)

  • Hang Sheng

    (School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China)

  • Qi Deng

    (School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China)

  • Qiang Ma

    (School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China)

  • Jun Liu

    (School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China)

  • Xiong-Wei Wu

    (School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China)

  • Jun-Jie Liu

    (School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, China
    School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China)

  • Yu-Ping Wu

    (School of Energy Science and Engineering, Nanjing Tech University, Nanjing 211816, China)

Abstract

LiNi x Co y Mn z O 2 (LNCM)-layered materials are considered the most promising cathode for high-energy lithium ion batteries, but suffer from poor rate capability and short lifecycle. In addition, the LiNi 1/3 Co 1/3 Mn 1/3 O 2 (NCM 111) is considered one of the most widely used LNCM cathodes because of its high energy density and good safety. Herein, a kind of NCM 111 with semi-closed structure was designed by controlling the amount of urea, which possesses high rate capability and long lifespan, exhibiting 140.9 mAh·g −1 at 0.85 A·g −1 and 114.3 mAh·g −1 at 1.70 A·g −1 , respectively. The semi-closed structure is conducive to the infiltration of electrolytes and fast lithium ion-transfer inside the electrode material, thus improving the rate performance of the battery. Our work may provide an effective strategy for designing layered-cathode materials with high rate capability.

Suggested Citation

  • Jun-Ping Hu & Hang Sheng & Qi Deng & Qiang Ma & Jun Liu & Xiong-Wei Wu & Jun-Jie Liu & Yu-Ping Wu, 2020. "High-Rate Layered Cathode of Lithium-Ion Batteries through Regulating Three-Dimensional Agglomerated Structure," Energies, MDPI, vol. 13(7), pages 1-12, April.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:7:p:1602-:d:339862
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    References listed on IDEAS

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    1. Cornelius Satria Yudha & Soraya Ulfa Muzayanha & Hendri Widiyandari & Ferry Iskandar & Wahyudi Sutopo & Agus Purwanto, 2019. "Synthesis of LiNi 0.85 Co 0.14 Al 0.01 O 2 Cathode Material and its Performance in an NCA/Graphite Full-Battery," Energies, MDPI, vol. 12(10), pages 1-14, May.
    2. M. Armand & J.-M. Tarascon, 2008. "Building better batteries," Nature, Nature, vol. 451(7179), pages 652-657, February.
    3. Robert Bock & Morten Onsrud & Håvard Karoliussen & Bruno G. Pollet & Frode Seland & Odne S. Burheim, 2020. "Thermal Gradients with Sintered Solid State Electrolytes in Lithium-Ion Batteries," Energies, MDPI, vol. 13(1), pages 1-13, January.
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    Cited by:

    1. Ngoc Hung Vu & Van-Duong Dao & Ha Tran Huu & Won Bin Im, 2020. "Effect of Synthesis Temperature on Structure and Electrochemical Performance of Spinel-Layered Li 1.33 MnTiO 4 +z in Li-Ion Batteries," Energies, MDPI, vol. 13(11), pages 1-11, June.
    2. Ruixia Chu & Yujian Zou & Peidong Zhu & Shiwei Tan & Fangyuan Qiu & Wenjun Fu & Fu Niu & Wanyou Huang, 2022. "Progress of Single-Crystal Nickel-Cobalt-Manganese Cathode Research," Energies, MDPI, vol. 15(23), pages 1-32, December.
    3. Byungkwon Lim & Hyeon Sook Kim & Jaehwan Park, 2021. "Implicit Interpretation of Indonesian Export Bans on LME Nickel Prices: Evidence from the Announcement Effect," Risks, MDPI, vol. 9(5), pages 1-7, May.

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