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Biomass to Syngas: Modified Non-Stoichiometric Thermodynamic Models for the Downdraft Biomass Gasification

Author

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  • Hafiz Muhammad Uzair Ayub

    (Department of Chemical and Biochemical Engineering, Dongguk University, 30, Pildong-ro 1-gil, Jung-gu, Seoul 04623, Korea)

  • Sang Jin Park

    (Department of Chemical and Biochemical Engineering, Dongguk University, 30, Pildong-ro 1-gil, Jung-gu, Seoul 04623, Korea)

  • Michael Binns

    (Department of Chemical and Biochemical Engineering, Dongguk University, 30, Pildong-ro 1-gil, Jung-gu, Seoul 04623, Korea)

Abstract

Biomass gasification is the most reliable thermochemical conversion technology for the conversion of biomass into gaseous fuels such as H 2 , CO, and CH 4 . The performance of a gasification process can be estimated using thermodynamic equilibrium models. This type of model generally assumes the system reaches equilibrium, while in reality the system may only approach equilibrium leading to some errors between experimental and model results. In this study non-stoichiometric equilibrium models are modified and improved with correction factors inserted into the design equations so that when the Gibbs free energy is minimized model predictions will more closely match experimental values. The equilibrium models are implemented in MatLab and optimized based on experimental values from the literature using the optimization toolbox. The modified non-stoichiometric models are shown to be more accurate than unmodified models based on the calculated root mean square error values. These models can be applied for various types of solid biomass for the production of syngas through biomass gasification processes such as wood, agricultural, and crop residues.

Suggested Citation

  • Hafiz Muhammad Uzair Ayub & Sang Jin Park & Michael Binns, 2020. "Biomass to Syngas: Modified Non-Stoichiometric Thermodynamic Models for the Downdraft Biomass Gasification," Energies, MDPI, vol. 13(21), pages 1-17, October.
    • Handle: RePEc:gam:jeners:v:13:y:2020:i:21:p:5668-:d:436974
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    References listed on IDEAS

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    1. Michael Binns & Hafiz Muhammad Uzair Ayub, 2021. "Model Reduction Applied to Empirical Models for Biomass Gasification in Downdraft Gasifiers," Sustainability, MDPI, vol. 13(21), pages 1-14, November.
    2. Marco Puglia & Nicolò Morselli & Simone Pedrazzi & Paolo Tartarini & Giulio Allesina & Alberto Muscio, 2021. "Specific and Cumulative Exhaust Gas Emissions in Micro-Scale Generators Fueled by Syngas from Biomass Gasification," Sustainability, MDPI, vol. 13(6), pages 1-13, March.
    3. Jacek Grams, 2022. "Upgrading of Lignocellulosic Biomass to Hydrogen-Rich Gas," Energies, MDPI, vol. 16(1), pages 1-5, December.
    4. María Pilar González-Vázquez & Fernando Rubiera & Covadonga Pevida & Daniel T. Pio & Luís A.C. Tarelho, 2021. "Thermodynamic Analysis of Biomass Gasification Using Aspen Plus: Comparison of Stoichiometric and Non-Stoichiometric Models," Energies, MDPI, vol. 14(1), pages 1-17, January.
    5. Zhang, Jinchun & Hou, Jinxiu & Zhang, Zichuan, 2022. "Real-time identification of out-of-control and instability in process parameter for gasification process: Integrated application of control chart and kalman filter," Energy, Elsevier, vol. 238(PB).
    6. Silva, Isabelly P. & Lima, Rafael M.A. & Santana, Hortência E.P. & Silva, Gabriel F. & Ruzene, Denise S. & Silva, Daniel P., 2022. "Development of a semi-empirical model for woody biomass gasification based on stoichiometric thermodynamic equilibrium model," Energy, Elsevier, vol. 241(C).
    7. Fariha Kanwal & Ashfaq Ahmed & Farrukh Jamil & Sikander Rafiq & H. M. Uzair Ayub & Moinuddin Ghauri & M. Shahzad Khurram & Shahid Munir & Abrar Inayat & Muhammad S. Abu Bakar & Surendar Moogi & Su Shi, 2021. "Co-Combustion of Blends of Coal and Underutilised Biomass Residues for Environmental Friendly Electrical Energy Production," Sustainability, MDPI, vol. 13(9), pages 1-21, April.
    8. Valentina Segneri & Jean Henry Ferrasse & Antonio Trinca & Giorgio Vilardi, 2022. "An Overview of Waste Gasification and Syngas Upgrading Processes," Energies, MDPI, vol. 15(17), pages 1-7, September.
    9. Rafail Isemin & Fouzi Tabet & Artemy Nebyvaev & Vadim Kokh-Tatarenko & Sergey Kuzmin & Oleg Milovanov & Dmitry Klimov & Alexander Mikhalev & Semen Dobkin & Yuri Zhulaev, 2022. "Prediction of the Behavior of Sunflower Husk Ash after Its Processing by Various Torrefaction Methods," Energies, MDPI, vol. 15(20), pages 1-14, October.
    10. M. Shahabuddin & Sankar Bhattacharya, 2021. "Co-Gasification Characteristics of Coal and Biomass Using CO 2 Reactant under Thermodynamic Equilibrium Modelling," Energies, MDPI, vol. 14(21), pages 1-12, November.

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