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Electron transport analysis in zinc oxide-based dye-sensitized solar cells: A review

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  • Omar, Azimah
  • Abdullah, Huda

Abstract

This research review highlights the use of zinc oxide (ZnO) nanostructure as a photoanode in the fabrication of dye-sensitised solar cells (DSSC). ZnO nanostructure thin films offer large surface area, direct electron pathways and effective light scattering centre. The fabrication work can produce a variety of ZnO nanostructures, from nanotubes, nanoporous, nanosheets, nanoflowers, nanoflakes, nanobranches and nanolipsticks. The internal mechanism inside the cell gives useful information on the electron transport properties and efficiency of ZnO-based DSSC. The review ends with an outlook highlighting the electron transport parameters analysed by electrochemical impedance spectroscopy (EIS) unit. Such parameters including charge transport resistance (Rct), transport resistance (Rt), chemical capacitance (Cμ), effective electron lifetime (τeff), effective electron chemical diffusion coefficient (Deff), effective rate constant for recombination (keff), effective electron diffusion length of the photoanode (Ln) and finite Warburg impedance in the electrolyte (ZD). Monitoring the electron transport properties may improve the photovoltaic performances of the ZnO-based DSSC such as open circuit voltage (Voc), short circuit current density (Jsc), fill factor (FF) and power conversion efficiency (η).

Suggested Citation

  • Omar, Azimah & Abdullah, Huda, 2014. "Electron transport analysis in zinc oxide-based dye-sensitized solar cells: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 149-157.
    • Handle: RePEc:eee:rensus:v:31:y:2014:i:c:p:149-157
    DOI: 10.1016/j.rser.2013.11.031
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    References listed on IDEAS

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    1. Julian Burschka & Norman Pellet & Soo-Jin Moon & Robin Humphry-Baker & Peng Gao & Mohammad K. Nazeeruddin & Michael Grätzel, 2013. "Sequential deposition as a route to high-performance perovskite-sensitized solar cells," Nature, Nature, vol. 499(7458), pages 316-319, July.
    2. El Chaar, L. & lamont, L.A. & El Zein, N., 2011. "Review of photovoltaic technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(5), pages 2165-2175, June.
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    Cited by:

    1. Ali, N. & Hussain, A. & Ahmed, R. & Wang, M.K. & Zhao, C. & Haq, B. Ul & Fu, Y.Q., 2016. "Advances in nanostructured thin film materials for solar cell applications," Renewable and Sustainable Energy Reviews, Elsevier, vol. 59(C), pages 726-737.
    2. Parisi, Maria Laura & Maranghi, Simone & Basosi, Riccardo, 2014. "The evolution of the dye sensitized solar cells from Grätzel prototype to up-scaled solar applications: A life cycle assessment approach," Renewable and Sustainable Energy Reviews, Elsevier, vol. 39(C), pages 124-138.
    3. Sengupta, D. & Das, P. & Mondal, B. & Mukherjee, K., 2016. "Effects of doping, morphology and film-thickness of photo-anode materials for dye sensitized solar cell application – A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 60(C), pages 356-376.
    4. Mahalingam, S. & Abdullah, H., 2016. "Electron transport study of indium oxide as photoanode in DSSCs: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 63(C), pages 245-255.

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