IDEAS home Printed from https://ideas.repec.org/a/eee/rensus/v208y2025ics1364032124007263.html
   My bibliography  Save this article

Low-temperature and reversible hydrogen storage advances of light metal borohydrides

Author

Listed:
  • Wang, Shun
  • Li, Zhenglong
  • Gao, Mingxia
  • Liu, Yongfeng
  • Pan, Hongge

Abstract

Solid-state light metal borohydrides represented by LiBH4, NaBH4, Mg(BH4)2, and Ca(BH4)2 with high hydrogen capacity are promising media to store and transport hydrogen safely and efficiently, raising a hope for popularizing electricity-hydrogen coupling systems built on clean and renewable energy. Yet stable thermodynamics and sluggish kinetics of light metal borohydrides remain two key issues to be addressed for achieving the rapid and reversible hydrogen desorption and absorption under mild conditions. In this review, the short introductions for basic hydrogen storage characteristics of light metal borohydrides and fundamental principles of common thermodynamic and kinetic modification strategies are first presented. Then the focus is on the research advances in reducing operation temperature, accelerating reaction rates, and enhancing cyclic reversibility of light metal borohydrides by using these strategies or their synergy. On this basis, the existing challenges and future directions on light metal borohydrides are proposed from novel and specific perspectives, aiming to obtain high performance hydrogen storage materials practically available towards electricity-hydrogen coupling systems.

Suggested Citation

  • Wang, Shun & Li, Zhenglong & Gao, Mingxia & Liu, Yongfeng & Pan, Hongge, 2025. "Low-temperature and reversible hydrogen storage advances of light metal borohydrides," Renewable and Sustainable Energy Reviews, Elsevier, vol. 208(C).
    • Handle: RePEc:eee:rensus:v:208:y:2025:i:c:s1364032124007263
    DOI: 10.1016/j.rser.2024.115000
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S1364032124007263
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.rser.2024.115000?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Omer, Abdeen Mustafa, 2008. "Energy, environment and sustainable development," Renewable and Sustainable Energy Reviews, Elsevier, vol. 12(9), pages 2265-2300, December.
    2. Cezar Comanescu, 2023. "Calcium Borohydride Ca(BH 4 ) 2 : Fundamentals, Prediction and Probing for High-Capacity Energy Storage Applications, Organic Synthesis and Catalysis," Energies, MDPI, vol. 16(11), pages 1-34, June.
    3. Risco-Bravo, A. & Varela, C. & Bartels, J. & Zondervan, E., 2024. "From green hydrogen to electricity: A review on recent advances, challenges, and opportunities on power-to-hydrogen-to-power systems," Renewable and Sustainable Energy Reviews, Elsevier, vol. 189(PA).
    4. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    5. Mazloomi, Kaveh & Gomes, Chandima, 2012. "Hydrogen as an energy carrier: Prospects and challenges," Renewable and Sustainable Energy Reviews, Elsevier, vol. 16(5), pages 3024-3033.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Pashchenko, Dmitry, 2023. "Hydrogen-rich gas as a fuel for the gas turbines: A pathway to lower CO2 emission," Renewable and Sustainable Energy Reviews, Elsevier, vol. 173(C).
    2. Burton, N.A. & Padilla, R.V. & Rose, A. & Habibullah, H., 2021. "Increasing the efficiency of hydrogen production from solar powered water electrolysis," Renewable and Sustainable Energy Reviews, Elsevier, vol. 135(C).
    3. Anna Laura Pisello & Gloria Pignatta & Veronica Lucia Castaldo & Franco Cotana, 2014. "Experimental Analysis of Natural Gravel Covering as Cool Roofing and Cool Pavement," Sustainability, MDPI, vol. 6(8), pages 1-17, July.
    4. Tutar, Halit & Eren, Ömer & Er, Hasan & Gonulal, Erdal & Gokdogan, Osman, 2025. "Field-based experimental greenhouse gas emissions and energy use efficiency study of sorghum x sudan grass hybrid growth in a semi-arid region," Energy, Elsevier, vol. 315(C).
    5. Chung, Kyong-Hwan, 2010. "High-pressure hydrogen storage on microporous zeolites with varying pore properties," Energy, Elsevier, vol. 35(5), pages 2235-2241.
    6. Anna Barwińska Małajowicz & Miroslava Knapková & Krzysztof Szczotka & Miriam Martinkovičová & Radosław Pyrek, 2022. "Energy Efficiency Policies in Poland and Slovakia in the Context of Individual Well-Being," Energies, MDPI, vol. 16(1), pages 1-29, December.
    7. Deng, Cheng-gang & Chen, Fei, 2021. "Model verification and photo-thermal conversion assessment of a novel facade embedded compound parabolic concentrator," Energy, Elsevier, vol. 220(C).
    8. Toledo, Olga Moraes & Oliveira Filho, Delly & Diniz, Antônia Sônia Alves Cardoso, 2010. "Distributed photovoltaic generation and energy storage systems: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 506-511, January.
    9. Baležentis, Alvydas & Baležentis, Tomas & Streimikiene, Dalia, 2011. "The energy intensity in Lithuania during 1995–2009: A LMDI approach," Energy Policy, Elsevier, vol. 39(11), pages 7322-7334.
    10. Lee, Boreum & Park, Junhyung & Lee, Hyunjun & Byun, Manhee & Yoon, Chang Won & Lim, Hankwon, 2019. "Assessment of the economic potential: COx-free hydrogen production from renewables via ammonia decomposition for small-sized H2 refueling stations," Renewable and Sustainable Energy Reviews, Elsevier, vol. 113(C), pages 1-1.
    11. Navas-Anguita, Zaira & García-Gusano, Diego & Iribarren, Diego, 2019. "A review of techno-economic data for road transportation fuels," Renewable and Sustainable Energy Reviews, Elsevier, vol. 112(C), pages 11-26.
    12. Zoltan Varga & Ervin Racz, 2022. "Machine Learning Analysis on the Performance of Dye-Sensitized Solar Cell—Thermoelectric Generator Hybrid System," Energies, MDPI, vol. 15(19), pages 1-18, October.
    13. Murshed, Muntasir, 2019. "Trade Liberalization Policies and Renewable Energy Transition in Low and Middle-Income Countries? An Instrumental Variable Approach," MPRA Paper 97075, University Library of Munich, Germany.
    14. Houljakbe Houlteurbe Dagou & Asli Pelin Gurgun & Kerim Koc & Cenk Budayan, 2025. "The Future of Construction: Integrating Innovative Technologies for Smarter Project Management," Sustainability, MDPI, vol. 17(10), pages 1-31, May.
    15. Dixon, Christopher & Reynolds, Steve & Rodley, David, 2016. "Micro/small wind turbine power control for electrolysis applications," Renewable Energy, Elsevier, vol. 87(P1), pages 182-192.
    16. Kumar, Yogesh & Ringenberg, Jordan & Depuru, Soma Shekara & Devabhaktuni, Vijay K. & Lee, Jin Woo & Nikolaidis, Efstratios & Andersen, Brett & Afjeh, Abdollah, 2016. "Wind energy: Trends and enabling technologies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 53(C), pages 209-224.
    17. Fukunaga, Akihiko & Kato, Asami & Hara, Yuki & Matsumoto, Takaya, 2023. "Dehydrogenation of methylcyclohexane using solid oxide fuel cell – A smart energy conversion," Applied Energy, Elsevier, vol. 348(C).
    18. Andrea Pianella & Lu Aye & Zhengdong Chen & Nicholas S. G. Williams, 2017. "Substrate Depth, Vegetation and Irrigation Affect Green Roof Thermal Performance in a Mediterranean Type Climate," Sustainability, MDPI, vol. 9(8), pages 1-19, August.
    19. Toyoto Sato & Shin-ichi Orimo, 2021. "The Crystal Structures in Hydrogen Absorption Reactions of REMgNi 4 -Based Alloys (RE: Rare-Earth Metals)," Energies, MDPI, vol. 14(23), pages 1-10, December.
    20. Radu-George Ciocarlan & Judit Farrando-Perez & Daniel Arenas-Esteban & Maarten Houlleberghs & Luke L. Daemen & Yongqiang Cheng & Anibal J. Ramirez-Cuesta & Eric Breynaert & Johan Martens & Sara Bals &, 2024. "Tuneable mesoporous silica material for hydrogen storage application via nano-confined clathrate hydrate construction," Nature Communications, Nature, vol. 15(1), pages 1-8, December.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:rensus:v:208:y:2025:i:c:s1364032124007263. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.elsevier.com/wps/find/journaldescription.cws_home/600126/description#description .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.