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Microalgae as a renewable fuel source: Fast pyrolysis of Scenedesmus sp

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  • Harman-Ware, Anne E.
  • Morgan, Tonya
  • Wilson, Michael
  • Crocker, Mark
  • Zhang, Jun
  • Liu, Kunlei
  • Stork, Jozsef
  • Debolt, Seth

Abstract

Herein we report the fast pyrolysis of dried, ground Scenedesmus sp. at two different reactor scales. Pyrolysis was performed at 480 °C and 1 bar in both an isothermal spouted bed reactor and a dynamic pyrolysis-GC/MS unit, each with 2 s vapor residence times. Bio-oil products were characterized on the basis of GC-MS, simulated distillation GC, elemental analysis, calorific content and total acid number. The ratio of crude oil: char obtained from the spouted bed reactor was 3.76 by weight, the average calorific content of the oil being 18.4 MJ/kg. The average total acid number (68 mg KOH/g) was lower than typical bio-oil produced via wood pyrolysis. Simulated distillation results indicated that a significant proportion of the oil corresponded to the boiling range typical for heavy gas oil (343 °C–524 °C). Elemental analysis showed the oil contained an average of 27.6 wt.% oxygen and 8.6 wt.% nitrogen, the relatively high nitrogen content being a consequence of the high protein content of the algae. According to GC-MS data, the oil consisted of various hydrocarbons as well as oxygenated and nitrogenous species, including indoles, fatty acids and amides. Pyrolysis-GC-MS was also performed on Scenedesmus sp. in order to provide insights into the nature of the primary pyrolysis products.

Suggested Citation

  • Harman-Ware, Anne E. & Morgan, Tonya & Wilson, Michael & Crocker, Mark & Zhang, Jun & Liu, Kunlei & Stork, Jozsef & Debolt, Seth, 2013. "Microalgae as a renewable fuel source: Fast pyrolysis of Scenedesmus sp," Renewable Energy, Elsevier, vol. 60(C), pages 625-632.
    • Handle: RePEc:eee:renene:v:60:y:2013:i:c:p:625-632
    DOI: 10.1016/j.renene.2013.06.016
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