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Metal hydride-based hydrogen production and storage system for stationary applications powered by renewable sources

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  • Rangel, C.M.
  • Fernandes, V.R.
  • Gano, A.J.

Abstract

In this work, a compact and low-cost electrochemical laboratory prototype for the storage and production of hydrogen, based on metallic hydrides, with high reversibility in the charge/discharge process is demonstrated, using electricity either from the grid or by direct coupling to renewable energies as power source. The reactor is a 316 L stainless steel vessel with a capacity up to 15 bar internal pressure. It includes working electrodes of alloy LaNi4.3Co0.4Al0.3 and counter-electrodes of Ni foam in an electrolyte solution of 35% KOH. The reactor uses unicellular/multicellular configurations, so that the overall capacity of the system can be extended by increasing the number of working electrodes, resulting in a highly modular system. Results show excellent linearity, reversibility, and stability under cycling at room temperature and pressure, demonstrated either when powered by the grid or by off-grid renewable energy. Furthermore, criteria were established for the quantification of the state of full charge and full discharge. The system was integrated with a custom electronic system, developed in-house for monitoring and control the reactor and to optimize the performance and energy efficiency of the hydrogen storage and discharge processes.

Suggested Citation

  • Rangel, C.M. & Fernandes, V.R. & Gano, A.J., 2022. "Metal hydride-based hydrogen production and storage system for stationary applications powered by renewable sources," Renewable Energy, Elsevier, vol. 197(C), pages 398-405.
    • Handle: RePEc:eee:renene:v:197:y:2022:i:c:p:398-405
    DOI: 10.1016/j.renene.2022.07.103
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    References listed on IDEAS

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    1. Mohammadi, Amin & Mehrpooya, Mehdi, 2018. "A comprehensive review on coupling different types of electrolyzer to renewable energy sources," Energy, Elsevier, vol. 158(C), pages 632-655.
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    3. Hassan, I.A. & Ramadan, Haitham S. & Saleh, Mohamed A. & Hissel, Daniel, 2021. "Hydrogen storage technologies for stationary and mobile applications: Review, analysis and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
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    2. Mou, Xiaofeng & Zhou, Wei & Bao, Zewei & Huang, Weixing, 2024. "Effective thermal conductivity of LaNi5 powder beds for hydrogen storage: Measurement and theoretical analysis," Renewable Energy, Elsevier, vol. 231(C).
    3. Maestre, V.M. & Ortiz, A. & Ortiz, I., 2024. "Sustainable and self-sufficient social home through a combined PV‑hydrogen pilot," Applied Energy, Elsevier, vol. 363(C).

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