IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v184y2022icp460-472.html

Dehydrogenation of ammonia borane recrystallized by different techniques

Author

Listed:
  • Komova, O.V.
  • Simagina, V.I.
  • Butenko, V.R.
  • Odegova, G.V.
  • Bulavchenko, O.A.
  • Nikolaeva, O.A.
  • Ozerova, A.M.
  • Lipatnikova, I.L.
  • Tayban, E.S.
  • Mukha, S.A.
  • Netskina, O.V.

Abstract

The literature shows that practically no attention has been paid to the size and shape of the particles of bulk ammonia borane (NH3BH3). The published results about the influence of the dispersity of this hydride on its dehydrogenation are not numerous and contradictory. This work presents new results on the low-temperature solid-state dehydrogenation of bulk NH3BH3. The samples under study were recrystallized using different procedures and had, therefore, different particle characteristics. The reactivity of these samples of NH3BH3 was compared on the basis of thermal analysis data obtained under non-isothermal conditions, including the Kissinger kinetics, and H2 evolution under isothermal conditions (84–96°С) using Avrami-Erofeev kinetics. The finely dispersed sample with a particle size of <40 μm was found to be the most active one. A correlation between the NH3BH3 melting temperature and the temperature of its dehydrogenation has been established. A filamentous NH3BH3 with a length-to-thickness ratio of the filaments of >100 was synthesized and described for the first time. It was suggested that its relatively high reactivity was determined by its ordered structure. These results show the importance of further investigations of bulk ammonia borane with different types of particles.

Suggested Citation

  • Komova, O.V. & Simagina, V.I. & Butenko, V.R. & Odegova, G.V. & Bulavchenko, O.A. & Nikolaeva, O.A. & Ozerova, A.M. & Lipatnikova, I.L. & Tayban, E.S. & Mukha, S.A. & Netskina, O.V., 2022. "Dehydrogenation of ammonia borane recrystallized by different techniques," Renewable Energy, Elsevier, vol. 184(C), pages 460-472.
    • Handle: RePEc:eee:renene:v:184:y:2022:i:c:p:460-472
    DOI: 10.1016/j.renene.2021.11.119
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121017146
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.11.119?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to

    for a different version of it.

    References listed on IDEAS

    as
    1. Tunç, Nihat & Rakap, Murat, 2020. "Preparation and characterization of Ni-M (M: Ru, Rh, Pd) nanoclusters as efficient catalysts for hydrogen evolution from ammonia borane methanolysis," Renewable Energy, Elsevier, vol. 155(C), pages 1222-1230.
    2. Gorlova, A.M. & Kayl, N.L. & Komova, O.V. & Netskina, O.V. & Ozerova, A.M. & Odegova, G.V. & Bulavchenko, O.A. & Ishchenko, A.V. & Simagina, V.I., 2018. "Fast hydrogen generation from solid NH3BH3 under moderate heating and supplying a limited quantity of CoCl2 or NiCl2 solution," Renewable Energy, Elsevier, vol. 121(C), pages 722-729.
    3. Zhao, Liqing & Wei, Qinghe & Zhang, Lili & Zhao, Yafei & Zhang, Bing, 2021. "NiCo alloy decorated on porous N-doped carbon derived from ZnCo-ZIF as highly efficient and magnetically recyclable catalyst for hydrogen evolution from ammonia borane," Renewable Energy, Elsevier, vol. 173(C), pages 273-282.
    4. Lee, Chi-Hang & Filler, Robert & Lee, JeongYong & Li, Jing & Mandal, Braja K., 2010. "Synthesis and hydrogen adsorption properties of a new phthalocyanine-based metal–organic framework," Renewable Energy, Elsevier, vol. 35(7), pages 1592-1595.
    5. Zhang, J. & He, L. & Yao, Y. & Zhou, X.J. & Yu, L.P. & Lu, X.Z. & Zhou, D.W., 2020. "Catalytic effect and mechanism of NiCu solid solutions on hydrogen storage properties of MgH2," Renewable Energy, Elsevier, vol. 154(C), pages 1229-1239.
    6. Umit Bilge Demirci, 2020. "Ammonia Borane: An Extensively Studied, Though Not Yet Implemented, Hydrogen Carrier," Energies, MDPI, vol. 13(12), pages 1-45, June.
    7. Daud, W.R.W. & Rosli, R.E. & Majlan, E.H. & Hamid, S.A.A. & Mohamed, R. & Husaini, T., 2017. "PEM fuel cell system control: A review," Renewable Energy, Elsevier, vol. 113(C), pages 620-638.
    8. Hassan, I.A. & Ramadan, Haitham S. & Saleh, Mohamed A. & Hissel, Daniel, 2021. "Hydrogen storage technologies for stationary and mobile applications: Review, analysis and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 149(C).
    9. Matsunaga, T. & Buchter, F. & Miwa, K. & Towata, S. & Orimo, S. & Züttel, A., 2008. "Magnesium borohydride: A new hydrogen storage material," Renewable Energy, Elsevier, vol. 33(2), pages 193-196.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Zhao, Liqing & Wei, Qinghe & Zhang, Lili & Zhao, Yafei & Zhang, Bing, 2021. "NiCo alloy decorated on porous N-doped carbon derived from ZnCo-ZIF as highly efficient and magnetically recyclable catalyst for hydrogen evolution from ammonia borane," Renewable Energy, Elsevier, vol. 173(C), pages 273-282.
    2. Bizon, Nicu, 2019. "Real-time optimization strategies of Fuel Cell Hybrid Power Systems based on Load-following control: A new strategy, and a comparative study of topologies and fuel economy obtained," Applied Energy, Elsevier, vol. 241(C), pages 444-460.
    3. Solanki, Bhanupratap Singh & Lim, Hoyoung & Yoon, Seok Jun & Ham, Hyung Chul & Park, Han Saem & Lee, Ha Eun & Lee, See Hoon, 2025. "Recent advancement of non-noble metal catalysts for hydrogen production by NH3 decomposition," Renewable and Sustainable Energy Reviews, Elsevier, vol. 207(C).
    4. Wu, Kangcheng & Du, Qing & Zu, Bingfeng & Wang, Yupeng & Cai, Jun & Gu, Xin & Xuan, Jin & Jiao, Kui, 2021. "Enabling real-time optimization of dynamic processes of proton exchange membrane fuel cell: Data-driven approach with semi-recurrent sliding window method," Applied Energy, Elsevier, vol. 303(C).
    5. Bizon, Nicu, 2019. "Efficient fuel economy strategies for the Fuel Cell Hybrid Power Systems under variable renewable/load power profile," Applied Energy, Elsevier, vol. 251(C), pages 1-1.
    6. Che Lah, Nurul Akmal, 2021. "Late transition metal nanocomplexes: Applications for renewable energy conversion and storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    7. Zhang, Rui & Cao, Xuewen & Zhang, Xingwang & Yang, Jian & Bian, Jiang, 2024. "Co-benefits of the liquid hydrogen economy and LNG economy: Advances in LNG integrating LH2 production processes," Energy, Elsevier, vol. 301(C).
    8. Zhu, Haohao & Wang, Xiluo & Wen, Yutong & Zhu, Jizhong & Li, Jiayi & Luo, Qingju & Liao, Chenlei, 2025. "A review of integrated energy system modeling and operation," Applied Energy, Elsevier, vol. 400(C).
    9. Rey, I. & Barrio, V.L. & Agirre, I., 2025. "Environmental and economic assessment of large-scale hydrogen supply chains across Europe: LOHC vs other hydrogen technologies," Applied Energy, Elsevier, vol. 401(PC).
    10. Nicu Bizon & Mircea Raceanu & Emmanouel Koudoumas & Adriana Marinoiu & Emmanuel Karapidakis & Elena Carcadea, 2020. "Renewable/Fuel Cell Hybrid Power System Operation Using Two Search Controllers of the Optimal Power Needed on the DC Bus," Energies, MDPI, vol. 13(22), pages 1-26, November.
    11. Ren, Lei & Zhou, Sheng & Peng, Tianduo & Ou, Xunmin, 2022. "Greenhouse gas life cycle analysis of China's fuel cell medium- and heavy-duty trucks under segmented usage scenarios and vehicle types," Energy, Elsevier, vol. 249(C).
    12. Elkholy, M.H. & Metwally, Hamid & Farahat, M.A. & Senjyu, Tomonobu & Elsayed Lotfy, Mohammed, 2022. "Smart centralized energy management system for autonomous microgrid using FPGA," Applied Energy, Elsevier, vol. 317(C).
    13. Raguman, Abdul & Vedagiri, Praveena, 2025. "Preparation and characterization of Juglans regia shell-based nanofluid for enhanced cooling in polymer electrolyte membrane fuel cells," Energy, Elsevier, vol. 331(C).
    14. Çakanyıldırım, Çetin & Gürü, Metin, 2009. "Production of NaBH4 and hydrogen release with catalyst," Renewable Energy, Elsevier, vol. 34(11), pages 2362-2365.
    15. Won, Jinyeon & Oh, Hwanyeong & Hong, Jongsup & Kim, Minjin & Lee, Won-Yong & Choi, Yoon-Young & Han, Soo-Bin, 2021. "Hybrid diagnosis method for initial faults of air supply systems in proton exchange membrane fuel cells," Renewable Energy, Elsevier, vol. 180(C), pages 343-352.
    16. Deng, Zhihua & Miao, Bin & Cui, Yunjia & Chen, Jian & Pan, Zehua & Liu, Hao & Deendarlianto, Deendarlianto & Suwarno, Suwarno & Chan, Siew Hwa, 2025. "Towards high-performance fuel cell systems: Comprehensive review of methods for modeling, control, and optimization," Renewable and Sustainable Energy Reviews, Elsevier, vol. 224(C).
    17. Cao, Qiang & Chen, Yuji & Wang, Zhiping & Wang, Miaomiao & Wang, Pengcheng & Ge, Lichun & Li, Peng & Zhao, Qinyu & Wang, Bo & Gan, Zhihua, 2025. "Improving the cooling efficiency of cryo-compressed hydrogen based on the temperature-distributed method in regenerative refrigerators," Energy, Elsevier, vol. 314(C).
    18. Luo, Yuqin & Yin, Cong, 2025. "Dynamic performance prediction of multi-cell proton exchange membrane fuel cells with a hybrid machine learning method," Energy, Elsevier, vol. 338(C).
    19. Quan, Shengwei & Wang, Ya-Xiong & Xiao, Xuelian & He, Hongwen & Sun, Fengchun, 2021. "Feedback linearization-based MIMO model predictive control with defined pseudo-reference for hydrogen regulation of automotive fuel cells," Applied Energy, Elsevier, vol. 293(C).
    20. Fragiacomo, Petronilla & Martorelli, Michele & Genovese, Matteo & Piraino, Francesco & Corigliano, Orlando, 2024. "Thermodynamic modelling, testing and sensitive analysis of a directly pressurized hydrogen refuelling process with a compressor," Renewable Energy, Elsevier, vol. 226(C).

    More about this item

    Keywords

    ;
    ;
    ;
    ;
    ;
    ;
    ;

    Statistics

    Access and download statistics

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:184:y:2022:i:c:p:460-472. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.