IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v121y2018icp722-729.html
   My bibliography  Save this article

Fast hydrogen generation from solid NH3BH3 under moderate heating and supplying a limited quantity of CoCl2 or NiCl2 solution

Author

Listed:
  • Gorlova, A.M.
  • Kayl, N.L.
  • Komova, O.V.
  • Netskina, O.V.
  • Ozerova, A.M.
  • Odegova, G.V.
  • Bulavchenko, O.A.
  • Ishchenko, A.V.
  • Simagina, V.I.

Abstract

New results of an investigation of NH3BH3 dehydrogenation with supplying a limited quantity of aqueous solution of a catalyst precursor to a solid-state bed of the hydride particles with subsequent external heating at 40–90 °C are presented. Measurements of the reaction layer temperature and the amount of the evolved hydrogen have shown that at external heating temperature higher than 85°С there was acceleration of the first stage of the process, the highly exothermic catalytic hydrolysis of a portion of ammonia borane, which resulted in a stronger heating of the reaction layer and the start of NH3BH3 thermolysis. This type of process is referred to as hydrothermolysis. A TEM, ATR FTIR, and XRD investigation has shown that in the reaction medium the metal chlorides become reduced to an amorphous catalytically active phase. During this process, ammonia reacts with chlorides to form NH4Cl. All of this leads to increased rate of hydrogen generation and hydrogen yield. Gravimetric hydrogen capacity of 7.6 wt% and the average rate of H2 evolution of 39 ml·gcomp.−1min−1 have been achieved at molar ratios of NH3BH3/MCl2 = 50 (M = Co, Ni) and H2O/NH3BH3 = 2 and at external heating of 85°С.

Suggested Citation

  • Gorlova, A.M. & Kayl, N.L. & Komova, O.V. & Netskina, O.V. & Ozerova, A.M. & Odegova, G.V. & Bulavchenko, O.A. & Ishchenko, A.V. & Simagina, V.I., 2018. "Fast hydrogen generation from solid NH3BH3 under moderate heating and supplying a limited quantity of CoCl2 or NiCl2 solution," Renewable Energy, Elsevier, vol. 121(C), pages 722-729.
    • Handle: RePEc:eee:renene:v:121:y:2018:i:c:p:722-729
    DOI: 10.1016/j.renene.2018.01.089
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148118300995
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2018.01.089?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Weng, Baicheng & Wu, Zhu & Li, Zhilin & Yang, Hui, 2012. "Hydrogen generation from hydrolysis of MNH2BH3 and NH3BH3/MH (M=Li, Na) for fuel cells based unmanned submarine vehicles application," Energy, Elsevier, vol. 38(1), pages 205-211.
    2. Niaz, Saba & Manzoor, Taniya & Pandith, Altaf Hussain, 2015. "Hydrogen storage: Materials, methods and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 50(C), pages 457-469.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Komova, O.V. & Simagina, V.I. & Butenko, V.R. & Odegova, G.V. & Bulavchenko, O.A. & Nikolaeva, O.A. & Ozerova, A.M. & Lipatnikova, I.L. & Tayban, E.S. & Mukha, S.A. & Netskina, O.V., 2022. "Dehydrogenation of ammonia borane recrystallized by different techniques," Renewable Energy, Elsevier, vol. 184(C), pages 460-472.
    2. Zhao, Liqing & Wei, Qinghe & Zhang, Lili & Zhao, Yafei & Zhang, Bing, 2021. "NiCo alloy decorated on porous N-doped carbon derived from ZnCo-ZIF as highly efficient and magnetically recyclable catalyst for hydrogen evolution from ammonia borane," Renewable Energy, Elsevier, vol. 173(C), pages 273-282.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Alina E. Kozhukhova & Stephanus P. du Preez & Dmitri G. Bessarabov, 2021. "Catalytic Hydrogen Combustion for Domestic and Safety Applications: A Critical Review of Catalyst Materials and Technologies," Energies, MDPI, vol. 14(16), pages 1-32, August.
    2. Ye, Yang & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2020. "Numerical simulation on the storage performance of a phase change materials based metal hydride hydrogen storage tank," Applied Energy, Elsevier, vol. 278(C).
    3. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.
    4. Zhang, Huaiwei & Bao, Liang & Qi, Jianbo & Xuan, Weidong & Fu, Li & Yuan, Yongjun, 2020. "Effects of nano-molybdenum coatings on the hydrogen storage properties of La–Mg–Ni based alloys," Renewable Energy, Elsevier, vol. 157(C), pages 1053-1060.
    5. Ye, Yang & Yue, Yi & Lu, Jianfeng & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "Enhanced hydrogen storage of a LaNi5 based reactor by using phase change materials," Renewable Energy, Elsevier, vol. 180(C), pages 734-743.
    6. Azadeh Maroufmashat & Michael Fowler, 2017. "Transition of Future Energy System Infrastructure; through Power-to-Gas Pathways," Energies, MDPI, vol. 10(8), pages 1-22, July.
    7. Ye, Yang & Ding, Jing & Wang, Weilong & Yan, Jinyue, 2021. "The storage performance of metal hydride hydrogen storage tanks with reaction heat recovery by phase change materials," Applied Energy, Elsevier, vol. 299(C).
    8. Sara Stelitano & Giuseppe Conte & Alfonso Policicchio & Alfredo Aloise & Giovanni Desiderio & Raffaele G. Agostino, 2020. "Pinecone-Derived Activated Carbons as an Effective Medium for Hydrogen Storage," Energies, MDPI, vol. 13(9), pages 1-16, May.
    9. Muhammad Aziz & Agung Tri Wijayanta & Asep Bayu Dani Nandiyanto, 2020. "Ammonia as Effective Hydrogen Storage: A Review on Production, Storage and Utilization," Energies, MDPI, vol. 13(12), pages 1-25, June.
    10. Montazerinejad, H. & Eicker, U., 2022. "Recent development of heat and power generation using renewable fuels: A comprehensive review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 165(C).
    11. Reuß, Markus & Grube, Thomas & Robinius, Martin & Stolten, Detlef, 2019. "A hydrogen supply chain with spatial resolution: Comparative analysis of infrastructure technologies in Germany," Applied Energy, Elsevier, vol. 247(C), pages 438-453.
    12. Wang, Cong & Feng, Yu & Liu, Zekuan & Wang, Yilin & Fang, Jiwei & Qin, Jiang & Shao, Jiahui & Huang, Hongyan, 2022. "Assessment of thermodynamic performance and CO2 emission reduction for a supersonic precooled turbine engine cycle fueled with a new green fuel of ammonia," Energy, Elsevier, vol. 261(PA).
    13. Perčić, Maja & Vladimir, Nikola & Fan, Ailong, 2021. "Techno-economic assessment of alternative marine fuels for inland shipping in Croatia," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    14. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah, 2014. "Hydrogen production through hydrolysis of sodium borohydride: Oleic acid stabilized Co–La–Zr–B nanoparticle as a novel catalyst," Energy, Elsevier, vol. 68(C), pages 152-159.
    15. Hanley, Emma S. & Deane, JP & Gallachóir, BP Ó, 2018. "The role of hydrogen in low carbon energy futures–A review of existing perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3027-3045.
    16. Zheng, Jianpeng & Chen, Liubiao & Liu, Xuming & Zhu, Honglai & Zhou, Yuan & Wang, Junjie, 2020. "Thermodynamic optimization of composite insulation system with cold shield for liquid hydrogen zero-boil-off storage," Renewable Energy, Elsevier, vol. 147(P1), pages 824-832.
    17. Lutz, Michael & Linder, Marc & Bürger, Inga, 2020. "High capacity, low pressure hydrogen storage based on magnesium hydride and thermochemical heat storage: Experimental proof of concept," Applied Energy, Elsevier, vol. 271(C).
    18. Sreedhar, I. & Kamani, Krutarth M. & Kamani, Bansi M. & Reddy, Benjaram M. & Venugopal, A., 2018. "A Bird's Eye view on process and engineering aspects of hydrogen storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 91(C), pages 838-860.
    19. Morales-Ospino, R. & Celzard, A. & Fierro, V., 2023. "Strategies to recover and minimize boil-off losses during liquid hydrogen storage," Renewable and Sustainable Energy Reviews, Elsevier, vol. 182(C).
    20. Bhandari, Ramchandra & Shah, Ronak Rakesh, 2021. "Hydrogen as energy carrier: Techno-economic assessment of decentralized hydrogen production in Germany," Renewable Energy, Elsevier, vol. 177(C), pages 915-931.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:121:y:2018:i:c:p:722-729. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.