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Evaluation of oxidative stability of soybean biodiesel using ethanolic and chloroform extracts of Platymiscium floribundum as antioxidant

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  • Nogueira, Tiago Rocha
  • de Mesquita Figueredo, Igor
  • Tavares Luna, Francisco Murilo
  • Cavalcante, Célio Loureiro
  • Evangelista de Ávila dos Santos, João
  • Sousa Lima, Mary Anne
  • Josino da Silva, Thiala Soares
  • Almeida Moreira Leal, Luzia Kalyne
  • Nunes, Fátima Miranda
  • Alexsandra de Sousa Rios, Maria
  • Ávila Pimenta, Antônia Torres

Abstract

The objective of this work was to evaluate the effect of Platymiscium floribundum ethanolic and chloroform extracts on the oxidative stability of soybean biodiesel using the Rancimat and DSC methods. The soybean biodiesel was obtained by transesterification. The antioxidant activity of the extracts was also evaluated by the free radical scavenging (DPPH) method and the total phenolic content by the Folin-Ciocalteu method. Both extracts showed antioxidant activity, reducing the DPPH by about 90%, and the total phenolic content of the ethanolic and chloroform extracts were 2.87 and 3.10 mg GAE/100 mg of extract, respectively. The extracts showed to be very efficient in retarding the oxidation of soybean biodiesel since the induction period increased from 4.53 h to 18.09 h (PF–EtOH, 10000 mg/kg) and 17.58 h (PF–CHCl3, 10000 mg/kg). Both extracts showed high thermal stability with Ton-e of 405.76 °C (PF–CHCl3) and 396.79 °C (PF–EtOH). The presence of the extracts increased the activation energy of the samples between 12.3% and 37.0%. The increase of the activation energy represents an improvement of the oxidative stability of biodiesel. All results confirmed the action of the antioxidants present in the extracts on controlling the oxidation reactions in biodiesel.

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  • Nogueira, Tiago Rocha & de Mesquita Figueredo, Igor & Tavares Luna, Francisco Murilo & Cavalcante, Célio Loureiro & Evangelista de Ávila dos Santos, João & Sousa Lima, Mary Anne & Josino da Silva, Thi, 2020. "Evaluation of oxidative stability of soybean biodiesel using ethanolic and chloroform extracts of Platymiscium floribundum as antioxidant," Renewable Energy, Elsevier, vol. 159(C), pages 767-774.
    • Handle: RePEc:eee:renene:v:159:y:2020:i:c:p:767-774
    DOI: 10.1016/j.renene.2020.06.062
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    References listed on IDEAS

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    1. Rial, Rafael Cardoso & de Freitas, Osmar Nunes & Santos, Gemima dos & Nazário, Carlos Eduardo Domingues & Viana, Luíz Henrique, 2019. "Evaluation of the oxidative and thermal stability of soybean methyl biodiesel with additions of dichloromethane extract ginger (Zingiber officinale Roscoe)," Renewable Energy, Elsevier, vol. 143(C), pages 295-300.
    2. Cavalheiro, Leandro Fontoura & Misutsu, Marcelo Yukio & Rial, Rafael Cardoso & Viana, Luíz Henrique & Oliveira, Lincoln Carlos Silva, 2020. "Characterization of residues and evaluation of the physico chemical properties of soybean biodiesel and biodiesel: Diesel blends in different storage conditions," Renewable Energy, Elsevier, vol. 151(C), pages 454-462.
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    4. Rodrigues, Jailson Silva & do Valle, Camila Peixoto & Uchoa, Antonia Flávia Justino & Ramos, Denise Moreira & da Ponte, Flávio Albuquerque Ferreira & Rios, Maria Alexsandra de Sousa & de Queiroz Malve, 2020. "Comparative study of synthetic and natural antioxidants on the oxidative stability of biodiesel from Tilapia oil," Renewable Energy, Elsevier, vol. 156(C), pages 1100-1106.
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    6. Rial, Rafael Cardoso & Merlo, Thais Cardoso & Michalski Santos, Piter Hernanny & Dias Melo, Luiz Felipe & Barbosa, Reginaldo Aparecido & de Freitas, Osmar Nunes & Domingues Nazário, Carlos Eduardo & V, 2020. "Evaluation of oxidative stability of soybean methyl biodiesel using extract of cagaite leaves (Eugenia dysenterica DC.) as additive," Renewable Energy, Elsevier, vol. 152(C), pages 1079-1085.
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    2. Umar, Yusuf & Velasco, Orlando & Abdelaziz, Omar Y. & Aboelazayem, Omar & Gadalla, Mamdouh A. & Hulteberg, Christian P. & Saha, Basudeb, 2022. "A renewable lignin-derived bio-oil for boosting the oxidation stability of biodiesel," Renewable Energy, Elsevier, vol. 182(C), pages 867-878.

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