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Evaluation of the oxidative and thermal stability of soybean methyl biodiesel with additions of dichloromethane extract ginger (Zingiber officinale Roscoe)

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  • Rial, Rafael Cardoso
  • de Freitas, Osmar Nunes
  • Santos, Gemima dos
  • Nazário, Carlos Eduardo Domingues
  • Viana, Luíz Henrique

Abstract

The objective of the present work was to evaluate the effect of the addition of dichloromethane extract obtained from Ginger rhizomes (Zingiber officinale Roscoe) in biodiesel, as well as to compare the results obtained with the synthetic antioxidants BHT and TBHQ. The soybean methyl biodiesel (BMS) used was produced in our laboratory. The thermal behavior of the extract, synthetic antioxidants and biodiesel produced were evaluated using TG/DTG techniques. The additions of EDG and BHT and TBHQ were performed in increasing proportions relative to the mass of the extract: mass of the methyl biodiesel and the samples were stored under the same conditions and studied for storage time of up to ninety days using TG/DTG and method to evaluate the action of the addition of these antioxidants in inhibiting and/or retarding the oxidative stability of the biodiesel samples. After 90 days of storage, the BAN-4 sample had the highest initial decomposition temperature. Regarding the oxidative stability, the samples with EDG additions also presented values higher than the minimum regulated by the ANP, confirming the action of the antioxidants present in the EDG in the control of the oxidation reactions of BMS.

Suggested Citation

  • Rial, Rafael Cardoso & de Freitas, Osmar Nunes & Santos, Gemima dos & Nazário, Carlos Eduardo Domingues & Viana, Luíz Henrique, 2019. "Evaluation of the oxidative and thermal stability of soybean methyl biodiesel with additions of dichloromethane extract ginger (Zingiber officinale Roscoe)," Renewable Energy, Elsevier, vol. 143(C), pages 295-300.
    • Handle: RePEc:eee:renene:v:143:y:2019:i:c:p:295-300
    DOI: 10.1016/j.renene.2019.04.164
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    References listed on IDEAS

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    1. Meher, L.C. & Vidya Sagar, D. & Naik, S.N., 2006. "Technical aspects of biodiesel production by transesterification--a review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 10(3), pages 248-268, June.
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    1. Nogueira, Tiago Rocha & de Mesquita Figueredo, Igor & Tavares Luna, Francisco Murilo & Cavalcante, Célio Loureiro & Evangelista de Ávila dos Santos, João & Sousa Lima, Mary Anne & Josino da Silva, Thi, 2020. "Evaluation of oxidative stability of soybean biodiesel using ethanolic and chloroform extracts of Platymiscium floribundum as antioxidant," Renewable Energy, Elsevier, vol. 159(C), pages 767-774.
    2. Jemima Romola, C.V. & Karl J Samuel, P.K. & Megana Harshini, M. & Ganesh Moorthy, I. & Shyam Kumar, R. & Chinnathambi, Arunachalam & Salmen, Saleh H. & Alharbi, Sulaiman Ali & Karthikumar, Sankar, 2021. "Improvement of fuel properties of used palm oil derived biodiesel with butyl ferulate as an additive," Renewable Energy, Elsevier, vol. 175(C), pages 1052-1068.
    3. Rial, Rafael Cardoso & Merlo, Thais Cardoso & Michalski Santos, Piter Hernanny & Dias Melo, Luiz Felipe & Barbosa, Reginaldo Aparecido & de Freitas, Osmar Nunes & Domingues Nazário, Carlos Eduardo & V, 2020. "Evaluation of oxidative stability of soybean methyl biodiesel using extract of cagaite leaves (Eugenia dysenterica DC.) as additive," Renewable Energy, Elsevier, vol. 152(C), pages 1079-1085.
    4. Li, Ruizhi & Wang, Shuang & Zhang, Huicong & Li, Fashe & Sui, Meng, 2022. "Synthesis, antioxidant properties, and oil solubility of a novel ionic liquid [UIM0Y2][C6H2(OH)3COO] in biodiesel," Renewable Energy, Elsevier, vol. 197(C), pages 545-551.
    5. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    6. Cavalheiro, Leandro Fontoura & Misutsu, Marcelo Yukio & Rial, Rafael Cardoso & Viana, Luíz Henrique & Oliveira, Lincoln Carlos Silva, 2020. "Characterization of residues and evaluation of the physico chemical properties of soybean biodiesel and biodiesel: Diesel blends in different storage conditions," Renewable Energy, Elsevier, vol. 151(C), pages 454-462.

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