IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v175y2021icp1052-1068.html
   My bibliography  Save this article

Improvement of fuel properties of used palm oil derived biodiesel with butyl ferulate as an additive

Author

Listed:
  • Jemima Romola, C.V.
  • Karl J Samuel, P.K.
  • Megana Harshini, M.
  • Ganesh Moorthy, I.
  • Shyam Kumar, R.
  • Chinnathambi, Arunachalam
  • Salmen, Saleh H.
  • Alharbi, Sulaiman Ali
  • Karthikumar, Sankar

Abstract

The present study addresses the significant utility of Used Palm oil Methyl Ester (UPOME) and enhancing the capabilities by adding butyl ferulate. This phenolic antioxidant ester was synthesized using Rhizopus nevius lipase immobilised onto cuttlebone. The butyl ferulate synthesis was monitored in RP-HPLC and confirmed via GC-MS. Concurrently, UPOME was prepared using KOH as the catalyst from the used palm oil. The UPOME was fortified with ferulic acid and butyl ferulate, separately at various concentrations and subjected to thermal oxidation at 110 °C. Biodiesel prepared were estimated for oxidative stability by pattern variations deciphered from the excitation-emission matrix profile. Similarly, the induction period (IP) of the prepared biodiesels was analysed in Rancimate. The addition of the butyl ferulate at 600 ppm in UPOME was able to reduce 80% of the hydroperoxide formation whereas the free ferulic acid showed Stokes shift at the same condition and concentration. Comparatively, 3.5 fold escalation in IP was observed in UPOME with 1000 ppm butyl ferulate than the free ferulic acid. Emission characteristics depicted a significant reduction in NOx (4.7%), CO (27.8%), CO2 (8.3%) and Unburned Hydrocarbons (5.7%) when fuelled B20 with 1000 ppm BF in Compression Ignition engine.

Suggested Citation

  • Jemima Romola, C.V. & Karl J Samuel, P.K. & Megana Harshini, M. & Ganesh Moorthy, I. & Shyam Kumar, R. & Chinnathambi, Arunachalam & Salmen, Saleh H. & Alharbi, Sulaiman Ali & Karthikumar, Sankar, 2021. "Improvement of fuel properties of used palm oil derived biodiesel with butyl ferulate as an additive," Renewable Energy, Elsevier, vol. 175(C), pages 1052-1068.
    • Handle: RePEc:eee:renene:v:175:y:2021:i:c:p:1052-1068
    DOI: 10.1016/j.renene.2021.05.065
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148121007412
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2021.05.065?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Ryuji Kawamoto & Hideo Mochizuki & Yoshihisa Moriguchi & Takahiro Nakano & Masayuki Motohashi & Yuji Sakai & Atsushi Inaba, 2019. "Estimation of CO 2 Emissions of Internal Combustion Engine Vehicle and Battery Electric Vehicle Using LCA," Sustainability, MDPI, vol. 11(9), pages 1-15, May.
    2. Khounani, Zahra & Hosseinzadeh-Bandbafha, Homa & Nizami, Abdul-Sattar & Sulaiman, Alawi & Goli, Sayed Amir Hossein & Tavassoli-Kafrani, Elham & Ghaffari, Akram & Rajaeifar, Mohammad Ali & Kim, Ki-Hyun, 2020. "Unlocking the potential of walnut husk extract in the production of waste cooking oil-based biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 119(C).
    3. Rodica Niculescu & Adrian Clenci & Victor Iorga-Siman, 2019. "Review on the Use of Diesel–Biodiesel–Alcohol Blends in Compression Ignition Engines," Energies, MDPI, vol. 12(7), pages 1-41, March.
    4. Al-Mawali, Kamla S. & Osman, Ahmed I. & Al-Muhtaseb, Ala’a H. & Mehta, Neha & Jamil, Farrukh & Mjalli, Farouk & Vakili-Nezhaad, G. Reza & Rooney, David W., 2021. "Life cycle assessment of biodiesel production utilising waste date seed oil and a novel magnetic catalyst: A circular bioeconomy approach," Renewable Energy, Elsevier, vol. 170(C), pages 832-846.
    5. Krzysztof Kosowski & Karol Tucki & Marian Piwowarski & Robert Stępień & Olga Orynycz & Wojciech Włodarski & Anna Bączyk, 2019. "Thermodynamic Cycle Concepts for High-Efficiency Power Plans. Part A: Public Power Plants 60+," Sustainability, MDPI, vol. 11(2), pages 1-11, January.
    6. Rashed, M.M. & Masjuki, H.H. & Kalam, M.A. & Alabdulkarem, Abdullah & Rahman, M.M. & Imdadul, H.K. & Rashedul, H.K., 2016. "Study of the oxidation stability and exhaust emission analysis of Moringa olifera biodiesel in a multi-cylinder diesel engine with aromatic amine antioxidants," Renewable Energy, Elsevier, vol. 94(C), pages 294-303.
    7. Qu, Tongxin & Niu, Shengli & Gong, Zhiqiang & Han, Kuihua & Wang, Yongzheng & Lu, Chunmei, 2020. "Wollastonite decorated with calcium oxide as heterogeneous transesterification catalyst for biodiesel production: Optimized by response surface methodology," Renewable Energy, Elsevier, vol. 159(C), pages 873-884.
    8. Kannan, G.R. & Karvembu, R. & Anand, R., 2011. "Effect of metal based additive on performance emission and combustion characteristics of diesel engine fuelled with biodiesel," Applied Energy, Elsevier, vol. 88(11), pages 3694-3703.
    9. Rial, Rafael Cardoso & de Freitas, Osmar Nunes & Santos, Gemima dos & Nazário, Carlos Eduardo Domingues & Viana, Luíz Henrique, 2019. "Evaluation of the oxidative and thermal stability of soybean methyl biodiesel with additions of dichloromethane extract ginger (Zingiber officinale Roscoe)," Renewable Energy, Elsevier, vol. 143(C), pages 295-300.
    10. Angel Sánchez & Rocio Maceiras & Angeles Cancela & Mónica Rodríguez, 2012. "Influence of n -Hexane on in Situ Transesterification of Marine Macroalgae," Energies, MDPI, vol. 5(2), pages 1-15, February.
    11. Qi, D.H. & Geng, L.M. & Chen, H. & Bian, Y.ZH. & Liu, J. & Ren, X.CH., 2009. "Combustion and performance evaluation of a diesel engine fueled with biodiesel produced from soybean crude oil," Renewable Energy, Elsevier, vol. 34(12), pages 2706-2713.
    12. Serqueira, Dalyelli S. & Pereira, Jian F.S. & Squissato, André L. & Rodrigues, Mônica A. & Lima, Renata C. & Faria, Anízio M. & Richter, Eduardo M. & Munoz, Rodrigo A.A., 2021. "Oxidative stability and corrosivity of biodiesel produced from residual cooking oil exposed to copper and carbon steel under simulated storage conditions: Dual effect of antioxidants," Renewable Energy, Elsevier, vol. 164(C), pages 1485-1495.
    13. Mohamed Mohamed & Chee-Keong Tan & Ali Fouda & Mohammed Saber Gad & Osayed Abu-Elyazeed & Abdel-Fatah Hashem, 2020. "Diesel Engine Performance, Emissions and Combustion Characteristics of Biodiesel and Its Blends Derived from Catalytic Pyrolysis of Waste Cooking Oil," Energies, MDPI, vol. 13(21), pages 1-13, October.
    14. Girardi, Julio Cezar & Bariccatti, Reinaldo Aparecido & Savada, Felipe Yassuo & Borsato, Dionísio & Melegari de Souza, Samuel Nelson & Amaral, Camila Zeni & Prior, Maritane, 2020. "Response surface methodology for the optimization of oxidative stability through the use of natural additives," Renewable Energy, Elsevier, vol. 159(C), pages 346-355.
    15. Muhammad Qasim & Tariq Mahmood Ansari & Mazhar Hussain, 2017. "Combustion, Performance, and Emission Evaluation of a Diesel Engine with Biodiesel Like Fuel Blends Derived From a Mixture of Pakistani Waste Canola and Waste Transformer Oils," Energies, MDPI, vol. 10(7), pages 1-16, July.
    16. Yahya, Syahirah & Muhamad Wahab, Syamsul Kamar & Harun, Farah Wahida, 2020. "Optimization of biodiesel production from waste cooking oil using Fe-Montmorillonite K10 by response surface methodology," Renewable Energy, Elsevier, vol. 157(C), pages 164-172.
    Full references (including those not matched with items on IDEAS)

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Mofijur, M. & Atabani, A.E. & Masjuki, H.H. & Kalam, M.A. & Masum, B.M., 2013. "A study on the effects of promising edible and non-edible biodiesel feedstocks on engine performance and emissions production: A comparative evaluation," Renewable and Sustainable Energy Reviews, Elsevier, vol. 23(C), pages 391-404.
    2. Marco Bietresato & Carlo Caligiuri & Anna Bolla & Massimiliano Renzi & Fabrizio Mazzetto, 2019. "Proposal of a Predictive Mixed Experimental- Numerical Approach for Assessing the Performance of Farm Tractor Engines Fuelled with Diesel- Biodiesel-Bioethanol Blends," Energies, MDPI, vol. 12(12), pages 1-45, June.
    3. E, Jiaqiang & Pham, Minhhieu & Zhao, D. & Deng, Yuanwang & Le, DucHieu & Zuo, Wei & Zhu, Hao & Liu, Teng & Peng, Qingguo & Zhang, Zhiqing, 2017. "Effect of different technologies on combustion and emissions of the diesel engine fueled with biodiesel: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 80(C), pages 620-647.
    4. Homeyra Piri & Massimiliano Renzi & Marco Bietresato, 2023. "Technical Implications of the Use of Biofuels in Agricultural and Industrial Compression-Ignition Engines with a Special Focus on the Interactions with (Bio)lubricants," Energies, MDPI, vol. 17(1), pages 1-45, December.
    5. Jain, Akshay & Bora, Bhaskor Jyoti & Kumar, Rakesh & Sharma, Prabhakar & Deka, Hiranya, 2023. "Theoretical potential estimation and multi-objective optimization of Water Hyacinth (Eichhornia Crassipes) biodiesel powered diesel engine at variable injection timings," Renewable Energy, Elsevier, vol. 206(C), pages 514-530.
    6. Jemima Romola, C.V. & Meganaharshini, M. & Rigby, S.P. & Ganesh Moorthy, I. & Shyam Kumar, R. & Karthikumar, Sankar, 2021. "A comprehensive review of the selection of natural and synthetic antioxidants to enhance the oxidative stability of biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 145(C).
    7. Daniel Romeo Kamta Legue & Zacharie Merlin Ayissi & Mahamat Hassane Babikir & Marcel Obounou & Henri Paul Ekobena Fouda, 2021. "Experimental and Simulation of Diesel Engine Fueled with Biodiesel with Variations in Heat Loss Model," Energies, MDPI, vol. 14(6), pages 1-17, March.
    8. Mofijur, M. & Masjuki, H.H. & Kalam, M.A. & Atabani, A.E., 2013. "Evaluation of biodiesel blending, engine performance and emissions characteristics of Jatropha curcas methyl ester: Malaysian perspective," Energy, Elsevier, vol. 55(C), pages 879-887.
    9. Shahabuddin, M. & Liaquat, A.M. & Masjuki, H.H. & Kalam, M.A. & Mofijur, M., 2013. "Ignition delay, combustion and emission characteristics of diesel engine fueled with biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 21(C), pages 623-632.
    10. Nirmala, N. & Dawn, S.S. & Harindra, C., 2020. "Analysis of performance and emission characteristics of Waste cooking oil and Chlorella variabilis MK039712.1 biodiesel blends in a single cylinder, four strokes diesel engine," Renewable Energy, Elsevier, vol. 147(P1), pages 284-292.
    11. Mohammed Kamil & Fatima M. Almarashda, 2023. "Economic Viability and Engine Performance Evaluation of Biodiesel Derived from Desert Palm Date Seeds," Energies, MDPI, vol. 16(3), pages 1-22, February.
    12. Dmytro Zhuravel & Kyrylo Samoichuk & Serhii Petrychenko & Andrii Bondar & Taras Hutsol & Maciej Kuboń & Marcin Niemiec & Lyudmyla Mykhailova & Zofia Gródek-Szostak & Dmytro Sorokin, 2022. "Modeling of Diesel Engine Fuel Systems Reliability When Operating on Biofuels," Energies, MDPI, vol. 15(5), pages 1-16, February.
    13. Bazooyar, Bahamin & Hosseini, Seyyed Yaghoob & Moradi Ghoje Begloo, Solat & Shariati, Ahmad & Hashemabadi, Seyed Hassan & Shaahmadi, Fariborz, 2018. "Mixed modified Fe2O3-WO3 as new fuel borne catalyst (FBC) for biodiesel fuel," Energy, Elsevier, vol. 149(C), pages 438-453.
    14. Solmaz, Hamit & Ardebili, Seyed Mohammad Safieddin & Calam, Alper & Yılmaz, Emre & İpci, Duygu, 2021. "Prediction of performance and exhaust emissions of a CI engine fueled with multi-wall carbon nanotube doped biodiesel-diesel blends using response surface method," Energy, Elsevier, vol. 227(C).
    15. Hoseini, S.S. & Najafi, G. & Ghobadian, B. & Mamat, R. & Ebadi, M.T. & Yusaf, Talal, 2019. "Characterization of biodiesel production (ultrasonic-assisted) from evening-primroses (Oenothera lamarckiana) as novel feedstock and its effect on CI engine parameters," Renewable Energy, Elsevier, vol. 130(C), pages 50-60.
    16. Adhirath Mandal & HaengMuk Cho & Bhupendra Singh Chauhan, 2022. "Experimental Investigation of Multiple Fry Waste Soya Bean Oil in an Agricultural CI Engine," Energies, MDPI, vol. 15(9), pages 1-14, April.
    17. Ferraz de Campos, Victor Arruda & Silva, Valter Bruno & Cardoso, João Sousa & Brito, Paulo S. & Tuna, Celso Eduardo & Silveira, José Luz, 2021. "A review of waste management in Brazil and Portugal: Waste-to-energy as pathway for sustainable development," Renewable Energy, Elsevier, vol. 178(C), pages 802-820.
    18. Ayhan, Vezir & Ece, Yılmaz Mert, 2020. "New application to reduce NOx emissions of diesel engines: Electronically controlled direct water injection at compression stroke," Applied Energy, Elsevier, vol. 260(C).
    19. Fabián Vargas & Armando Pérez & Rene Delgado & Emilio Hernández & José Alejandro Suástegui, 2019. "Performance Analysis of a Compression Ignition Engine Using Mixture Biodiesel Palm and Diesel," Sustainability, MDPI, vol. 11(18), pages 1-26, September.
    20. Subramaniam, D. & Murugesan, A. & Avinash, A. & Kumaravel, A., 2013. "Bio-diesel production and its engine characteristics—An expatiate view," Renewable and Sustainable Energy Reviews, Elsevier, vol. 22(C), pages 361-370.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:175:y:2021:i:c:p:1052-1068. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.