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Biodiesel production and parameter optimization: An approach to utilize residual ash from sugarcane leaf, a novel heterogeneous catalyst, from Calophyllum inophyllum oil

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  • Arumugam, A.
  • Sankaranarayanan, Pooja

Abstract

The rapid depletion of natural oil resources and growing environmental problems has led to the hunt for a cost-efficient method for production of fuel-grade Fatty acid methyl esters (FAME). The supremacy of heterogeneous catalysis urges the development of bio-based catalyst as an alternative to the previously used catalyst. The present study elevates the practicability of utilizing residual ash from sugarcane leaves as a catalyst for the production of Calophyllum inophyllum methyl esters. XRD, SEM, FT-IR were used to characterize the residual ash. Central Composite design based response surface methodology was employed to study the relationship between process parameters on FAME yield. In optimum conditions of methanol to oil ratio of 19:1, 5 wt% of catalyst and temperature of 64 °C, there obtained a maximum FAME yield of 97%.85% yield up to 6 cycles has been shown by reusability data. Performance and emission exhaust analysis of produced FAME shows that blended version of B10 and B80 has a better efficiency of using biodiesel as a backup energy source.

Suggested Citation

  • Arumugam, A. & Sankaranarayanan, Pooja, 2020. "Biodiesel production and parameter optimization: An approach to utilize residual ash from sugarcane leaf, a novel heterogeneous catalyst, from Calophyllum inophyllum oil," Renewable Energy, Elsevier, vol. 153(C), pages 1272-1282.
    • Handle: RePEc:eee:renene:v:153:y:2020:i:c:p:1272-1282
    DOI: 10.1016/j.renene.2020.02.101
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    1. Tan, Yie Hua & Abdullah, Mohammad Omar & Nolasco-Hipolito, Cirilo & Taufiq-Yap, Yun Hin, 2015. "Waste ostrich- and chicken-eggshells as heterogeneous base catalyst for biodiesel production from used cooking oil: Catalyst characterization and biodiesel yield performance," Applied Energy, Elsevier, vol. 160(C), pages 58-70.
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    3. Arumugam, A. & Thulasidharan, D. & Jegadeesan, Gautham B., 2018. "Process optimization of biodiesel production from Hevea brasiliensis oil using lipase immobilized on spherical silica aerogel," Renewable Energy, Elsevier, vol. 116(PA), pages 755-761.
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    2. S, Prabakaran & T, Mohanraj & A, Arumugam, 2021. "Azolla pinnata methyl ester production and process optimization using a novel heterogeneous catalyst," Renewable Energy, Elsevier, vol. 180(C), pages 353-371.
    3. Miladinović, Marija R. & Krstić, Jugoslav B. & Zdujić, Miodrag V. & Veselinović, Ljiljana M. & Veljović, Djordje N. & Banković-Ilić, Ivana B. & Stamenković, Olivera S. & Veljković, Vlada B., 2022. "Transesterification of used cooking sunflower oil catalyzed by hazelnut shell ash," Renewable Energy, Elsevier, vol. 183(C), pages 103-113.
    4. Vishali, K. & Rupesh, K.J. & Prabakaran, S. & Sudalai, S. & Uppuluri, Kiran Babu & Arumugam, A., 2023. "Development and techno-economic analysis of Calophyllum inophyllum biorefinery for the production of biodiesel, biohydrogen, bio-oil, and biochar: Waste to energy approach," Renewable Energy, Elsevier, vol. 218(C).
    5. Jume, Binta Hadi & Gabris, Mohammad Ali & Rashidi Nodeh, Hamid & Rezania, Shahabaldin & Cho, Jinwoo, 2020. "Biodiesel production from waste cooking oil using a novel heterogeneous catalyst based on graphene oxide doped metal oxide nanoparticles," Renewable Energy, Elsevier, vol. 162(C), pages 2182-2189.

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