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Highly efficient hydrogen generation from hydrazine borane via a MoOx-promoted NiPd nanocatalyst

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  • Yao, Qilu
  • Yang, Kangkang
  • Nie, Wendan
  • Li, Yaxing
  • Lu, Zhang-Hui

Abstract

Hydrazine borane (N2H4BH3) has been considered as a promising chemical hydrogen storage material in recent years for its high hydrogen content (15.4 wt%), easy preparing, and good stability. Designing highly efficient and selective catalysts for realizing the hydrogen evolution from N2H4BH3 is highly attractive but still remains challenging. In this work, NiPd nanoparticles (NPs) modified with MoOx have been readily synthesized via a co-reduction route at room temperature and served as highly efficient catalysts toward hydrogen generation from N2H4BH3 in aqueous solution. Compared to the pure Ni0.6Pd0.4 NPs, the obtained Ni0.6Pd0.4-MoOx catalyst exhibits much higher catalytic performances in dehydrogenation of N2H4BH3 at 323 K, providing a total turnover frequency (TOF) value of 405 h−1 and almost 100% hydrogen selectivity. The improved catalytic activity of NiPd-MoOx catalyst may be attributed to the small particles size and increased electron density of NiPd as well as the strong basic sites of NiPd NPs induced by the MoOx dopant. The facile synthesis of high-performance and cost-effective of metal NPs catalysts is of great significance for the development of N2H4BH3 as a promising hydrogen storage material.

Suggested Citation

  • Yao, Qilu & Yang, Kangkang & Nie, Wendan & Li, Yaxing & Lu, Zhang-Hui, 2020. "Highly efficient hydrogen generation from hydrazine borane via a MoOx-promoted NiPd nanocatalyst," Renewable Energy, Elsevier, vol. 147(P1), pages 2024-2031.
    • Handle: RePEc:eee:renene:v:147:y:2020:i:p1:p:2024-2031
    DOI: 10.1016/j.renene.2019.09.144
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    References listed on IDEAS

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    1. Huan Yan & Yue Lin & Hong Wu & Wenhua Zhang & Zhihu Sun & Hao Cheng & Wei Liu & Chunlei Wang & Junjie Li & Xiaohui Huang & Tao Yao & Jinlong Yang & Shiqiang Wei & Junling Lu, 2017. "Bottom-up precise synthesis of stable platinum dimers on graphene," Nature Communications, Nature, vol. 8(1), pages 1-11, December.
    2. Louis Schlapbach & Andreas Züttel, 2001. "Hydrogen-storage materials for mobile applications," Nature, Nature, vol. 414(6861), pages 353-358, November.
    3. Romain Moury & Umit B. Demirci, 2015. "Hydrazine Borane and Hydrazinidoboranes as Chemical Hydrogen Storage Materials," Energies, MDPI, vol. 8(4), pages 1-24, April.
    4. Wang, Yan & Shen, Yan & Qi, Kezhen & Cao, Zhongqiu & Zhang, Ke & Wu, Shiwei, 2016. "Nanostructured cobalt–phosphorous catalysts for hydrogen generation from hydrolysis of sodium borohydride solution," Renewable Energy, Elsevier, vol. 89(C), pages 285-294.
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    Cited by:

    1. Munonde, Tshimangadzo S. & Zheng, Haitao & Matseke, Mphoma S. & Nomngongo, Philiswa N. & Wang, Yi & Tsiakaras, Panagiotis, 2020. "A green approach for enhancing the electrocatalytic activity and stability of NiFe2O4/CB nanospheres towards hydrogen production," Renewable Energy, Elsevier, vol. 154(C), pages 704-714.
    2. Guo, Feng & Zou, Hongtao & Yao, Qilu & Huang, Bin & Lu, Zhang-Hui, 2020. "Monodispersed bimetallic nanoparticles anchored on TiO2-decorated titanium carbide MXene for efficient hydrogen production from hydrazine in aqueous solution," Renewable Energy, Elsevier, vol. 155(C), pages 1293-1301.
    3. Feng, Yufa & Chen, Xiaodong & Wang, Huize & Li, Xiaolei & Huang, Hanzhao & Liu, Yu & Li, Hao, 2021. "Durable and high performing Ti supported Ni0.4Cu0.6Co2O4 nanoleaf-like array catalysts for hydrogen production," Renewable Energy, Elsevier, vol. 169(C), pages 660-669.

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