IDEAS home Printed from https://ideas.repec.org/a/eee/renene/v146y2020icp1242-1248.html
   My bibliography  Save this article

Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment

Author

Listed:
  • Dahdah, Eliane
  • Estephane, Jane
  • Haydar, Reem
  • Youssef, Yara
  • El Khoury, Bilal
  • Gennequin, Cedric
  • Aboukaïs, Antoine
  • Abi-Aad, Edmond
  • Aouad, Samer

Abstract

Different Ca–Mg–Al catalysts were prepared by the hydrotalcite route using co-precipitation and impregnation techniques. The effect of thermal treatment was studied and the obtained mixed oxides were characterized by X-ray diffraction, N2 adsorption-desorption and CO2-temperature programmed desorption. Catalysts were then tested in the transesterification of sunflower oil. The catalyst that showed the best catalytic performance was an uncalcined Mg4Al2 support impregnated with 40 wt% of calcium followed by a calcination at 600 °C (Ca600/Mg4Al2HT). Optimum conditions for biodiesel production over this catalyst were a reaction time of 6 h, a catalyst to oil ratio of 2.5 wt%, a 15:1 methanol to oil molar ratio, a stirring rate of 400 rpm and a temperature of 60 °C giving a final FAME yield of 95%.

Suggested Citation

  • Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.
    • Handle: RePEc:eee:renene:v:146:y:2020:i:c:p:1242-1248
    DOI: 10.1016/j.renene.2019.06.171
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0960148119310110
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.renene.2019.06.171?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    2. Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
    3. Lee, H.V. & Juan, J.C. & Taufiq-Yap, Y.H., 2015. "Preparation and application of binary acid–base CaO–La2O3 catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 74(C), pages 124-132.
    4. Marinković, Dalibor M. & Stanković, Miroslav V. & Veličković, Ana V. & Avramović, Jelena M. & Miladinović, Marija R. & Stamenković, Olivera O. & Veljković, Vlada B. & Jovanović, Dušan M., 2016. "Calcium oxide as a promising heterogeneous catalyst for biodiesel production: Current state and perspectives," Renewable and Sustainable Energy Reviews, Elsevier, vol. 56(C), pages 1387-1408.
    5. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    6. Papargyriou, Despoina & Broumidis, Emmanouil & de Vere-Tucker, Matthew & Gavrielides, Stelios & Hilditch, Paul & Irvine, John T.S. & Bonaccorso, Alfredo D., 2019. "Investigation of solid base catalysts for biodiesel production from fish oil," Renewable Energy, Elsevier, vol. 139(C), pages 661-669.
    7. Mutreja, Vishal & Singh, Satnam & Ali, Amjad, 2011. "Biodiesel from mutton fat using KOH impregnated MgO as heterogeneous catalysts," Renewable Energy, Elsevier, vol. 36(8), pages 2253-2258.
    8. Oumer, A.N. & Hasan, M.M. & Baheta, Aklilu Tesfamichael & Mamat, Rizalman & Abdullah, A.A., 2018. "Bio-based liquid fuels as a source of renewable energy: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 88(C), pages 82-98.
    9. Trakarnpruk, Wimonrat & Porntangjitlikit, Suriya, 2008. "Palm oil biodiesel synthesized with potassium loaded calcined hydrotalcite and effect of biodiesel blend on elastomer properties," Renewable Energy, Elsevier, vol. 33(7), pages 1558-1563.
    10. Asif, M. & Muneer, T., 2007. "Energy supply, its demand and security issues for developed and emerging economies," Renewable and Sustainable Energy Reviews, Elsevier, vol. 11(7), pages 1388-1413, September.
    11. Gomes, João F.P. & Puna, Jaime F.B. & Gonçalves, Lissa M. & Bordado, João C.M., 2011. "Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production," Energy, Elsevier, vol. 36(12), pages 6770-6778.
    12. Tuza, Pablo V. & Manfro, Robinson L. & Ribeiro, Nielson F.P. & Souza, Mariana M.V.M., 2013. "Production of renewable hydrogen by aqueous-phase reforming of glycerol over Ni–Cu catalysts derived from hydrotalcite precursors," Renewable Energy, Elsevier, vol. 50(C), pages 408-414.
    13. Issariyakul, Titipong & Dalai, Ajay K., 2014. "Biodiesel from vegetable oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 31(C), pages 446-471.
    14. Helwani, Z. & Aziz, N. & Kim, J. & Othman, M.R., 2016. "Improving the yield of Jatropha curcas's FAME through sol–gel derived meso-porous hydrotalcites," Renewable Energy, Elsevier, vol. 86(C), pages 68-74.
    15. Doyle, Aidan M. & Albayati, Talib M. & Abbas, Ammar S. & Alismaeel, Ziad T., 2016. "Biodiesel production by esterification of oleic acid over zeolite Y prepared from kaolin," Renewable Energy, Elsevier, vol. 97(C), pages 19-23.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. John, Monnie & Abdullah, Mohammad Omar & Hua, Tan Yie & Nolasco-Hipólito, Cirilo, 2021. "Techno-economical and energy analysis of sunflower oil biodiesel synthesis assisted with waste ginger leaves derived catalysts," Renewable Energy, Elsevier, vol. 168(C), pages 815-828.
    2. Long, Feng & Liu, Weiguo & Jiang, Xia & Zhai, Qiaolong & Cao, Xincheng & Jiang, Jianchun & Xu, Junming, 2021. "State-of-the-art technologies for biofuel production from triglycerides: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 148(C).
    3. Nahas, Lea & Dahdah, Eliane & Aouad, Samer & El Khoury, Bilal & Gennequin, Cedric & Abi Aad, Edmond & Estephane, Jane, 2023. "Highly efficient scallop seashell-derived catalyst for biodiesel production from sunflower and waste cooking oils: Reaction kinetics and effect of calcination temperature studies," Renewable Energy, Elsevier, vol. 202(C), pages 1086-1095.
    4. Vasaki E, Madhu & Karri, Rama Rao & Ravindran, Gobinath & Paramasivan, Balasubramanian, 2021. "Predictive capability evaluation and optimization of sustainable biodiesel production from oleaginous biomass grown on pulp and paper industrial wastewater," Renewable Energy, Elsevier, vol. 168(C), pages 204-215.
    5. Ebrahimian, Elham & Denayer, Joeri F.M. & Aghbashlo, Mortaza & Tabatabaei, Meisam & Karimi, Keikhosro, 2022. "Biomethane and biodiesel production from sunflower crop: A biorefinery perspective," Renewable Energy, Elsevier, vol. 200(C), pages 1352-1361.
    6. Xie, Wenlei & Xiong, Yunfei & Wang, Hongyan, 2021. "Fe3O4-poly(AGE-DVB-GMA) composites immobilized with guanidine as a magnetically recyclable catalyst for enhanced biodiesel production," Renewable Energy, Elsevier, vol. 174(C), pages 758-768.
    7. Anderson Breno Souza & Alvaro Antonio Villa Ochoa & José Ângelo Peixoto da Costa & Gustavo de Novaes Pires Leite & Héber Claudius Nunes Silva & Andrezza Carolina Carneiro Tómas & David Campos Barbosa , 2023. "A Review of Tropical Organic Materials for Biodiesel as a Substitute Energy Source in Internal Combustion Engines: A Viable Solution?," Energies, MDPI, vol. 16(9), pages 1-25, April.
    8. Chalima, Angelina & Taxeidis, George & Topakas, Evangelos, 2020. "Optimization of the production of docosahexaenoic fatty acid by the heterotrophic microalga Crypthecodinium cohnii utilizing a dark fermentation effluent," Renewable Energy, Elsevier, vol. 152(C), pages 102-109.
    9. Al-Hwaiti, Mohammad S. & Alsbou, Eid M. & Al Haddad, Rawan M. & Osman, Ahmed I. & Jrai, Ahmed Abu & Al-Muhtaseb, Ala’a H. & Hasan, Ahmad O. & Morgan, Kevin & El-Sayed, El-Sayed M. & Al-Fatesh, Ahmed S, 2020. "Spatio-temporal analyses of extracted citrullus colocynthis seeds (Handal seed oil) as biofuel in internal combustion engine," Renewable Energy, Elsevier, vol. 166(C), pages 234-244.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Saba, Tony & Estephane, Jane & El Khoury, Bilal & El Khoury, Maroulla & Khazma, Mahmoud & El Zakhem, Henri & Aouad, Samer, 2016. "Biodiesel production from refined sunflower vegetable oil over KOH/ZSM5 catalysts," Renewable Energy, Elsevier, vol. 90(C), pages 301-306.
    2. Mansir, Nasar & Teo, Siow Hwa & Rashid, Umer & Saiman, Mohd Izham & Tan, Yen Ping & Alsultan, G. Abdulkareem & Taufiq-Yap, Yun Hin, 2018. "Modified waste egg shell derived bifunctional catalyst for biodiesel production from high FFA waste cooking oil. A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 82(P3), pages 3645-3655.
    3. Goh, Brandon Han Hoe & Ong, Hwai Chyuan & Cheah, Mei Yee & Chen, Wei-Hsin & Yu, Kai Ling & Mahlia, Teuku Meurah Indra, 2019. "Sustainability of direct biodiesel synthesis from microalgae biomass: A critical review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 107(C), pages 59-74.
    4. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
    5. di Bitonto, Luigi & Reynel-Ávila, Hilda Elizabeth & Mendoza-Castillo, Didilia Ileana & Bonilla-Petriciolet, Adrián & Durán-Valle, Carlos J. & Pastore, Carlo, 2020. "Synthesis and characterization of nanostructured calcium oxides supported onto biochar and their application as catalysts for biodiesel production," Renewable Energy, Elsevier, vol. 160(C), pages 52-66.
    6. Zhang, Heng & Li, Hu & Hu, Yulin & Venkateswara Rao, Kasanneni Tirumala & Xu, Chunbao (Charles) & Yang, Song, 2019. "Advances in production of bio-based ester fuels with heterogeneous bifunctional catalysts," Renewable and Sustainable Energy Reviews, Elsevier, vol. 114(C), pages 1-1.
    7. Mardhiah, H. Haziratul & Ong, Hwai Chyuan & Masjuki, H.H. & Lim, Steven & Lee, H.V., 2017. "A review on latest developments and future prospects of heterogeneous catalyst in biodiesel production from non-edible oils," Renewable and Sustainable Energy Reviews, Elsevier, vol. 67(C), pages 1225-1236.
    8. Navarro-Pineda, Freddy S. & Baz-Rodríguez, Sergio A. & Handler, Robert & Sacramento-Rivero, Julio C., 2016. "Advances on the processing of Jatropha curcas towards a whole-crop biorefinery," Renewable and Sustainable Energy Reviews, Elsevier, vol. 54(C), pages 247-269.
    9. Rattanaphra, Dussadee & Soodjit, Phansiri & Thanapimmetha, Anusith & Saisriyoot, Maythee & Srinophakun, Penjit, 2019. "Synthesis, characterization and catalytic activity studies of lanthanum oxide from Thai monazite ore for biodiesel production," Renewable Energy, Elsevier, vol. 131(C), pages 1128-1137.
    10. Muñoz, Robinson & González, Aixa & Valdebenito, Fabiola & Ciudad, Gustavo & Navia, Rodrigo & Pecchi, Gina & Azócar, Laura, 2020. "Fly ash as a new versatile acid-base catalyst for biodiesel production," Renewable Energy, Elsevier, vol. 162(C), pages 1931-1939.
    11. Borah, Manash Jyoti & Devi, Anuchaya & Saikia, Raktim Abha & Deka, Dhanapati, 2018. "Biodiesel production from waste cooking oil catalyzed by in-situ decorated TiO2 on reduced graphene oxide nanocomposite," Energy, Elsevier, vol. 158(C), pages 881-889.
    12. Ensafi, Ali A. & Nabiyan, Afshin & Jafari-Asl, Mehdi & Dinari, Mohammad & Farrokhpour, Hossein & Rezaei, B., 2016. "Galvanic exchange at layered doubled hydroxide/N-doped graphene as an in-situ method to fabricate powerful electrocatalysts for hydrogen evolution reaction," Energy, Elsevier, vol. 116(P1), pages 1087-1096.
    13. Bambase, Manolito E. & Almazan, Rober Angelo R. & Demafelis, Rex B. & Sobremisana, Marisa J. & Dizon, Lisa Stephanie H., 2021. "Biodiesel production from refined coconut oil using hydroxide-impregnated calcium oxide by cosolvent method," Renewable Energy, Elsevier, vol. 163(C), pages 571-578.
    14. Papargyriou, Despoina & Broumidis, Emmanouil & de Vere-Tucker, Matthew & Gavrielides, Stelios & Hilditch, Paul & Irvine, John T.S. & Bonaccorso, Alfredo D., 2019. "Investigation of solid base catalysts for biodiesel production from fish oil," Renewable Energy, Elsevier, vol. 139(C), pages 661-669.
    15. Xia, Shaige & Li, Jian & Chen, Guanyi & Tao, Junyu & Li, Wanqing & Zhu, Guangbin, 2022. "Magnetic reusable acid-base bifunctional Co doped Fe2O3–CaO nanocatalysts for biodiesel production from soybean oil and waste frying oil," Renewable Energy, Elsevier, vol. 189(C), pages 421-434.
    16. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
    17. Alvarez Serafini, Mariana S. & Reinoso, Deborath M. & Tonetto, Gabriela M., 2018. "Response surface study and kinetic modelling of biodiesel synthesis catalyzed by zinc stearate," Energy, Elsevier, vol. 164(C), pages 264-274.
    18. Ko, Chun-Han & Yeh, Kai-Wun & Wang, Ya-Nang & Wu, Chien-Hou & Chang, Fang-Chih & Cheng, Ming-Hsun & Liou, Chia-Shin, 2012. "Impact of methanol addition strategy on enzymatic transesterification of jatropha oil for biodiesel processing," Energy, Elsevier, vol. 48(1), pages 375-379.
    19. Zhang, Rongyan & Zhu, Fenfen & Dong, Yi & Wu, Xuemin & Sun, Yihe & Zhang, Dongrui & Zhang, Tao & Han, Meiling, 2020. "Function promotion of SO42−/Al2O3–SnO2 catalyst for biodiesel production from sewage sludge," Renewable Energy, Elsevier, vol. 147(P1), pages 275-283.
    20. Hoora Mazaheri & Hwai Chyuan Ong & Zeynab Amini & Haji Hassan Masjuki & M. Mofijur & Chia Hung Su & Irfan Anjum Badruddin & T.M. Yunus Khan, 2021. "An Overview of Biodiesel Production via Calcium Oxide Based Catalysts: Current State and Perspective," Energies, MDPI, vol. 14(13), pages 1-23, July.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:renene:v:146:y:2020:i:c:p:1242-1248. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/renewable-energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.