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Biodiesel production from waste cooking oil catalyzed by in-situ decorated TiO2 on reduced graphene oxide nanocomposite

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  • Borah, Manash Jyoti
  • Devi, Anuchaya
  • Saikia, Raktim Abha
  • Deka, Dhanapati

Abstract

Current research reports the synthesis of in-situ TiO2/RGO nanocomposite and used as a heterogeneous catalyst for the transesterification of waste cooking oil into biodiesel. The prepared catalyst was characterized viz. X-ray diffraction (XRD), Fourier Transform Infrared Spectroscopy (FT-IR), Scanning Electron Microscopy (SEM), Energy Dispersive X-ray (EDX), Transmission Electron Microscopy (TEM), Thermogravimetric analysis (TGA) techniques conforming the successful formation of nanocomposite. The effects of various reaction parameters used for transesterification were examined to optimize the reaction conditions. The best operational conditions were oil to methanol molar ratio of 1:12 at 65 °C with 1.5 wt% catalyst loading and reaction time of 3 h. The catalyst showed good catalytic activity in biodiesel production and biodiesel conversion of 98% was obtained under optimum reaction conditions. Biodiesel conversion was confirmed by Proton Nuclear Magnetic Resonance (1H NMR), Carbon Nuclear Magnetic Resonance (13C NMR) and Gas Chromatography-Mass Spectroscopy (GC-MS) techniques. The excellent catalytic activity of TiO2/RGO could be attributed to the enhanced surface area of the composite.

Suggested Citation

  • Borah, Manash Jyoti & Devi, Anuchaya & Saikia, Raktim Abha & Deka, Dhanapati, 2018. "Biodiesel production from waste cooking oil catalyzed by in-situ decorated TiO2 on reduced graphene oxide nanocomposite," Energy, Elsevier, vol. 158(C), pages 881-889.
    • Handle: RePEc:eee:energy:v:158:y:2018:i:c:p:881-889
    DOI: 10.1016/j.energy.2018.06.079
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    1. Chen, Lei & Yin, Ping & Liu, Xiguang & Yang, Lixia & Yu, Zhongxi & Guo, Xin & Xin, Xinquan, 2011. "Biodiesel production over copper vanadium phosphate," Energy, Elsevier, vol. 36(1), pages 175-180.
    2. Soares Dias, Ana Paula & Bernardo, Joana & Felizardo, Pedro & Neiva Correia, Maria Joana, 2012. "Biodiesel production over thermal activated cerium modified Mg-Al hydrotalcites," Energy, Elsevier, vol. 41(1), pages 344-353.
    3. Atabani, A.E. & Mahlia, T.M.I. & Masjuki, H.H. & Badruddin, Irfan Anjum & Yussof, Hafizuddin Wan & Chong, W.T. & Lee, Keat Teong, 2013. "A comparative evaluation of physical and chemical properties of biodiesel synthesized from edible and non-edible oils and study on the effect of biodiesel blending," Energy, Elsevier, vol. 58(C), pages 296-304.
    4. Deng, Xin & Fang, Zhen & Liu, Yun-hu & Yu, Chang-Liu, 2011. "Production of biodiesel from Jatropha oil catalyzed by nanosized solid basic catalyst," Energy, Elsevier, vol. 36(2), pages 777-784.
    5. Gomes, João F.P. & Puna, Jaime F.B. & Gonçalves, Lissa M. & Bordado, João C.M., 2011. "Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production," Energy, Elsevier, vol. 36(12), pages 6770-6778.
    6. Macor, A. & Pavanello, P., 2009. "Performance and emissions of biodiesel in a boiler for residential heating," Energy, Elsevier, vol. 34(12), pages 2025-2032.
    7. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
    8. Endalew, Abebe K. & Kiros, Yohannes & Zanzi, Rolando, 2011. "Heterogeneous catalysis for biodiesel production from Jatropha curcas oil (JCO)," Energy, Elsevier, vol. 36(5), pages 2693-2700.
    9. Chen, Kang-Shin & Lin, Yuan-Chung & Hsieh, Lien-Te & Lin, Long-Full & Wu, Chia-Chieh, 2010. "Saving energy and reducing pollution by use of emulsified palm-biodiesel blends with bio-solution additive," Energy, Elsevier, vol. 35(5), pages 2043-2048.
    10. Gui, M.M. & Lee, K.T. & Bhatia, S., 2008. "Feasibility of edible oil vs. non-edible oil vs. waste edible oil as biodiesel feedstock," Energy, Elsevier, vol. 33(11), pages 1646-1653.
    11. Farooq, Muhammad & Ramli, Anita & Naeem, Abdul, 2015. "Biodiesel production from low FFA waste cooking oil using heterogeneous catalyst derived from chicken bones," Renewable Energy, Elsevier, vol. 76(C), pages 362-368.
    12. Lee, H.V. & Taufiq-Yap, Y.H. & Hussein, M.Z. & Yunus, R., 2013. "Transesterification of jatropha oil with methanol over Mg–Zn mixed metal oxide catalysts," Energy, Elsevier, vol. 49(C), pages 12-18.
    13. Demirbas, Ayhan, 2007. "Importance of biodiesel as transportation fuel," Energy Policy, Elsevier, vol. 35(9), pages 4661-4670, September.
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    4. Zik, N.A.F.A. & Sulaiman, S. & Jamal, P., 2020. "Biodiesel production from waste cooking oil using calcium oxide/nanocrystal cellulose/polyvinyl alcohol catalyst in a packed bed reactor," Renewable Energy, Elsevier, vol. 155(C), pages 267-277.

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