IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v36y2011i12p6770-6778.html
   My bibliography  Save this article

Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production

Author

Listed:
  • Gomes, João F.P.
  • Puna, Jaime F.B.
  • Gonçalves, Lissa M.
  • Bordado, João C.M.

Abstract

This paper, reports experimental work on the use of new heterogeneous solid basic catalysts for biodiesel production: double oxides of Mg and Al, produced by calcination, at high temperature, of MgAl lamellar structures, the hydrotalcites (HT). The most suitable catalyst system studied are hydrotalcite Mg:Al 2:1 calcinated at 507 °C and 700 °C, leading to higher values of FAME also in the second reaction stage. One of the prepared catalysts resulted in 97.1% Fatty acids methyl esters (FAME) in the 1st reaction step, 92.2% FAME in the 2nd reaction step and 34% FAME in the 3rd reaction step. The biodiesel obtained in the transesterification reaction showed composition and quality parameters within the limits specified by the European Standard EN 14214. 2.5% wt catalyst/oil and a molar ratio methanol:oil of 9:1 or 12:1 at 60–65 °C and 4 h of reaction time are the best operating conditions achieved in this study. This study showed the potential of Mg/Al hydrotalcites as heterogeneous catalysts for biodiesel production.

Suggested Citation

  • Gomes, João F.P. & Puna, Jaime F.B. & Gonçalves, Lissa M. & Bordado, João C.M., 2011. "Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production," Energy, Elsevier, vol. 36(12), pages 6770-6778.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:12:p:6770-6778
    DOI: 10.1016/j.energy.2011.10.024
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544211006839
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2011.10.024?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Balat, Mustafa & Balat, Havva, 2009. "Recent trends in global production and utilization of bio-ethanol fuel," Applied Energy, Elsevier, vol. 86(11), pages 2273-2282, November.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Veiga, Paula Moraes & Luna, Aderval Severino & de Figueiredo Portilho, Marcio & de Oliveira Veloso, Cláudia & Henriques, Cristiane Assumpção, 2014. "Zn,Al-catalysts for heterogeneous biodiesel production: Basicity and process optimization," Energy, Elsevier, vol. 75(C), pages 453-462.
    2. Rajasekar, E. & Selvi, S., 2014. "Review of combustion characteristics of CI engines fueled with biodiesel," Renewable and Sustainable Energy Reviews, Elsevier, vol. 35(C), pages 390-399.
    3. Xue, Bao-jin & Luo, Jia & Zhang, Fan & Fang, Zhen, 2014. "Biodiesel production from soybean and Jatropha oils by magnetic CaFe2O4–Ca2Fe2O5-based catalyst," Energy, Elsevier, vol. 68(C), pages 584-591.
    4. Ensafi, Ali A. & Nabiyan, Afshin & Jafari-Asl, Mehdi & Dinari, Mohammad & Farrokhpour, Hossein & Rezaei, B., 2016. "Galvanic exchange at layered doubled hydroxide/N-doped graphene as an in-situ method to fabricate powerful electrocatalysts for hydrogen evolution reaction," Energy, Elsevier, vol. 116(P1), pages 1087-1096.
    5. Tamboli, Ashif H. & Jadhav, Amol R. & Chung, Wook-Jin & Kim, Hern, 2015. "Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 93(P1), pages 955-962.
    6. Jia, Yongsheng & Wang, Yingjie & Jiang, Cong & Wang, Xun & Hu, Zhiquan & Xiao, Bo & Liu, Shiming, 2022. "Simultaneous enhancement of the H2 yield and HCl removal efficiency from pyrolysis of infusion tube under novel mayenite-based mesoporous catalytic sorbents," Energy, Elsevier, vol. 244(PB).
    7. Soares Dias, Ana Paula & Bernardo, Joana & Felizardo, Pedro & Neiva Correia, Maria Joana, 2012. "Biodiesel production over thermal activated cerium modified Mg-Al hydrotalcites," Energy, Elsevier, vol. 41(1), pages 344-353.
    8. Tesfa, B. & Mishra, R. & Zhang, C. & Gu, F. & Ball, A.D., 2013. "Combustion and performance characteristics of CI (compression ignition) engine running with biodiesel," Energy, Elsevier, vol. 51(C), pages 101-115.
    9. Ma, Yingqun & Wang, Qunhui & Zheng, Lu & Gao, Zhen & Wang, Qiang & Ma, Yuhui, 2016. "Mixed methanol/ethanol on transesterification of waste cooking oil using Mg/Al hydrotalcite catalyst," Energy, Elsevier, vol. 107(C), pages 523-531.
    10. Dahdah, Eliane & Estephane, Jane & Haydar, Reem & Youssef, Yara & El Khoury, Bilal & Gennequin, Cedric & Aboukaïs, Antoine & Abi-Aad, Edmond & Aouad, Samer, 2020. "Biodiesel production from refined sunflower oil over Ca–Mg–Al catalysts: Effect of the composition and the thermal treatment," Renewable Energy, Elsevier, vol. 146(C), pages 1242-1248.
    11. S. Ozkan & J. F. Puna & J. F. Gomes & T. Cabrita & J. V. Palmeira & M. T. Santos, 2019. "Preliminary Study on the Use of Biodiesel Obtained from Waste Vegetable Oils for Blending with Hydrotreated Kerosene Fossil Fuel Using Calcium Oxide (CaO) from Natural Waste Materials as Heterogeneous," Energies, MDPI, vol. 12(22), pages 1-19, November.
    12. Ko, Chun-Han & Yeh, Kai-Wun & Wang, Ya-Nang & Wu, Chien-Hou & Chang, Fang-Chih & Cheng, Ming-Hsun & Liou, Chia-Shin, 2012. "Impact of methanol addition strategy on enzymatic transesterification of jatropha oil for biodiesel processing," Energy, Elsevier, vol. 48(1), pages 375-379.
    13. Yan, Kai & Chen, Aicheng, 2013. "Efficient hydrogenation of biomass-derived furfural and levulinic acid on the facilely synthesized noble-metal-free Cu–Cr catalyst," Energy, Elsevier, vol. 58(C), pages 357-363.
    14. Frolich, Karel & Vávra, Aleš & Kocík, Jaroslav & Hájek, Martin & Jílková, Alena, 2019. "The long-term catalytic performance of mixed oxides in fixed-bed reactors in transesterification," Renewable Energy, Elsevier, vol. 143(C), pages 1259-1267.
    15. Aghbashlo, Mortaza & Hosseinpour, Soleiman & Tabatabaei, Meisam & Dadak, Ali, 2017. "Fuzzy modeling and optimization of the synthesis of biodiesel from waste cooking oil (WCO) by a low power, high frequency piezo-ultrasonic reactor," Energy, Elsevier, vol. 132(C), pages 65-78.
    16. Banerjee, Madhuchanda & Dey, Binita & Talukdar, Jayanta & Chandra Kalita, Mohan, 2014. "Production of biodiesel from sunflower oil using highly catalytic bimetallic gold–silver core–shell nanoparticle," Energy, Elsevier, vol. 69(C), pages 695-699.
    17. Borah, Manash Jyoti & Devi, Anuchaya & Saikia, Raktim Abha & Deka, Dhanapati, 2018. "Biodiesel production from waste cooking oil catalyzed by in-situ decorated TiO2 on reduced graphene oxide nanocomposite," Energy, Elsevier, vol. 158(C), pages 881-889.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Filimonau, Viachaslau & Högström, Michaela, 2017. "The attitudes of UK tourists to the use of biofuels in civil aviation: An exploratory study," Journal of Air Transport Management, Elsevier, vol. 63(C), pages 84-94.
    2. Yasuda, Masahide & Matsumoto, Tomoko & Yamashita, Toshiaki, 2018. "Sacrificial hydrogen production over TiO2-based photocatalysts: Polyols, carboxylic acids, and saccharides," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1627-1635.
    3. Bharathiraja, B. & Jayamuthunagai, J. & Sudharsanaa, T. & Bharghavi, A. & Praveenkumar, R. & Chakravarthy, M. & Yuvaraj, D., 2017. "Biobutanol – An impending biofuel for future: A review on upstream and downstream processing tecniques," Renewable and Sustainable Energy Reviews, Elsevier, vol. 68(P1), pages 788-807.
    4. Zhang, Chen & Sun, Zongxuan, 2017. "Trajectory-based combustion control for renewable fuels in free piston engines," Applied Energy, Elsevier, vol. 187(C), pages 72-83.
    5. Andrea Patané & Giorgio Jansen & Piero Conca & Giovanni Carapezza & Jole Costanza & Giuseppe Nicosia, 2019. "Multi-objective optimization of genome-scale metabolic models: the case of ethanol production," Annals of Operations Research, Springer, vol. 276(1), pages 211-227, May.
    6. M'Arimi, M.M. & Mecha, C.A. & Kiprop, A.K. & Ramkat, R., 2020. "Recent trends in applications of advanced oxidation processes (AOPs) in bioenergy production: Review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 121(C).
    7. Sánchez, S. & Lozano, L.J. & Godínez, C. & Juan, D. & Pérez, A. & Hernández, F.J., 2010. "Carob pod as a feedstock for the production of bioethanol in Mediterranean areas," Applied Energy, Elsevier, vol. 87(11), pages 3417-3424, November.
    8. Jin, Wenxiang & Chen, Ling & Hu, Meng & Sun, Dan & Li, Ao & Li, Ying & Hu, Zhen & Zhou, Shiguang & Tu, Yuanyuan & Xia, Tao & Wang, Yanting & Xie, Guosheng & Li, Yanbin & Bai, Baowei & Peng, Liangcai, 2016. "Tween-80 is effective for enhancing steam-exploded biomass enzymatic saccharification and ethanol production by specifically lessening cellulase absorption with lignin in common reed," Applied Energy, Elsevier, vol. 175(C), pages 82-90.
    9. Diep, Nhu Quynh & Fujimoto, Shinji & Minowa, Tomoaki & Sakanishi, Kinya & Nakagoshi, Nobukazu, 2012. "Estimation of the potential of rice straw for ethanol production and the optimum facility size for different regions in Vietnam," Applied Energy, Elsevier, vol. 93(C), pages 205-211.
    10. Phanankosi Moyo & Mahluli Moyo & Donatus Dube & Oswell Rusinga, 2013. "Biofuel Policy as a Key Driver for Sustainable Development in the Biofuel Sector: The Missing Ingredient in Zimbabwe’s Biofuel Pursuit," Modern Applied Science, Canadian Center of Science and Education, vol. 8(1), pages 1-36, February.
    11. Tan, Raymond R. & Aviso, Kathleen B. & Barilea, Ivan U. & Culaba, Alvin B. & Cruz, Jose B., 2012. "A fuzzy multi-regional input–output optimization model for biomass production and trade under resource and footprint constraints," Applied Energy, Elsevier, vol. 90(1), pages 154-160.
    12. Yao, Yung-Chen & Tsai, Jiun-Horng & Wang, I-Ting, 2013. "Emissions of gaseous pollutant from motorcycle powered by ethanol–gasoline blend," Applied Energy, Elsevier, vol. 102(C), pages 93-100.
    13. Arkadiusz Piwowar & Maciej Dzikuć, 2019. "Development of Renewable Energy Sources in the Context of Threats Resulting from Low-Altitude Emissions in Rural Areas in Poland: A Review," Energies, MDPI, vol. 12(18), pages 1-15, September.
    14. Lenka Rumánková & Luboš Smutka, 2013. "Global sugar market - the analysis of factors influencing supply and demand," Acta Universitatis Agriculturae et Silviculturae Mendelianae Brunensis, Mendel University Press, vol. 61(2), pages 463-471.
    15. Starfelt, Fredrik & Daianova, Lilia & Yan, Jinyue & Thorin, Eva & Dotzauer, Erik, 2012. "The impact of lignocellulosic ethanol yields in polygeneration with district heating – A case study," Applied Energy, Elsevier, vol. 92(C), pages 791-799.
    16. Akroum-Amrouche, Dahbia & Abdi, Nadia & Lounici, Hakim & Mameri, Nabil, 2011. "Effect of physico-chemical parameters on biohydrogen production and growth characteristics by batch culture of Rhodobacter sphaeroides CIP 60.6," Applied Energy, Elsevier, vol. 88(6), pages 2130-2135, June.
    17. Vallinayagam, R. & Vedharaj, S. & Yang, W.M. & Roberts, W.L. & Dibble, R.W., 2015. "Feasibility of using less viscous and lower cetane (LVLC) fuels in a diesel engine: A review," Renewable and Sustainable Energy Reviews, Elsevier, vol. 51(C), pages 1166-1190.
    18. Aloisio S. Nascimento Filho & Rafael G. O. dos Santos & João Gabriel A. Calmon & Peterson A. Lobato & Marcelo A. Moret & Thiago B. Murari & Hugo Saba, 2022. "Induction of a Consumption Pattern for Ethanol and Gasoline in Brazil," Sustainability, MDPI, vol. 14(15), pages 1-11, July.
    19. Katia A. Figueroa-Rodríguez & Francisco Hernández-Rosas & Benjamín Figueroa-Sandoval & Joel Velasco-Velasco & Noé Aguilar Rivera, 2019. "What Has Been the Focus of Sugarcane Research? A Bibliometric Overview," IJERPH, MDPI, vol. 16(18), pages 1-15, September.
    20. Poder, Thomas G. & He, Jie, 2017. "Willingness to pay for a cleaner car: The case of car pollution in Quebec and France," Energy, Elsevier, vol. 130(C), pages 48-54.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:36:y:2011:i:12:p:6770-6778. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.