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Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis

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  • Tamboli, Ashif H.
  • Jadhav, Amol R.
  • Chung, Wook-Jin
  • Kim, Hern

Abstract

Rare earth metal doped HTLPs (hydrotalcites-like precursors) were successfully synthesized by co-precipitation method. The prepared HTLPs were characterized by FE-SEM (field emission scanning electron microscopy), EDX (energy dispersive X-ray spectrometer), Fourier transform infrared spectroscopy (FT-IR), XRD (X-ray diffraction), BET (Brunauer–Emmett–Teller) technique. BET surface analysis results revealed that the surface area of Ce doped HTLPs are quite high than un-doped precursors. Further, the catalytic performance of prepared materials was investigated for hydrogen production from sodium borohydride and it was found that a small amount of Ce doping thoroughly enhance the catalytic activity of HTLPs. BET and XRD results clearly indicated that sizeable change in framework and surface restructuring could occur during cerium doping resulting beneficial effect on its catalytic performances and HTLPs are highly stable even at highly basic conditions. The reaction conditions such as temperature ranging from 25 °C to 75 °C, catalyst amount of 0.08 wt % to 0.16 wt % while molar percent of cerium from 2 mol % to 10 mol %, respectively were investigated. Moreover, it is very convenient to recover the catalyst at the end of reactions; the solid catalyst left could be readily reused for the next consecutive cycles.

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  • Tamboli, Ashif H. & Jadhav, Amol R. & Chung, Wook-Jin & Kim, Hern, 2015. "Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 93(P1), pages 955-962.
    • Handle: RePEc:eee:energy:v:93:y:2015:i:p1:p:955-962
    DOI: 10.1016/j.energy.2015.09.059
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    References listed on IDEAS

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    1. Soares Dias, Ana Paula & Bernardo, Joana & Felizardo, Pedro & Neiva Correia, Maria Joana, 2012. "Biodiesel production over thermal activated cerium modified Mg-Al hydrotalcites," Energy, Elsevier, vol. 41(1), pages 344-353.
    2. Arthur, Ernest Evans & Li, Fang & Momade, Francis W.Y. & Kim, Hern, 2014. "Catalytic hydrolysis of ammonia borane for hydrogen generation using cobalt nanocluster catalyst supported on polydopamine functionalized multiwalled carbon nanotube," Energy, Elsevier, vol. 76(C), pages 822-829.
    3. Li, Qiming & Chen, Yingbo & Lee, Dong Joo & Li, Fang & Kim, Hern, 2012. "Preparation of Y-zeolite/CoCl2 doped PVDF composite nanofiber and its application in hydrogen production," Energy, Elsevier, vol. 38(1), pages 144-150.
    4. Tamboli, Ashif H. & Chaugule, Avinash A. & Sheikh, Faheem A. & Chung, Wook-Jin & Kim, Hern, 2015. "Synthesis and application of CeO2–NiO loaded TiO2 nanofiber as novel catalyst for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 89(C), pages 568-575.
    5. Chinnappan, Amutha & Kang, Hyuck-Chul & Kim, Hern, 2011. "Preparation of PVDF nanofiber composites for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 36(2), pages 755-759.
    6. Chinnappan, Amutha & Jadhav, Arvind H. & Puguan, John Marc C. & Appiah-Ntiamoah, Richard & Kim, Hern, 2015. "Fabrication of ionic liquid/polymer nanoscale networks by electrospinning and chemical cross-linking and their application in hydrogen generation from the hydrolysis of NaBH4," Energy, Elsevier, vol. 79(C), pages 482-488.
    7. Gomes, João F.P. & Puna, Jaime F.B. & Gonçalves, Lissa M. & Bordado, João C.M., 2011. "Study on the use of MgAl hydrotalcites as solid heterogeneous catalysts for biodiesel production," Energy, Elsevier, vol. 36(12), pages 6770-6778.
    8. Santos, D.M.F. & Sequeira, C.A.C., 2011. "Sodium borohydride as a fuel for the future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3980-4001.
    9. Liu, Yongan & Wang, Xinhua & Liu, Haizhen & Dong, Zhaohui & Cao, Guozhou & Yan, Mi, 2014. "Hydrogen generation from Mg–LiBH4 hydrolysis improved by AlCl3 addition," Energy, Elsevier, vol. 68(C), pages 548-554.
    10. Barbir, Frano, 2009. "Transition to renewable energy systems with hydrogen as an energy carrier," Energy, Elsevier, vol. 34(3), pages 308-312.
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    2. Bozkurt, Gamze & Özer, Abdulkadir & Yurtcan, Ayşe Bayrakçeken, 2019. "Development of effective catalysts for hydrogen generation from sodium borohydride: Ru, Pt, Pd nanoparticles supported on Co3O4," Energy, Elsevier, vol. 180(C), pages 702-713.
    3. Tomboc, Gracita Raquel M. & Tamboli, Ashif H. & Kim, Hern, 2017. "Synthesis of Co3O4 macrocubes catalyst using novel chitosan/urea template for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 121(C), pages 238-245.
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    5. Shen, Qiuwan & Shao, Zicheng & Li, Shian & Yang, Guogang & Sunden, Bengt, 2023. "Effects of B-site Al doping on microstructure characteristics and hydrogen production performance of novel LaNixAl1-xO3-δ perovskite in methanol steam reforming," Energy, Elsevier, vol. 268(C).

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