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Preparation of PVDF nanofiber composites for hydrogen generation from sodium borohydride

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  • Chinnappan, Amutha
  • Kang, Hyuck-Chul
  • Kim, Hern

Abstract

Nanofibers are able to form a highly porous mesh and their large surface to volume ratio improves performance for many applications. Organic-inorganic polyvinylidene fluoride (PVDF)-cobalt (II) chloride hexahydrate nanofiber composites were prepared by electrospinning method. The structure and physical-chemical properties of the novel nanofiber composites are characterized by SEM, EDX and FTIR. The SEM results showed the morphology of the fibers and EDX was given the composition of the nanocomposite catalysts. The nanofibers loaded with metal catalysts are used for the hydrogen production by directly mixing with NaBH4 and water. The novel PVDF nanofiber composites catalyst has shown the stability and given the promising results for the quick production of hydrogen.

Suggested Citation

  • Chinnappan, Amutha & Kang, Hyuck-Chul & Kim, Hern, 2011. "Preparation of PVDF nanofiber composites for hydrogen generation from sodium borohydride," Energy, Elsevier, vol. 36(2), pages 755-759.
    • Handle: RePEc:eee:energy:v:36:y:2011:i:2:p:755-759
    DOI: 10.1016/j.energy.2010.12.048
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    References listed on IDEAS

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    1. Penner, S.S., 2006. "Steps toward the hydrogen economy," Energy, Elsevier, vol. 31(1), pages 33-43.
    2. Barbir, Frano, 2009. "Transition to renewable energy systems with hydrogen as an energy carrier," Energy, Elsevier, vol. 34(3), pages 308-312.
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    Full references (including those not matched with items on IDEAS)

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    1. Yue, Xirong & Ji, Xu & Xu, Haiyang & Yang, Bianfeng & Wang, Mengqi & Yang, Yuan, 2023. "Performance investigation on GO-TiO2/PVDF composite ultrafiltration membrane for slightly polluted ground water treatment," Energy, Elsevier, vol. 273(C).
    2. Tamboli, Ashif H. & Jadhav, Amol R. & Chung, Wook-Jin & Kim, Hern, 2015. "Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 93(P1), pages 955-962.
    3. Huang, Yao-Hui & Su, Chia-Chi & Wang, Shu-Ling & Lu, Ming-Chun, 2012. "Development of Al2O3 carrier-Ru composite catalyst for hydrogen generation from alkaline NaBH4 hydrolysis," Energy, Elsevier, vol. 46(1), pages 242-247.
    4. Loghmani, Mohammad Hassan & Shojaei, Abdollah Fallah, 2014. "Hydrogen production through hydrolysis of sodium borohydride: Oleic acid stabilized Co–La–Zr–B nanoparticle as a novel catalyst," Energy, Elsevier, vol. 68(C), pages 152-159.
    5. Li, Qiming & Chen, Yingbo & Lee, Dong Joo & Li, Fang & Kim, Hern, 2012. "Preparation of Y-zeolite/CoCl2 doped PVDF composite nanofiber and its application in hydrogen production," Energy, Elsevier, vol. 38(1), pages 144-150.
    6. Shih, Yu-Jen & Su, Chia-Chi & Huang, Yao-Hui & Lu, Ming-Chun, 2013. "SiO2-supported ferromagnetic catalysts for hydrogen generation from alkaline NaBH4 (sodium borohydride) solution," Energy, Elsevier, vol. 54(C), pages 263-270.
    7. Li, Fang & Arthur, Ernest Evans & La, Dahye & Li, Qiming & Kim, Hern, 2014. "Immobilization of CoCl2 (cobalt chloride) on PAN (polyacrylonitrile) composite nanofiber mesh filled with carbon nanotubes for hydrogen production from hydrolysis of NaBH4 (sodium borohydride)," Energy, Elsevier, vol. 71(C), pages 32-39.
    8. Arthur, Ernest Evans & Li, Fang & Momade, Francis W.Y. & Kim, Hern, 2014. "Catalytic hydrolysis of ammonia borane for hydrogen generation using cobalt nanocluster catalyst supported on polydopamine functionalized multiwalled carbon nanotube," Energy, Elsevier, vol. 76(C), pages 822-829.
    9. Tamboli, Ashif H. & Chaugule, Avinash A. & Sheikh, Faheem A. & Chung, Wook-Jin & Kim, Hern, 2015. "Synthesis and application of CeO2–NiO loaded TiO2 nanofiber as novel catalyst for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 89(C), pages 568-575.
    10. Sahiner, Nurettin & Turhan, Tugce & Lyon, L. Andrew, 2014. "ILC (ionic liquid colloids) based on p(4-VP) (poly(4-vinyl pyridine)) microgels: Synthesis, characterization and use in hydrogen production," Energy, Elsevier, vol. 66(C), pages 256-263.
    11. Cai, Haokun & Liu, Liping & Chen, Qiang & Lu, Ping & Dong, Jian, 2016. "Ni-polymer nanogel hybrid particles: A new strategy for hydrogen production from the hydrolysis of dimethylamine-borane and sodium borohydride," Energy, Elsevier, vol. 99(C), pages 129-135.

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