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Sodium borohydride as a fuel for the future

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  • Santos, D.M.F.
  • Sequeira, C.A.C.

Abstract

In a time of unprecedented change in environmental, geopolitical and socio-economic world affairs, the search for new energy materials has become a topic of great relevance. Sodium borohydride, NaBH4, seems to be a promising fuel in the context of the future hydrogen economy. NaBH4 belongs to a class of materials with the highest gravimetric hydrogen densities, which has been discovered in the 1940s by Schlesinger and Brown. In the present paper, the most relevant issues concerning the use of NaBH4 are examined. Its basic properties are summarised and its synthesis methods are described. The general processes of NaBH4 oxidation, hydrolysis, and monitoring are reviewed. A comprehensive bibliometric analysis of the NaBH4 publications in the energy field opens the discussion for current perspectives and future outlook of NaBH4 as an efficient energy/hydrogen carrier. Despite the observed exponential increase in the research on NaBH4 it is clear that further efforts are still necessary for achieving significant overchanges.

Suggested Citation

  • Santos, D.M.F. & Sequeira, C.A.C., 2011. "Sodium borohydride as a fuel for the future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3980-4001.
    • Handle: RePEc:eee:rensus:v:15:y:2011:i:8:p:3980-4001
    DOI: 10.1016/j.rser.2011.07.018
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    1. Ma, Jia & Choudhury, Nurul A. & Sahai, Yogeshwar, 2010. "A comprehensive review of direct borohydride fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 183-199, January.
    2. Prashant S. Khadke & Pitchumani Sethuraman & Palanivelu Kandasamy & Sridhar Parthasarathi & Ashok K. Shukla, 2009. "A Self-Supported Direct Borohydride-Hydrogen Peroxide Fuel Cell System," Energies, MDPI, vol. 2(2), pages 1-12, April.
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    2. Izaskun Alvarez-Meaza & Enara Zarrabeitia-Bilbao & Rosa Maria Rio-Belver & Gaizka Garechana-Anacabe, 2020. "Fuel-Cell Electric Vehicles: Plotting a Scientific and Technological Knowledge Map," Sustainability, MDPI, vol. 12(6), pages 1-25, March.
    3. An, L. & Jung, C.Y., 2017. "Transport phenomena in direct borohydride fuel cells," Applied Energy, Elsevier, vol. 205(C), pages 1270-1282.
    4. Jianfeng Mao & Duncan H. Gregory, 2015. "Recent Advances in the Use of Sodium Borohydride as a Solid State Hydrogen Store," Energies, MDPI, vol. 8(1), pages 1-24, January.
    5. Tamboli, Ashif H. & Jadhav, Amol R. & Chung, Wook-Jin & Kim, Hern, 2015. "Structurally modified cerium doped hydrotalcite-like precursor as efficient catalysts for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 93(P1), pages 955-962.
    6. Jiang, Hanchen & Qiang, Maoshan & Lin, Peng, 2016. "A topic modeling based bibliometric exploration of hydropower research," Renewable and Sustainable Energy Reviews, Elsevier, vol. 57(C), pages 226-237.
    7. Helder X. Nunes & Diogo L. Silva & Carmen M. Rangel & Alexandra M. F. R. Pinto, 2021. "Rehydrogenation of Sodium Borates to Close the NaBH 4 -H 2 Cycle: A Review," Energies, MDPI, vol. 14(12), pages 1-28, June.
    8. Marwa H. Gouda & Noha A. Elessawy & Diogo M.F. Santos, 2020. "Synthesis and Characterization of Novel Green Hybrid Nanocomposites for Application as Proton Exchange Membranes in Direct Borohydride Fuel Cells," Energies, MDPI, vol. 13(5), pages 1-15, March.
    9. Zhao, Yi & Zhang, Zili & Wang, Hao & Qian, Xinfeng, 2016. "Absorption of carbon dioxide by hydrogen donor under atmospheric pressure," Renewable and Sustainable Energy Reviews, Elsevier, vol. 64(C), pages 84-90.
    10. Tamboli, Ashif H. & Chaugule, Avinash A. & Sheikh, Faheem A. & Chung, Wook-Jin & Kim, Hern, 2015. "Synthesis and application of CeO2–NiO loaded TiO2 nanofiber as novel catalyst for hydrogen production from sodium borohydride hydrolysis," Energy, Elsevier, vol. 89(C), pages 568-575.
    11. Netskina, O.V. & Komova, O.V. & Simagina, V.I. & Odegova, G.V. & Prosvirin, I.P. & Bulavchenko, O.A., 2016. "Aqueous-alkaline NaBH4 solution: The influence of storage duration of solutions on reduction and activity of cobalt catalysts," Renewable Energy, Elsevier, vol. 99(C), pages 1073-1081.
    12. Takaya Ogawa & Mizutomo Takeuchi & Yuya Kajikawa, 2018. "Comprehensive Analysis of Trends and Emerging Technologies in All Types of Fuel Cells Based on a Computational Method," Sustainability, MDPI, vol. 10(2), pages 1-30, February.

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