IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v71y2014icp160-169.html
   My bibliography  Save this article

Evaluation of operating conditions on DBFC (direct borohydride fuel cell) performance with PtRu anode catalyst by response surface method

Author

Listed:
  • Boyacı San, Fatma Gül
  • Okur, Osman
  • İyigün Karadağ, Çiğdem
  • Isik-Gulsac, Isil
  • Okumuş, Emin

Abstract

Borohydride has been considered as a potential fuel for the fuel cell application due to its high energy density. A DBFC (direct borohydride fuel cell) is an electrochemical device that converts chemical energy stored in borohydride and oxidant directly to electrical energy as long as the fuel and oxidant is supplied. One of the main problems encountered in a DBFC is the simultaneous hydrolysis of BH4− at the anode surface. The hydrolysis decreases the fuel utilization and fuel cell performance, since hydrogen bubbles hinder the contact of catalyst with reactant. This study investigates the effect of operating conditions (cell temperature, borohydride concentration, flow rates of fuel and oxidant) on DBFC performance by RSM (response surface methodology). PtRu/C is used as the anode catalyst to systematically investigate the effect of hydrogen evolution rate on the fuel cell performance. The maximum power density is obtained at 80 °C fuel cell temperature, 0.5 M NaBH4 concentration, 5 cm3 min−1 flow of anolyte and 100 cm3 min−1 flow of oxygen.

Suggested Citation

  • Boyacı San, Fatma Gül & Okur, Osman & İyigün Karadağ, Çiğdem & Isik-Gulsac, Isil & Okumuş, Emin, 2014. "Evaluation of operating conditions on DBFC (direct borohydride fuel cell) performance with PtRu anode catalyst by response surface method," Energy, Elsevier, vol. 71(C), pages 160-169.
    • Handle: RePEc:eee:energy:v:71:y:2014:i:c:p:160-169
    DOI: 10.1016/j.energy.2014.04.037
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544214004502
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2014.04.037?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Thepkaew, Jarupuk & Therdthianwong, Apichai & Therdthianwong, Supaporn, 2008. "Key parameters of active layers affecting proton exchange membrane (PEM) fuel cell performance," Energy, Elsevier, vol. 33(12), pages 1794-1800.
    2. Boyaci San, Fatma Gül & Isik-Gulsac, Isil & Okur, Osman, 2013. "Analysis of the polymer composite bipolar plate properties on the performance of PEMFC (polymer electrolyte membrane fuel cells) by RSM (response surface methodology)," Energy, Elsevier, vol. 55(C), pages 1067-1075.
    3. Carton, J.G. & Olabi, A.G., 2010. "Design of experiment study of the parameters that affect performance of three flow plate configurations of a proton exchange membrane fuel cell," Energy, Elsevier, vol. 35(7), pages 2796-2806.
    4. Ma, Jia & Choudhury, Nurul A. & Sahai, Yogeshwar, 2010. "A comprehensive review of direct borohydride fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 14(1), pages 183-199, January.
    5. Chen, Liwei & Zhang, Houcheng & Gao, Songhua & Yan, Huixian, 2014. "Performance optimum analysis of an irreversible molten carbonate fuel cell–Stirling heat engine hybrid system," Energy, Elsevier, vol. 64(C), pages 923-930.
    6. Taymaz, Imdat & Akgun, Fehmi & Benli, Merthan, 2011. "Application of response surface methodology to optimize and investigate the effects of operating conditions on the performance of DMFC," Energy, Elsevier, vol. 36(2), pages 1155-1160.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Zohdi-Fasaei, Hossein & Atashi, Hossein & Farshchi Tabrizi, Farshad & Mirzaei, Ali Akbar, 2017. "Modeling and optimization of Fischer-Tropsch synthesis over Co-Mn-Ce/SiO2 catalyst using hybrid RSM/LHHW approaches," Energy, Elsevier, vol. 128(C), pages 496-508.
    2. Najafi, Gholamhassan & Ghobadian, Barat & Yusaf, Talal & Safieddin Ardebili, Seyed Mohammad & Mamat, Rizalman, 2015. "Optimization of performance and exhaust emission parameters of a SI (spark ignition) engine with gasoline–ethanol blended fuels using response surface methodology," Energy, Elsevier, vol. 90(P2), pages 1815-1829.
    3. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.
    4. Boyacı San, Fatma Gül & İyigün Karadağ, Çiğdem & Okur, Osman & Okumuş, Emin, 2016. "Optimization of the catalyst loading for the direct borohydride fuel cell," Energy, Elsevier, vol. 114(C), pages 214-224.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Rahnavard, Aylin & Rowshanzamir, Soosan & Parnian, Mohammad Javad & Amirkhanlou, Gholam Reza, 2015. "The effect of sulfonated poly (ether ether ketone) as the electrode ionomer for self-humidifying nanocomposite proton exchange membrane fuel cells," Energy, Elsevier, vol. 82(C), pages 746-757.
    2. Sayadi, Parvin & Rowshanzamir, Soosan & Parnian, Mohammad Javad, 2016. "Study of hydrogen crossover and proton conductivity of self-humidifying nanocomposite proton exchange membrane based on sulfonated poly (ether ether ketone)," Energy, Elsevier, vol. 94(C), pages 292-303.
    3. Boyaci San, Fatma Gül & Isik-Gulsac, Isil & Okur, Osman, 2013. "Analysis of the polymer composite bipolar plate properties on the performance of PEMFC (polymer electrolyte membrane fuel cells) by RSM (response surface methodology)," Energy, Elsevier, vol. 55(C), pages 1067-1075.
    4. Boyacı San, Fatma Gül & İyigün Karadağ, Çiğdem & Okur, Osman & Okumuş, Emin, 2016. "Optimization of the catalyst loading for the direct borohydride fuel cell," Energy, Elsevier, vol. 114(C), pages 214-224.
    5. Parnian, Mohammad Javad & Rowshanzamir, Soosan & Gashoul, Fatemeh, 2017. "Comprehensive investigation of physicochemical and electrochemical properties of sulfonated poly (ether ether ketone) membranes with different degrees of sulfonation for proton exchange membrane fuel ," Energy, Elsevier, vol. 125(C), pages 614-628.
    6. Fofana, Daouda & Natarajan, Sadesh Kumar & Hamelin, Jean & Benard, Pierre, 2014. "Low platinum, high limiting current density of the PEMFC (proton exchange membrane fuel cell) based on multilayer cathode catalyst approach," Energy, Elsevier, vol. 64(C), pages 398-403.
    7. Najafi, Gholamhassan & Ghobadian, Barat & Yusaf, Talal & Safieddin Ardebili, Seyed Mohammad & Mamat, Rizalman, 2015. "Optimization of performance and exhaust emission parameters of a SI (spark ignition) engine with gasoline–ethanol blended fuels using response surface methodology," Energy, Elsevier, vol. 90(P2), pages 1815-1829.
    8. Laoun, Brahim & Kasat, Harshal A. & Ahmad, Riaz & Kannan, Arunachala M., 2018. "Gas diffusion layer development using design of experiments for the optimization of a proton exchange membrane fuel cell performance," Energy, Elsevier, vol. 151(C), pages 689-695.
    9. Ren, Zhijun & Zhang, Dongming & Wang, Zaiyi, 2012. "Stacks with TiN/titanium as the bipolar plate for PEMFCs," Energy, Elsevier, vol. 48(1), pages 577-581.
    10. Oluwatosin Ijaodola & Emmanuel Ogungbemi & Fawwad Nisar. Khatib & Tabbi Wilberforce & Mohamad Ramadan & Zaki El Hassan & James Thompson & Abdul Ghani Olabi, 2018. "Evaluating the Effect of Metal Bipolar Plate Coating on the Performance of Proton Exchange Membrane Fuel Cells," Energies, MDPI, vol. 11(11), pages 1-28, November.
    11. Guo, Hang & Liu, Xuan & Zhao, Jian Fu & Ye, Fang & Ma, Chong Fang, 2016. "Effect of low gravity on water removal inside proton exchange membrane fuel cells (PEMFCs) with different flow channel configurations," Energy, Elsevier, vol. 112(C), pages 926-934.
    12. Gong, Wenyin & Cai, Zhihua, 2013. "Accelerating parameter identification of proton exchange membrane fuel cell model with ranking-based differential evolution," Energy, Elsevier, vol. 59(C), pages 356-364.
    13. Huang, Zhen-Ming & Su, Ay & Liu, Ying-Chieh, 2013. "Hydrogen generator system using Ru catalyst for PEMFC (proton exchange membrane fuel cell) applications," Energy, Elsevier, vol. 51(C), pages 230-236.
    14. Yuan, Zhenyu & Yang, Jie & Zhang, Yufeng & Zhang, Xiwei, 2015. "The optimization of air-breathing micro direct methanol fuel cell using response surface method," Energy, Elsevier, vol. 80(C), pages 340-349.
    15. Huang, Yu-Xian & Cheng, Chin-Hsiang & Wang, Xiao-Dong & Jang, Jiin-Yuh, 2010. "Effects of porosity gradient in gas diffusion layers on performance of proton exchange membrane fuel cells," Energy, Elsevier, vol. 35(12), pages 4786-4794.
    16. Santos, D.M.F. & Sequeira, C.A.C., 2011. "Sodium borohydride as a fuel for the future," Renewable and Sustainable Energy Reviews, Elsevier, vol. 15(8), pages 3980-4001.
    17. Okur, Osman & İyigün Karadağ, Çiğdem & Boyacı San, Fatma Gül & Okumuş, Emin & Behmenyar, Gamze, 2013. "Optimization of parameters for hot-pressing manufacture of membrane electrode assembly for PEM (polymer electrolyte membrane fuel cells) fuel cell," Energy, Elsevier, vol. 57(C), pages 574-580.
    18. Lejing Li & Zhuofeng Hu & Yongqiang Kang & Shiyu Cao & Liangpang Xu & Luo Yu & Lizhi Zhang & Jimmy C. Yu, 2023. "Electrochemical generation of hydrogen peroxide from a zinc gallium oxide anode with dual active sites," Nature Communications, Nature, vol. 14(1), pages 1-12, December.
    19. Abdollahzadeh, M. & Ribeirinha, P. & Boaventura, M. & Mendes, A., 2018. "Three-dimensional modeling of PEMFC with contaminated anode fuel," Energy, Elsevier, vol. 152(C), pages 939-959.
    20. Yuan, Zhenyu & Yang, Jie & Li, Xiaoyang & Wang, Shikai, 2016. "The micro-scale analysis of the micro direct methanol fuel cell," Energy, Elsevier, vol. 100(C), pages 10-17.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:71:y:2014:i:c:p:160-169. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.