IDEAS home Printed from https://ideas.repec.org/a/eee/energy/v128y2017icp496-508.html
   My bibliography  Save this article

Modeling and optimization of Fischer-Tropsch synthesis over Co-Mn-Ce/SiO2 catalyst using hybrid RSM/LHHW approaches

Author

Listed:
  • Zohdi-Fasaei, Hossein
  • Atashi, Hossein
  • Farshchi Tabrizi, Farshad
  • Mirzaei, Ali Akbar

Abstract

Operating conditions considerably affect the energy required for Fischer-Tropsch synthesis, depending on the catalyst composition and reactor type (catalyst system). This paper reports the use of cobalt-manganese-cerium supported on silica as a novel CO hydrogenation catalyst, to produce hydrocarbons in a fixed bed micro-reactor. Response surface methodology (RSM) was applied to study the effects of temperature, pressure, feed ratio and their interactions on CO consumption rate, and the selectivity of light olefins (light olefinity), methane and C5+ hydrocarbons. Quadratic mathematical models adequately described the responses in this catalyst system. According to Langmuir Hinshelwood Hougen Watson (LHHW) approach, kinetic mechanism of the reaction was found to be an associative adsorption of H2 and CO. Statistical analysis demonstrated that pressure and feed ratio were the most important factors for the production of C5+ and light alkenes, respectively. Model graphs indicated that minimum methane selectivity was achieved at 523.15 k and 2 bar. The maximum amounts of light olefins and heavier hydrocarbons were obtained at H2/CO = 1 and H2/CO = 2, respectively. Characterization of precursor and calcined catalyst (before and after the reaction) was carried out using SEM and BET techniques.

Suggested Citation

  • Zohdi-Fasaei, Hossein & Atashi, Hossein & Farshchi Tabrizi, Farshad & Mirzaei, Ali Akbar, 2017. "Modeling and optimization of Fischer-Tropsch synthesis over Co-Mn-Ce/SiO2 catalyst using hybrid RSM/LHHW approaches," Energy, Elsevier, vol. 128(C), pages 496-508.
    • Handle: RePEc:eee:energy:v:128:y:2017:i:c:p:496-508
    DOI: 10.1016/j.energy.2017.03.122
    as

    Download full text from publisher

    File URL: http://www.sciencedirect.com/science/article/pii/S0360544217305133
    Download Restriction: Full text for ScienceDirect subscribers only
    File URL: https://libkey.io/10.1016/j.energy.2017.03.122?utm_source=ideas
    LibKey link: if access is restricted and if your library uses this service, LibKey will redirect you to where you can use your library subscription to access this item
    ---><---

    As the access to this document is restricted, you may want to search for a different version of it.

    References listed on IDEAS

    as
    1. Stempien, Jan Pawel & Ni, Meng & Sun, Qiang & Chan, Siew Hwa, 2015. "Thermodynamic analysis of combined Solid Oxide Electrolyzer and Fischer–Tropsch processes," Energy, Elsevier, vol. 81(C), pages 682-690.
    2. Becker, W.L. & Braun, R.J. & Penev, M. & Melaina, M., 2012. "Production of Fischer–Tropsch liquid fuels from high temperature solid oxide co-electrolysis units," Energy, Elsevier, vol. 47(1), pages 99-115.
    3. Okur, Osman & Alper, Erdogan & Almansoori, Ali, 2014. "Optimization of catalyst preparation conditions for direct sodium borohydride fuel cell using response surface methodology," Energy, Elsevier, vol. 67(C), pages 97-105.
    4. Betiku, Eriola & Omilakin, Oluwasesan Ropo & Ajala, Sheriff Olalekan & Okeleye, Adebisi Aminat & Taiwo, Abiola Ezekiel & Solomon, Bamidele Ogbe, 2014. "Mathematical modeling and process parameters optimization studies by artificial neural network and response surface methodology: A case of non-edible neem (Azadirachta indica) seed oil biodiesel synth," Energy, Elsevier, vol. 72(C), pages 266-273.
    5. Boyacı San, Fatma Gül & Okur, Osman & İyigün Karadağ, Çiğdem & Isik-Gulsac, Isil & Okumuş, Emin, 2014. "Evaluation of operating conditions on DBFC (direct borohydride fuel cell) performance with PtRu anode catalyst by response surface method," Energy, Elsevier, vol. 71(C), pages 160-169.
    6. Rahimpour, M.R. & Mirvakili, A. & Paymooni, K., 2011. "A novel water perm-selective membrane dual-type reactor concept for Fischer–Tropsch synthesis of GTL (gas to liquid) technology," Energy, Elsevier, vol. 36(2), pages 1223-1235.
    Full references (including those not matched with items on IDEAS)

    Citations

    Citations are extracted by the CitEc Project, subscribe to its RSS feed for this item.
    as


    Cited by:

    1. Firas K. Al-Zuhairi & Zaidoon M. Shakor & Ihsan Hamawand, 2023. "Maximizing Liquid Fuel Production from Reformed Biogas by Kinetic Studies and Optimization of Fischer–Tropsch Reactions," Energies, MDPI, vol. 16(19), pages 1-21, October.

    Most related items

    These are the items that most often cite the same works as this one and are cited by the same works as this one.
    1. Najafi, Gholamhassan & Ghobadian, Barat & Yusaf, Talal & Safieddin Ardebili, Seyed Mohammad & Mamat, Rizalman, 2015. "Optimization of performance and exhaust emission parameters of a SI (spark ignition) engine with gasoline–ethanol blended fuels using response surface methodology," Energy, Elsevier, vol. 90(P2), pages 1815-1829.
    2. Chen, Bin & Xu, Haoran & Ni, Meng, 2017. "Modelling of SOEC-FT reactor: Pressure effects on methanation process," Applied Energy, Elsevier, vol. 185(P1), pages 814-824.
    3. Brynolf, Selma & Taljegard, Maria & Grahn, Maria & Hansson, Julia, 2018. "Electrofuels for the transport sector: A review of production costs," Renewable and Sustainable Energy Reviews, Elsevier, vol. 81(P2), pages 1887-1905.
    4. Reznicek, Evan P. & Braun, Robert J., 2020. "Reversible solid oxide cell systems for integration with natural gas pipeline and carbon capture infrastructure for grid energy management," Applied Energy, Elsevier, vol. 259(C).
    5. Stoševski, Ivan & Krstić, Jelena & Milikić, Jadranka & Šljukić, Biljana & Kačarević-Popović, Zorica & Mentus, Slavko & Miljanić, Šćepan, 2016. "Radiolitically synthesized nano Ag/C catalysts for oxygen reduction and borohydride oxidation reactions in alkaline media, for potential applications in fuel cells," Energy, Elsevier, vol. 101(C), pages 79-90.
    6. Mahrokh Samavati & Andrew Martin & Massimo Santarelli & Vera Nemanova, 2018. "Synthetic Diesel Production as a Form of Renewable Energy Storage," Energies, MDPI, vol. 11(5), pages 1-21, May.
    7. Stempien, Jan Pawel & Ni, Meng & Sun, Qiang & Chan, Siew Hwa, 2015. "Production of sustainable methane from renewable energy and captured carbon dioxide with the use of Solid Oxide Electrolyzer: A thermodynamic assessment," Energy, Elsevier, vol. 82(C), pages 714-721.
    8. Mehran, Muhammad Taqi & Yu, Seong-Bin & Lee, Dong-Young & Hong, Jong-Eun & Lee, Seung-Bok & Park, Seok-Joo & Song, Rak-Hyun & Lim, Tak-Hyoung, 2018. "Production of syngas from H2O/CO2 by high-pressure coelectrolysis in tubular solid oxide cells," Applied Energy, Elsevier, vol. 212(C), pages 759-770.
    9. Xu, Haoran & Maroto-Valer, M. Mercedes & Ni, Meng & Cao, Jun & Xuan, Jin, 2019. "Low carbon fuel production from combined solid oxide CO2 co-electrolysis and Fischer-Tropsch synthesis system: A modelling study," Applied Energy, Elsevier, vol. 242(C), pages 911-918.
    10. Herz, Gregor & Rix, Christopher & Jacobasch, Eric & Müller, Nils & Reichelt, Erik & Jahn, Matthias & Michaelis, Alexander, 2021. "Economic assessment of Power-to-Liquid processes – Influence of electrolysis technology and operating conditions," Applied Energy, Elsevier, vol. 292(C).
    11. Herz, Gregor & Reichelt, Erik & Jahn, Matthias, 2018. "Techno-economic analysis of a co-electrolysis-based synthesis process for the production of hydrocarbons," Applied Energy, Elsevier, vol. 215(C), pages 309-320.
    12. Albrecht, Friedemann Georg & Nguyen, Tuong-Van, 2020. "Prospects of electrofuels to defossilize transportation in Denmark – A techno-economic and ecological analysis," Energy, Elsevier, vol. 192(C).
    13. König, Daniel H. & Baucks, Nadine & Dietrich, Ralph-Uwe & Wörner, Antje, 2015. "Simulation and evaluation of a process concept for the generation of synthetic fuel from CO2 and H2," Energy, Elsevier, vol. 91(C), pages 833-841.
    14. Samavati, Mahrokh & Santarelli, Massimo & Martin, Andrew & Nemanova, Vera, 2017. "Thermodynamic and economy analysis of solid oxide electrolyser system for syngas production," Energy, Elsevier, vol. 122(C), pages 37-49.
    15. Qi, Huiying & Zhang, Junfeng & Tu, Baofeng & Yin, Yanxia & Zhang, Tonghuan & Liu, Di & Zhang, Fujun & Su, Xin & Cui, Daan & Cheng, Mojie, 2022. "Extreme management strategy and thermodynamic analysis of high temperature H2O/CO2 co-electrolysis for energy conversion," Renewable Energy, Elsevier, vol. 183(C), pages 229-241.
    16. Luo, Yu & Shi, Yixiang & Li, Wenying & Cai, Ningsheng, 2014. "Comprehensive modeling of tubular solid oxide electrolysis cell for co-electrolysis of steam and carbon dioxide," Energy, Elsevier, vol. 70(C), pages 420-434.
    17. Li, Li & Zheng, Keqing & Ni, Meng & Leung, Michael K.H. & Xuan, Jin, 2015. "Partial modification of flow-through porous electrodes in microfluidic fuel cell," Energy, Elsevier, vol. 88(C), pages 563-571.
    18. Yesilyurt, Murat Kadir & Eryilmaz, Tanzer & Arslan, Mevlüt, 2018. "A comparative analysis of the engine performance, exhaust emissions and combustion behaviors of a compression ignition engine fuelled with biodiesel/diesel/1-butanol (C4 alcohol) and biodiesel/diesel/," Energy, Elsevier, vol. 165(PB), pages 1332-1351.
    19. Gómez, Sergio Yesid & Hotza, Dachamir, 2016. "Current developments in reversible solid oxide fuel cells," Renewable and Sustainable Energy Reviews, Elsevier, vol. 61(C), pages 155-174.
    20. Iftikhar Ahmad & Adil Sana & Manabu Kano & Izzat Iqbal Cheema & Brenno C. Menezes & Junaid Shahzad & Zahid Ullah & Muzammil Khan & Asad Habib, 2021. "Machine Learning Applications in Biofuels’ Life Cycle: Soil, Feedstock, Production, Consumption, and Emissions," Energies, MDPI, vol. 14(16), pages 1-27, August.

    Corrections

    All material on this site has been provided by the respective publishers and authors. You can help correct errors and omissions. When requesting a correction, please mention this item's handle: RePEc:eee:energy:v:128:y:2017:i:c:p:496-508. See general information about how to correct material in RePEc.

    If you have authored this item and are not yet registered with RePEc, we encourage you to do it here. This allows to link your profile to this item. It also allows you to accept potential citations to this item that we are uncertain about.

    If CitEc recognized a bibliographic reference but did not link an item in RePEc to it, you can help with this form .

    If you know of missing items citing this one, you can help us creating those links by adding the relevant references in the same way as above, for each refering item. If you are a registered author of this item, you may also want to check the "citations" tab in your RePEc Author Service profile, as there may be some citations waiting for confirmation.

    For technical questions regarding this item, or to correct its authors, title, abstract, bibliographic or download information, contact: Catherine Liu (email available below). General contact details of provider: http://www.journals.elsevier.com/energy .

    Please note that corrections may take a couple of weeks to filter through the various RePEc services.

    IDEAS is a RePEc service. RePEc uses bibliographic data supplied by the respective publishers.